{"categories": [{"id": 1, "name": "structure"}, {"id": 2, "name": "text"}, {"id": 3, "name": "identifier"}, {"id": 4, "name": "supplement"}], "licenses": [{"name": "", "id": 0, "url": ""}], "info": {"contributor": "Jiang Guo", "date_created": "Feb. 01", "description": "A dataset for chemical visual diagram analysis", "url": "", "version": "v1", "year": "2022"}, "images": [{"id": 1356, "width": 1348, "height": 616, "file_name": "ja9612413-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [864.78, 7.22, 157.82, 115.52], "category_id": 1}, {"id": 1, "bbox": [312.23, 23.26, 382.47, 82.06], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [], "products": [0]}], "caption": "Table 3. Metal Size and Ancillary Ligation Effects on the Turnover Frequencies for Primary Aminoalkyne Hydroamination/ Cyclization ", "pdf": {"Page": 9, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 259, 758, 297], "ImageBB": [438, 305, 775, 458]}, "diagram_type": "single"}, {"id": 1357, "width": 1412, "height": 2840, "file_name": "op9701245-Table-c4.png", "license": 0, "bboxes": [{"id": 4, "bbox": [1010.0, 2211.0, 339.0, 544.0], "category_id": 1}, {"id": 5, "bbox": [378.0, 1000.0, 418.0, 237.0], "category_id": 1}, {"id": 6, "bbox": [1098.0, 1013.0, 314.0, 227.0], "category_id": 1}, {"id": 7, "bbox": [0.0, 1728.0, 391.0, 219.0], "category_id": 1}, {"id": 8, "bbox": [575.0, 1742.0, 407.0, 210.0], "category_id": 1}, {"id": 12, "bbox": [271.3, 2230.0, 310.7, 541.4], "category_id": 1}, {"id": 13, "bbox": [1095.0, 1365.0, 317.0, 238.4], "category_id": 1}, {"id": 14, "bbox": [1022.0, 662.0, 390.0, 239.5], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [], "products": [24, 9]}, {"reactants": [9], "conditions": [], "products": [23]}, {"reactants": [14], "conditions": [18, 17, 7], "products": [15]}, {"reactants": [15], "conditions": [6, 16], "products": [22]}, {"reactants": [22], "conditions": [11, 12, 10], "products": [5]}], "caption": "Table 4. Pancreatin resolution screenings", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 306, 67], "ImageBB": [74, 70, 427, 780]}, "diagram_type": "tree"}, {"id": 1358, "width": 1336, "height": 2728, "file_name": "op0602270-Figure-c1.png", "license": 0, "bboxes": [{"id": 1, "bbox": [977.0, 1269.0, 357.0, 243.0], "category_id": 1}, {"id": 2, "bbox": [69.0, 1271.0, 370.0, 241.0], "category_id": 1}, {"id": 3, "bbox": [903.6, 34.0, 379.4, 249.9], "category_id": 1}, {"id": 5, "bbox": [0.0, 0.0, 249.0, 331.0], "category_id": 1}], "reactions": [{"reactants": [11], "conditions": [1, 2], "products": [6]}, {"reactants": [5], "conditions": [7, 3], "products": [4]}], "caption": "Figure 1. Solvent and pressure variation. Reactions were carried out at 10 \u00b0C for 24 h with 0.0024 mmol [Rh(cod)2]BF4, 0.005 mmol ligand 6a and 0.24 mmol substrate in 2.0 mL of solvent. Conversions and ee\u2019s were determined by GC (50 m Chiraldex \u03b2-PM, 130 \u00b0C, (S)-7a 15.1 min, (R)-7a 16.4 min). The absolute configuration was determined by comparison with reported data.3l ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 738, 409, 835], "ImageBB": [75, 53, 409, 735]}, "diagram_type": "multiple"}, {"id": 1359, "width": 1352, "height": 640, "file_name": "op0601316-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [811.2, 0.0, 347.8, 209.9], "category_id": 1}, {"id": 1, "bbox": [220.2, 10.0, 213.5, 192.8], "category_id": 1}, {"id": 2, "bbox": [898.2, 334.1, 256.3, 190.8], "category_id": 1}, {"id": 3, "bbox": [361.2, 358.0, 127.5, 131.7], "category_id": 1}, {"id": 4, "bbox": [28.2, 333.2, 214.5, 193.7], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [12], "products": [1]}, {"reactants": [6, 5], "conditions": [0], "products": [4]}], "caption": "Figure 1. BAL-catalyzed carboligation.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 410, 661, 424], "ImageBB": [439, 247, 777, 407]}, "diagram_type": "multiple"}, {"id": 1360, "width": 1348, "height": 988, "file_name": "op034181b-Table-c3.png", "license": 0, "bboxes": [{"id": 2, "bbox": [324.0, 3.0, 384.4, 133.0], "category_id": 1}, {"id": 3, "bbox": [135.0, 13.0, 141.8, 281.0], "category_id": 1}, {"id": 4, "bbox": [718.95, 78.0, 500.55, 131.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [3, 1], "products": [5]}], "caption": "Table 3. Suzuki coupling results", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 271, 257, 285], "ImageBB": [74, 288, 410, 535]}, "diagram_type": "single"}, {"id": 1361, "width": 1348, "height": 392, "file_name": "ol801791g-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [972.2, 0.0, 230.8, 173.0], "category_id": 1}, {"id": 1, "bbox": [143.0, 19.3, 448.0, 173.7], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [1], "products": [0]}], "caption": "Table 1. Intramolecular Hydroacylation of 8a", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 409, 661, 424], "ImageBB": [425, 433, 762, 531]}, "diagram_type": "single"}, {"id": 1362, "width": 1480, "height": 1496, "file_name": "ol801163v-Figure-c1.png", "license": 0, "bboxes": [{"id": 1, "bbox": [760.0, 197.0, 395.0, 610.4], "category_id": 1}, {"id": 2, "bbox": [698.5, 823.07, 546.8, 622.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [1, 5], "products": [3]}, {"reactants": [8], "conditions": [4, 9], "products": [6]}], "caption": "Figure 1. 1H NMR spectra of dicarbonyl compound 6a and cyclophane 7a in CDCl3 at the aromatic range. ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 185, 393, 214], "ImageBB": [392, 46, 762, 420]}, "diagram_type": "multiple"}, {"id": 1363, "width": 1352, "height": 524, "file_name": "ol801035c-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [910.0, 191.0, 350.0, 199.0], "category_id": 1}, {"id": 5, "bbox": [1037.1, 2.0, 265.9, 196.8], "category_id": 1}, {"id": 6, "bbox": [681.6, 14.0, 348.4, 181.5], "category_id": 1}, {"id": 7, "bbox": [49.1, 24.7, 263.9, 177.0], "category_id": 1}], "reactions": [{"reactants": [10], "conditions": [1, 6], "products": [9, 8, 0]}], "caption": "Table 1. Study of the Direct Phenylation of 2", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 75, 296, 88], "ImageBB": [58, 97, 396, 228]}, "diagram_type": "single"}, {"id": 1364, "width": 1344, "height": 1668, "file_name": "ol401042b-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [778.6, 4.4, 493.1, 211.9], "category_id": 1}, {"id": 1, "bbox": [261.6, 381.9, 392.4, 210.8], "category_id": 1}, {"id": 2, "bbox": [864.4, 354.0, 276.2, 186.6], "category_id": 1}, {"id": 3, "bbox": [1027.6, 784.0, 273.4, 181.1], "category_id": 1}, {"id": 4, "bbox": [460.5, 692.0, 439.5, 288.7], "category_id": 1}, {"id": 5, "bbox": [233.6, 3.0, 436.5, 246.4], "category_id": 1}, {"id": 6, "bbox": [422.66, 1407.98, 397.65, 257.94], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [], "products": [0]}, {"reactants": [1], "conditions": [4], "products": [0]}, {"reactants": [0], "conditions": [6], "products": [2]}, {"reactants": [17], "conditions": [7], "products": [5]}, {"reactants": [5], "conditions": [9], "products": [3]}, {"reactants": [5], "conditions": [], "products": [17]}], "caption": "Figure 2. Substrate with blocked s-trans configuration.", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 542, 728, 555], "ImageBB": [437, 112, 773, 529]}, "diagram_type": "tree"}, {"id": 1365, "width": 1348, "height": 1032, "file_name": "ol200703g-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1013.0, 27.0, 273.0, 202.9], "category_id": 1}, {"id": 2, "bbox": [66.0, 18.0, 348.0, 209.0], "category_id": 1}], "reactions": [{"reactants": [6, 5], "conditions": [1, 2], "products": [0]}], "caption": "Table 1. Copper-Catalyzed Enantioselective Propargylic Ami- nation of Propargylic Pentafluorobenzoates (1) with Anilinesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 171, 767, 198], "ImageBB": [436, 209, 773, 467]}, "diagram_type": "single"}, {"id": 1366, "width": 1356, "height": 1440, "file_name": "op500224x-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [50.2, 577.0, 289.8, 272.9], "category_id": 1}, {"id": 1, "bbox": [10.7, 152.8, 248.3, 141.8], "category_id": 1}, {"id": 2, "bbox": [478.0, 192.7, 266.2, 271.3], "category_id": 1}, {"id": 3, "bbox": [987.7, 1057.7, 343.0, 214.6], "category_id": 1}, {"id": 4, "bbox": [574.9, 1045.7, 291.1, 226.3], "category_id": 1}, {"id": 5, "bbox": [1008.0, 182.0, 271.7, 272.0], "category_id": 1}, {"id": 6, "bbox": [55.0, 1047.7, 297.0, 227.3], "category_id": 1}, {"id": 7, "bbox": [997.0, 575.0, 277.7, 277.8], "category_id": 1}, {"id": 8, "bbox": [510.0, 570.0, 300.6, 278.9], "category_id": 1}, {"id": 21, "bbox": [0.55, 241.25, 256.73, 208.48], "category_id": 1}], "reactions": [{"reactants": [1, 30], "conditions": [7, 8], "products": [2]}, {"reactants": [2], "conditions": [27, 29], "products": [5]}, {"reactants": [0], "conditions": [18], "products": [10]}, {"reactants": [10], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [20], "products": [3]}, {"reactants": [3], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [19], "products": [6]}], "caption": "Figure 4. Synthesis of cyclopropyl pyrrolidines.", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 849, 679, 863], "ImageBB": [448, 480, 787, 840]}, "diagram_type": "tree"}, {"id": 1367, "width": 1348, "height": 1176, "file_name": "op300235t-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [952.0, 4.0, 344.5, 395.0], "category_id": 1}, {"id": 1, "bbox": [39.0, 4.7, 303.1, 399.3], "category_id": 1}, {"id": 5, "bbox": [450.0, 4.0, 357.0, 400.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [0]}], "caption": "Table 4. Halogenation through a zincate intermediatea", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 669, 759, 690], "ImageBB": [449, 696, 786, 990]}, "diagram_type": "single"}, {"id": 1368, "width": 1352, "height": 792, "file_name": "op100205s-Table-c5.png", "license": 0, "bboxes": [{"id": 1, "bbox": [1.0, 0.0, 513.0, 335.0], "category_id": 1}, {"id": 2, "bbox": [772.0, 0.0, 580.0, 338.0], "category_id": 1}, {"id": 3, "bbox": [331.0, 415.0, 567.0, 335.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [6], "products": [2]}], "caption": "Table 5. Solubility of 4 in common solvents at 20 \u00b0C", "pdf": {"Page": 8, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 455, 348, 473], "ImageBB": [58, 249, 396, 447]}, "diagram_type": "multiple"}, {"id": 1369, "width": 1348, "height": 296, "file_name": "acs.orglett.5b02545-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [861.0, 13.0, 251.0, 144.0], "category_id": 1}, {"id": 1, "bbox": [240.0, 3.0, 252.0, 160.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [2, 3], "products": [0]}], "caption": "Table 1. Reaction Optimizationa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 632, 110], "ImageBB": [449, 116, 786, 190]}, "diagram_type": "single"}, {"id": 1370, "width": 1348, "height": 1964, "file_name": "acs.orglett.5b02498-Table-c1.png", "license": 0, "bboxes": [{"id": 2, "bbox": [352.0, 50.0, 229.0, 185.0], "category_id": 1}, {"id": 3, "bbox": [26.0, 54.0, 264.0, 161.0], "category_id": 1}, {"id": 4, "bbox": [1048.0, 4.0, 285.0, 242.0], "category_id": 1}], "reactions": [{"reactants": [5, 4], "conditions": [0, 3], "products": [7]}], "caption": "Table 1. Substrate Scopea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 487, 229, 508], "ImageBB": [82, 514, 419, 1005]}, "diagram_type": "single"}, {"id": 1371, "width": 1356, "height": 480, "file_name": "acs.oprd.6b00180-Table-c10.png", "license": 0, "bboxes": [{"id": 1, "bbox": [290.1, 79.4, 267.9, 142.4], "category_id": 1}, {"id": 3, "bbox": [2.0, 65.2, 185.0, 138.8], "category_id": 1}, {"id": 4, "bbox": [1091.7, 9.0, 258.2, 205.2], "category_id": 1}], "reactions": [{"reactants": [5, 3], "conditions": [6, 2], "products": [7]}], "caption": "Table 10. Suzuki Reaction of 2-Bromopyridine (4) and PhB(OH)2 in H2Oa ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 649, 760, 679], "ImageBB": [448, 685, 787, 805]}, "diagram_type": "single"}, {"id": 1372, "width": 2816, "height": 588, "file_name": "acs.oprd.6b00011-Table-c2.png", "license": 0, "bboxes": [{"id": 2, "bbox": [565.0, 4.0, 356.0, 336.0], "category_id": 1}, {"id": 3, "bbox": [1020.0, 46.0, 380.0, 262.0], "category_id": 1}, {"id": 4, "bbox": [1734.0, 4.0, 514.0, 389.0], "category_id": 1}], "reactions": [{"reactants": [3, 4], "conditions": [6, 7], "products": [5]}], "caption": "Table 2. Optimization of Cross-Coupling Reaction To Form Crude GDC-0084", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 378, 527, 393], "ImageBB": [82, 399, 786, 546]}, "diagram_type": "single"}, {"id": 1373, "width": 1356, "height": 432, "file_name": "acs.oprd.5b00251-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [295.5, 51.91, 162.6, 125.78], "category_id": 1}, {"id": 1, "bbox": [875.0, 40.0, 214.0, 133.8], "category_id": 1}, {"id": 2, "bbox": [185.3, 229.0, 98.6, 177.9], "category_id": 1}, {"id": 3, "bbox": [1014.0, 234.1, 170.0, 149.9], "category_id": 1}, {"id": 4, "bbox": [805.1, 219.0, 133.9, 213.0], "category_id": 1}, {"id": 5, "bbox": [362.0, 236.5, 210.9, 131.1], "category_id": 1}], "reactions": [{"reactants": [2, 3], "conditions": [1], "products": [4, 0]}, {"reactants": [5, 8], "conditions": [], "products": [7, 6]}], "caption": "Figure 2. Reaction scheme for in situ epoxidation with peracetic acid.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 946, 784, 960], "ImageBB": [448, 829, 787, 937]}, "diagram_type": "multiple"}, {"id": 1374, "width": 1752, "height": 1960, "file_name": "ol501424f-Figure-c3.png", "license": 0, "bboxes": [{"id": 5, "bbox": [187.1, 960.8, 259.4, 129.1], "category_id": 1}, {"id": 6, "bbox": [489.1, 931.6, 269.0, 135.7], "category_id": 1}, {"id": 7, "bbox": [1018.1, 883.1, 315.2, 213.4], "category_id": 1}, {"id": 8, "bbox": [941.6, 1341.6, 393.9, 210.8], "category_id": 1}, {"id": 9, "bbox": [188.5, 1354.1, 298.3, 184.3], "category_id": 1}], "reactions": [{"reactants": [12, 13], "conditions": [5, 17], "products": [14]}, {"reactants": [14], "conditions": [10], "products": [15]}, {"reactants": [15], "conditions": [3, 4], "products": [16]}], "caption": "Figure 3. (Top) Blown-up orbital interactions of diene and dienophile in the inverse demand Diels\u2212Alder. (Bottom) HOMO\u2212LUMO interaction diagram of the reactants. ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 592, 784, 634], "ImageBB": [421, 637, 859, 1127]}, "diagram_type": "tree"}, {"id": 1375, "width": 1352, "height": 696, "file_name": "ol500121z-Table-c1.png", "license": 0, "bboxes": [{"id": 2, "bbox": [808.0, 344.0, 456.0, 107.0], "category_id": 1}, {"id": 3, "bbox": [811.0, 5.0, 386.0, 183.0], "category_id": 1}, {"id": 5, "bbox": [84.0, 176.0, 287.0, 110.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [2, 8], "products": [4, 3]}], "caption": "Table 1. Palladium Catalysts for the Alkylation of 1a with 2aa ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 533, 775, 563], "ImageBB": [449, 569, 787, 743]}, "diagram_type": "single"}, {"id": 1376, "width": 1344, "height": 988, "file_name": "ol401535k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [38.0, 4.0, 425.0, 164.4], "category_id": 1}, {"id": 1, "bbox": [881.0, 4.0, 431.0, 163.9], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [5, 1], "products": [3]}], "caption": "Table 1. Optimization of C H Oxygenation with Carbamate 1aa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 264, 405, 280], "ImageBB": [71, 291, 407, 538]}, "diagram_type": "single"}, {"id": 1377, "width": 1344, "height": 676, "file_name": "ol034434l-Table-c1.png", "license": 0, "bboxes": [{"id": 1, "bbox": [270.3, 6.0, 280.7, 118.7], "category_id": 1}, {"id": 2, "bbox": [800.33, 9.9, 280.47, 116.01], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [5], "products": [3]}], "caption": "Table 1. Reduction of N,N-Dibenzylhydroxylamine (1) with Indium Metal ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 437, 392, 465], "ImageBB": [74, 471, 410, 640]}, "diagram_type": "single"}, {"id": 1378, "width": 1348, "height": 1080, "file_name": "jo991283k-Table-c1.png", "license": 0, "bboxes": [{"id": 3, "bbox": [112.0, 0.0, 196.0, 137.0], "category_id": 1}, {"id": 4, "bbox": [1064.0, 0.0, 184.1, 137.0], "category_id": 1}, {"id": 5, "bbox": [583.0, 0.0, 186.0, 134.9], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [], "products": [3]}, {"reactants": [6], "conditions": [], "products": [4]}], "caption": "Table 1. Reduction of Methyl Ketones and          Trifluoromethyl Ketonesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [481, 64, 733, 89], "ImageBB": [439, 94, 776, 364]}, "diagram_type": "single"}, {"id": 1379, "width": 1356, "height": 1308, "file_name": "jo201478d-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [66.5, 346.0, 427.5, 258.0], "category_id": 1}, {"id": 7, "bbox": [905.0, 1025.0, 317.0, 193.0], "category_id": 1}, {"id": 8, "bbox": [543.0, 1025.2, 376.0, 196.8], "category_id": 1}, {"id": 9, "bbox": [123.0, 1029.0, 435.0, 153.7], "category_id": 1}, {"id": 10, "bbox": [770.0, 750.0, 237.0, 136.0], "category_id": 1}, {"id": 11, "bbox": [801.0, 331.0, 396.5, 249.2], "category_id": 1}, {"id": 13, "bbox": [960.0, 59.5, 382.7, 203.0], "category_id": 1}, {"id": 14, "bbox": [450.5, 90.3, 143.3, 133.8], "category_id": 1}, {"id": 15, "bbox": [9.0, 61.0, 399.7, 202.2], "category_id": 1}, {"id": 19, "bbox": [53.0, 734.0, 200.0, 177.0], "category_id": 1}, {"id": 20, "bbox": [288.0, 707.0, 415.0, 204.0], "category_id": 1}, {"id": 21, "bbox": [1052.0, 719.0, 284.0, 190.0], "category_id": 1}], "reactions": [{"reactants": [20, 19], "conditions": [8], "products": [18]}, {"reactants": [0], "conditions": [9], "products": [16]}, {"reactants": [16], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [24, 25]}, {"reactants": [24, 25], "conditions": [], "products": [0]}, {"reactants": [16], "conditions": [], "products": [15, 26]}, {"reactants": [15, 26], "conditions": [], "products": [16]}], "caption": "Table 4. E\ufb00ects of Additives on the Addition/ISMS Reaction Sequence ", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 482, 771, 512], "ImageBB": [436, 133, 775, 460]}, "diagram_type": "tree"}, {"id": 1380, "width": 1352, "height": 660, "file_name": "ol701624y-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [853.0, 27.0, 409.0, 211.0], "category_id": 1}, {"id": 3, "bbox": [85.14, 19.86, 385.0, 219.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [6, 5], "products": [2]}], "caption": "Table 2.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 798, 120, 811], "ImageBB": [73, 814, 411, 979]}, "diagram_type": "single"}, {"id": 1381, "width": 1352, "height": 1536, "file_name": "acs.joc.6b00020-Table-c1.png", "license": 0, "bboxes": [{"id": 2, "bbox": [0.0, 1072.0, 408.0, 307.0], "category_id": 1}, {"id": 3, "bbox": [406.0, 1071.0, 399.0, 300.0], "category_id": 1}, {"id": 4, "bbox": [887.0, 0.0, 394.0, 286.0], "category_id": 1}, {"id": 6, "bbox": [872.0, 696.0, 410.0, 290.0], "category_id": 1}, {"id": 7, "bbox": [408.0, 692.0, 410.0, 303.0], "category_id": 1}, {"id": 8, "bbox": [4.0, 686.0, 391.0, 325.0], "category_id": 1}, {"id": 9, "bbox": [877.0, 313.0, 470.0, 298.0], "category_id": 1}, {"id": 10, "bbox": [410.0, 305.0, 482.0, 317.0], "category_id": 1}, {"id": 11, "bbox": [4.0, 310.0, 374.0, 250.0], "category_id": 1}, {"id": 14, "bbox": [550.0, 30.0, 183.0, 52.0], "category_id": 1}, {"id": 15, "bbox": [19.69, 36.0, 362.0, 217.0], "category_id": 1}, {"id": 22, "bbox": [868.0, 1070.9, 469.0, 346.1], "category_id": 1}], "reactions": [{"reactants": [17], "conditions": [14, 15, 16], "products": [4]}], "caption": "Table 1. [Co]-Catalyzed [2 + 2 + 2]-Cyclotrimerization Reaction of Diynes 2/2\u2032 with Various Alkynesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 233, 396, 263], "ImageBB": [82, 269, 420, 653]}, "diagram_type": "single"}, {"id": 1382, "width": 1352, "height": 600, "file_name": "acs.joc.5b00632-Figure-c1.png", "license": 0, "bboxes": [{"id": 2, "bbox": [836.0, 37.1, 373.0, 203.9], "category_id": 1}, {"id": 3, "bbox": [800.2, 416.4, 362.4, 133.6], "category_id": 1}, {"id": 6, "bbox": [125.7, 41.6, 359.0, 206.4], "category_id": 1}, {"id": 7, "bbox": [118.6, 294.8, 469.2, 247.5], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [8], "products": [2]}], "caption": "Figure 1. Thiophenopyridine antiplatelet agents.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 804, 318, 818], "ImageBB": [82, 645, 420, 795]}, "diagram_type": "single"}, {"id": 1383, "width": 1352, "height": 572, "file_name": "ja905415r-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [750.81, 25.43, 360.29, 178.99], "category_id": 1}, {"id": 1, "bbox": [536.7, 11.62, 261.87, 254.09], "category_id": 1}, {"id": 2, "bbox": [50.64, 4.71, 306.76, 237.69], "category_id": 1}, {"id": 7, "bbox": [992.55, 105.72, 301.58, 199.71], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [0, 2], "products": [4, 3, 10]}], "caption": "Table 6. Gold-Catalyzed Cycloadditions of 1c in the Presence of MeOHa ", "pdf": {"Page": 7, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 565, 382, 589], "ImageBB": [58, 597, 396, 740]}, "diagram_type": "single"}, {"id": 1384, "width": 1352, "height": 948, "file_name": "ja402810t-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [746.48, 589.9, 218.02, 194.7], "category_id": 1}, {"id": 1, "bbox": [7.56, 139.43, 563.91, 308.49], "category_id": 1}, {"id": 2, "bbox": [682.33, 137.05, 562.72, 307.31], "category_id": 1}, {"id": 3, "bbox": [12.31, 507.7, 588.86, 308.49], "category_id": 1}, {"id": 4, "bbox": [1033.31, 528.63, 310.26, 304.51], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [1, 5]}], "caption": "Figure 2. Fragmentation patterns observed following CID of singly protonated PRAGS-derivatized (a) and FRAGS-derivatized (c) maltoheptaose and CID spectra of singly protonated PRAGS- derivatized (b) and FRAGS-derivatized (d) maltoheptaose. The parent ion refers to the protonated molecular ion. The possible fragmentation of the reducing terminus glycan subunit is not observed because of the low mass cuto\ufb00. ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 614, 417, 711], "ImageBB": [82, 716, 420, 953]}, "diagram_type": "multiple"}, {"id": 1385, "width": 1272, "height": 964, "file_name": "ja075824w-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [7.69, 19.36, 286.93, 221.66], "category_id": 1}, {"id": 1, "bbox": [925.24, 21.87, 339.65, 221.66], "category_id": 1}, {"id": 2, "bbox": [362.91, 107.22, 220.39, 52.21], "category_id": 1}], "reactions": [{"reactants": [2, 4], "conditions": [1, 0], "products": [3]}], "caption": "Figure 2. Solvent effect in the DMAP-catalyzed isobutyrylation of l-menthol. The reaction of l-menthol (5 mmol) was conducted with (i-PrCO)2O (5 mmol) in the presence of 1 (0.1 mol %) in solvent (5 mL): green circles, no solvent; red squares, heptane; blue triangles, THF; orange squares, CH3CN; black circles, CH2Cl2. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 610, 409, 673], "ImageBB": [83, 365, 401, 606]}, "diagram_type": "single"}, {"id": 1386, "width": 1348, "height": 1320, "file_name": "ja011003u-Table-c2.png", "license": 0, "bboxes": [{"id": 3, "bbox": [6.33, 7.47, 577.72, 293.65], "category_id": 1}, {"id": 4, "bbox": [761.97, 505.54, 575.83, 363.73], "category_id": 1}, {"id": 5, "bbox": [57.46, 825.6, 539.85, 388.34], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [5]}], "caption": "Table 2. Experimental and Calculated (DFT) 13C NMR Spectra", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 466, 756, 480], "ImageBB": [440, 125, 777, 455]}, "diagram_type": "tree"}, {"id": 1387, "width": 1348, "height": 432, "file_name": "op500334b-Table-c3.png", "license": 0, "bboxes": [{"id": 2, "bbox": [30.0, 0.0, 352.0, 278.0], "category_id": 1}, {"id": 3, "bbox": [805.0, 0.0, 512.0, 286.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [1, 0], "products": [5]}], "caption": "Table 3. Optimization of the base", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 274, 110], "ImageBB": [82, 116, 419, 224]}, "diagram_type": "single"}, {"id": 1388, "width": 1352, "height": 788, "file_name": "op0340816-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.2, 303.7, 226.7, 187.5], "category_id": 1}, {"id": 1, "bbox": [8.5, 538.0, 253.6, 183.9], "category_id": 1}, {"id": 2, "bbox": [42.4, 6.0, 245.6, 221.4], "category_id": 1}, {"id": 4, "bbox": [448.39, 310.94, 285.21, 180.06], "category_id": 1}], "reactions": [{"reactants": [10], "conditions": [5, 9], "products": [13]}, {"reactants": [2], "conditions": [12, 11], "products": [15]}, {"reactants": [15], "conditions": [18, 3], "products": [6]}, {"reactants": [6], "conditions": [0, 1, 8, 4, 16], "products": [7]}], "caption": "Figure 3. Attempts to extend the methodology to tetrachlo- robenzenes. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 253, 409, 281], "ImageBB": [74, 53, 412, 250]}, "diagram_type": "multiple"}, {"id": 1389, "width": 1348, "height": 1044, "file_name": "op0256183-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [42.0, 16.0, 372.0, 125.0], "category_id": 1}, {"id": 1, "bbox": [942.0, 12.0, 378.0, 136.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [3, 1], "products": [4]}], "caption": "Table 1. Effect of reduced precatalyst loadings", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 444, 698, 458], "ImageBB": [439, 462, 776, 723]}, "diagram_type": "single"}, {"id": 1390, "width": 1352, "height": 1196, "file_name": "ol802669r-Table-c1.png", "license": 0, "bboxes": [{"id": 2, "bbox": [63.0, 56.0, 301.0, 208.0], "category_id": 1}, {"id": 3, "bbox": [938.0, 69.0, 351.0, 167.2], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [4, 6], "products": [5]}], "caption": "Table 1. Optimization of the Pd(0)-Catalyzed Cyclopropane Ring-Expansion Reaction of 1ba ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 75, 369, 102], "ImageBB": [58, 111, 396, 410]}, "diagram_type": "single"}, {"id": 1391, "width": 1344, "height": 1332, "file_name": "ol3023903-Figure-c2.png", "license": 0, "bboxes": [{"id": 3, "bbox": [198.9, 815.9, 404.0, 282.0], "category_id": 1}, {"id": 5, "bbox": [258.0, 161.7, 286.9, 207.3], "category_id": 1}, {"id": 6, "bbox": [878.1, 207.7, 164.2, 156.6], "category_id": 1}, {"id": 7, "bbox": [641.4, 443.9, 565.9, 271.5], "category_id": 1}, {"id": 8, "bbox": [603.0, 163.4, 172.4, 108.7], "category_id": 1}, {"id": 9, "bbox": [796.7, 782.3, 329.0, 252.4], "category_id": 1}, {"id": 11, "bbox": [136.0, 426.7, 499.0, 260.3], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [10, 2], "products": [8]}], "caption": "Figure 2. Synthesis of trifluoromethyl olefins via strategy A.", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 1007, 756, 1020], "ImageBB": [437, 661, 773, 994]}, "diagram_type": "single"}, {"id": 1392, "width": 1348, "height": 1092, "file_name": "ol202499g-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [137.4, 55.6, 101.6, 137.4], "category_id": 1}, {"id": 1, "bbox": [884.0, 33.9, 293.5, 200.6], "category_id": 1}, {"id": 3, "bbox": [645.2, 143.2, 172.4, 145.4], "category_id": 1}, {"id": 4, "bbox": [322.0, 94.0, 143.0, 62.0], "category_id": 1}], "reactions": [{"reactants": [0, 4], "conditions": [12, 5, 10, 3], "products": [1]}], "caption": "Table 3. Tandem Cyanation Allylic Alkylation Reaction with MBH Adductsa ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 536, 770, 563], "ImageBB": [436, 574, 773, 847]}, "diagram_type": "single"}, {"id": 1393, "width": 1416, "height": 908, "file_name": "ol1018773-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [370.7, 669.2, 458.6, 147.9], "category_id": 1}, {"id": 4, "bbox": [121.7, 218.3, 452.3, 330.7], "category_id": 1}, {"id": 5, "bbox": [870.5, 220.6, 490.2, 340.7], "category_id": 1}, {"id": 6, "bbox": [1010.3, 690.6, 350.6, 172.4], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [0, 6]}], "caption": "Figure 1. Retrosynthesis of 1 highlighting the chirons from stereoselective hydrogenations. ", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 834, 760, 862], "ImageBB": [408, 600, 762, 827]}, "diagram_type": "multiple"}, {"id": 1394, "width": 1352, "height": 1232, "file_name": "op500072b-Table-c3.png", "license": 0, "bboxes": [{"id": 2, "bbox": [298.0, 822.0, 907.0, 410.0], "category_id": 1}, {"id": 3, "bbox": [0.0, 379.0, 897.0, 423.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [6, 2], "products": [4]}], "caption": "Table 3. Selective O-alkylation of triol 14", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 243, 317, 258], "ImageBB": [82, 265, 420, 573]}, "diagram_type": "multiple"}, {"id": 1395, "width": 1344, "height": 1116, "file_name": "op200174k-Table-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [356.5, 56.5, 265.0, 171.5], "category_id": 1}, {"id": 2, "bbox": [953.0, 44.5, 366.0, 203.0], "category_id": 1}, {"id": 3, "bbox": [25.4, 2.0, 284.6, 196.5], "category_id": 1}], "reactions": [{"reactants": [6, 3], "conditions": [2, 1], "products": [5]}], "caption": "Table 8. E\ufb00ect of Added Tertiary Amine Base on Model Reaction Performancea ", "pdf": {"Page": 7, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 750, 122], "ImageBB": [437, 133, 773, 412]}, "diagram_type": "single"}, {"id": 1396, "width": 1344, "height": 548, "file_name": "op200011x-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [49.3, 82.2, 223.6, 175.8], "category_id": 1}, {"id": 5, "bbox": [1069.1, 77.0, 233.3, 237.7], "category_id": 1}, {"id": 6, "bbox": [702.3, 80.1, 257.3, 205.6], "category_id": 1}, {"id": 7, "bbox": [375.1, 5.0, 241.9, 134.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [8], "products": [7, 6]}], "caption": "Table 1", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 481, 115, 496], "ImageBB": [71, 521, 407, 658]}, "diagram_type": "single"}, {"id": 1397, "width": 1356, "height": 2456, "file_name": "op100104z-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [734.0, 415.8, 502.0, 510.2], "category_id": 1}, {"id": 9, "bbox": [0.0, 95.5, 228.0, 254.5], "category_id": 1}, {"id": 10, "bbox": [398.0, 108.5, 214.7, 246.5], "category_id": 1}, {"id": 11, "bbox": [768.0, 103.6, 266.5, 253.4], "category_id": 1}, {"id": 12, "bbox": [38.0, 436.9, 550.1, 520.1], "category_id": 1}, {"id": 13, "bbox": [52.8, 1137.0, 410.7, 345.0], "category_id": 1}, {"id": 14, "bbox": [542.9, 1120.0, 259.5, 248.6], "category_id": 1}, {"id": 15, "bbox": [827.5, 985.0, 528.5, 519.2], "category_id": 1}], "reactions": [{"reactants": [15], "conditions": [5], "products": [16]}, {"reactants": [16], "conditions": [1], "products": [17]}, {"reactants": [17], "conditions": [0], "products": [19]}, {"reactants": [19], "conditions": [18], "products": [2]}], "caption": "Figure 1. 6-[(5S,9R)-9-(4-Cyanophenyl)-3-(3,5-dichlorophenyl)- 1-methyl-2,4-dioxo-1,3,7-triazaspiro[4.4]non-7-yl]nicotinic acid. ", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 372, 761, 399], "ImageBB": [424, 424, 763, 1038]}, "diagram_type": "multiple"}, {"id": 1398, "width": 1344, "height": 1784, "file_name": "ol0616236-Table-c1.png", "license": 0, "bboxes": [{"id": 11, "bbox": [877.2, 314.5, 187.0, 154.3], "category_id": 1}, {"id": 12, "bbox": [651.8, 337.1, 186.8, 126.1], "category_id": 1}, {"id": 13, "bbox": [451.0, 319.9, 145.1, 164.7], "category_id": 1}, {"id": 14, "bbox": [83.0, 356.7, 216.2, 111.5], "category_id": 1}, {"id": 15, "bbox": [316.2, 359.7, 140.0, 105.0], "category_id": 1}, {"id": 16, "bbox": [93.3, 504.6, 134.1, 163.0], "category_id": 1}, {"id": 17, "bbox": [244.8, 499.6, 180.2, 187.6], "category_id": 1}, {"id": 18, "bbox": [435.6, 522.5, 220.6, 118.3], "category_id": 1}, {"id": 20, "bbox": [90.3, 25.3, 454.7, 241.7], "category_id": 1}, {"id": 21, "bbox": [647.3, 0.0, 149.6, 133.2], "category_id": 1}, {"id": 22, "bbox": [1059.8, 341.6, 201.9, 112.4], "category_id": 1}, {"id": 23, "bbox": [928.6, 16.3, 327.8, 180.6], "category_id": 1}, {"id": 24, "bbox": [937.0, 524.6, 145.6, 113.8], "category_id": 1}], "reactions": [{"reactants": [22], "conditions": [23, 25], "products": [27]}], "caption": "Table 1. Mild Synthesis of R-Fluoro Acrylates", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 440, 324, 457], "ImageBB": [74, 465, 410, 911]}, "diagram_type": "single"}, {"id": 1399, "width": 1352, "height": 720, "file_name": "ol053021c-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [863.8, 156.5, 295.8, 211.1], "category_id": 1}, {"id": 1, "bbox": [1044.0, 429.1, 238.9, 210.9], "category_id": 1}, {"id": 7, "bbox": [315.1, 429.0, 272.9, 207.9], "category_id": 1}, {"id": 8, "bbox": [562.4, 429.2, 216.6, 212.8], "category_id": 1}, {"id": 9, "bbox": [790.1, 430.2, 235.9, 209.7], "category_id": 1}, {"id": 10, "bbox": [107.2, 162.0, 208.3, 212.3], "category_id": 1}, {"id": 13, "bbox": [75.2, 432.0, 231.8, 207.9], "category_id": 1}], "reactions": [{"reactants": [12], "conditions": [11, 10], "products": [0]}], "caption": "Figure 2. Relative reactivity of (NR)-indoles.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 243, 680, 256], "ImageBB": [439, 51, 777, 231]}, "diagram_type": "single"}, {"id": 1400, "width": 1352, "height": 996, "file_name": "ol051901l-Table-c1.png", "license": 0, "bboxes": [{"id": 2, "bbox": [67.0, 22.0, 336.0, 238.0], "category_id": 1}, {"id": 3, "bbox": [949.0, 23.0, 338.0, 242.0], "category_id": 1}], "reactions": [{"reactants": [3, 7], "conditions": [], "products": [5]}, {"reactants": [3, 8], "conditions": [], "products": [5]}], "caption": "Table 1. Reaction of Amidine 3a with Acetals 4 and 5 Leading to the Trisubstituted Pyrimidine 6aa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 522, 732, 550], "ImageBB": [439, 560, 777, 809]}, "diagram_type": "single"}, {"id": 1401, "width": 1252, "height": 928, "file_name": "jo011082s-Table-c2.png", "license": 0, "bboxes": [{"id": 5, "bbox": [388.2, 315.3, 274.1, 183.0], "category_id": 1}, {"id": 6, "bbox": [2.0, 224.5, 356.9, 194.9], "category_id": 1}, {"id": 7, "bbox": [740.3, 572.0, 274.9, 199.0], "category_id": 1}, {"id": 8, "bbox": [686.4, 201.4, 339.5, 173.8], "category_id": 1}, {"id": 9, "bbox": [259.2, 582.7, 321.8, 193.2], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [11, 12, 6], "products": [9]}, {"reactants": [9], "conditions": [], "products": [10, 8]}], "caption": "Table 2. 1,3-Dienes 10 and 11", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [520, 279, 695, 291], "ImageBB": [464, 35, 777, 267]}, "diagram_type": "multiple"}, {"id": 1402, "width": 1352, "height": 564, "file_name": "jo0109321-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [10.0, 78.0, 513.0, 68.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [4, 3, 2, 0], "products": [5, 6, 8]}], "caption": "Table 1. Effect of Solvent on the Regioselectivity of the  RhCl3\u201anH2O-Promoted Hydroboration of 1-Octene with                        BH3-THFa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [443, 64, 771, 102], "ImageBB": [439, 111, 777, 252]}, "diagram_type": "single"}, {"id": 1403, "width": 1352, "height": 1000, "file_name": "acs.orglett.5b03589-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [851.0, 27.0, 174.0, 155.0], "category_id": 1}, {"id": 5, "bbox": [354.0, 741.0, 285.0, 124.0], "category_id": 1}, {"id": 6, "bbox": [720.0, 520.0, 206.0, 159.0], "category_id": 1}, {"id": 8, "bbox": [598.0, 134.0, 228.0, 126.0], "category_id": 1}, {"id": 10, "bbox": [352.0, 529.0, 195.0, 107.7], "category_id": 1}, {"id": 11, "bbox": [727.6, 713.0, 292.4, 153.1], "category_id": 1}, {"id": 12, "bbox": [343.0, 62.4, 140.0, 112.6], "category_id": 1}], "reactions": [{"reactants": [18], "conditions": [12, 15, 10, 13, 9], "products": [0]}], "caption": "Table 3. Scope of the Tandem Coupling/Cyclization Reactions with Alkyl Substituted Carboxylic Acids ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 141, 373, 171], "ImageBB": [82, 178, 420, 428]}, "diagram_type": "single"}, {"id": 1404, "width": 1356, "height": 1052, "file_name": "acs.orglett.5b00805-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [48.7, 39.2, 325.3, 219.8], "category_id": 1}, {"id": 1, "bbox": [392.0, 73.6, 193.0, 109.4], "category_id": 1}, {"id": 4, "bbox": [932.0, 6.0, 378.0, 251.0], "category_id": 1}], "reactions": [{"reactants": [1, 2], "conditions": [0, 3], "products": [7]}], "caption": "Table 2. Enantioselective Addition of Cumene Hydroperoxide 2a to Various Ketimines 1a,d\u2212m Using 4e ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 401, 777, 431], "ImageBB": [448, 437, 787, 700]}, "diagram_type": "single"}, {"id": 1405, "width": 1172, "height": 940, "file_name": "acs.orglett.5b00663-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [181.0, 849.5, 285.0, 85.5], "category_id": 1}, {"id": 1, "bbox": [187.0, 730.0, 185.9, 98.5], "category_id": 1}, {"id": 2, "bbox": [584.0, 743.0, 120.0, 71.9], "category_id": 1}, {"id": 3, "bbox": [579.6, 880.4, 147.2, 38.2], "category_id": 1}, {"id": 6, "bbox": [578.0, 620.0, 111.0, 88.0], "category_id": 1}, {"id": 7, "bbox": [581.0, 523.0, 131.0, 58.0], "category_id": 1}, {"id": 8, "bbox": [570.0, 433.0, 162.0, 57.0], "category_id": 1}, {"id": 9, "bbox": [573.0, 331.0, 154.0, 57.0], "category_id": 1}, {"id": 10, "bbox": [571.0, 243.0, 161.0, 53.0], "category_id": 1}, {"id": 11, "bbox": [184.0, 617.0, 139.0, 88.0], "category_id": 1}, {"id": 12, "bbox": [183.0, 515.0, 206.0, 71.0], "category_id": 1}, {"id": 13, "bbox": [189.0, 416.0, 222.0, 77.0], "category_id": 1}, {"id": 14, "bbox": [192.0, 321.0, 222.0, 78.0], "category_id": 1}, {"id": 15, "bbox": [183.0, 219.0, 240.0, 80.0], "category_id": 1}, {"id": 29, "bbox": [132.0, 13.0, 155.0, 58.0], "category_id": 1}], "reactions": [{"reactants": [34], "conditions": [32, 1, 0], "products": [35]}], "caption": "Table 4. Substrate Scope for the Debenzylation Reactiona", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 403, 109], "ImageBB": [104, 116, 397, 351]}, "diagram_type": "single"}, {"id": 1406, "width": 1356, "height": 1144, "file_name": "acs.oprd.6b00180-Table-c3.png", "license": 0, "bboxes": [{"id": 2, "bbox": [0.0, 65.0, 288.1, 160.2], "category_id": 1}, {"id": 3, "bbox": [380.6, 75.6, 249.4, 146.1], "category_id": 1}, {"id": 4, "bbox": [989.0, 0.0, 362.0, 237.0], "category_id": 1}], "reactions": [{"reactants": [2, 3], "conditions": [4, 5], "products": [7]}], "caption": "Table 3. Screening Conditions for 100 mL Scale Pd(OAc)2 Catalyzed Suzuki Reaction of 4-Bromoanisole (1) and PhB(OH)2 in H2Oa ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 363, 783, 408], "ImageBB": [448, 414, 787, 700]}, "diagram_type": "single"}, {"id": 1407, "width": 2816, "height": 456, "file_name": "acs.oprd.5b00370-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1645.5, 0.0, 441.5, 352.6], "category_id": 1}, {"id": 3, "bbox": [722.0, 2.0, 437.0, 352.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [4, 1], "products": [0]}], "caption": "Table 5. Batch Experiments for the Reduction of Thebaine Using p-Toluenesulfonyl Hydrazidea", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 624, 111], "ImageBB": [82, 116, 786, 230]}, "diagram_type": "single"}, {"id": 1408, "width": 1356, "height": 1336, "file_name": "ol051245p-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 349.0, 845.0, 986.0], "category_id": 1}, {"id": 1, "bbox": [968.9, 319.6, 225.4, 364.0], "category_id": 1}, {"id": 2, "bbox": [859.4, 674.8, 496.6, 661.2], "category_id": 1}, {"id": 3, "bbox": [1016.8, 139.1, 266.7, 177.5], "category_id": 1}, {"id": 4, "bbox": [572.7, 141.9, 297.1, 192.5], "category_id": 1}, {"id": 5, "bbox": [246.8, 151.0, 224.8, 143.5], "category_id": 1}, {"id": 6, "bbox": [36.3, 166.0, 193.7, 164.6], "category_id": 1}, {"id": 7, "bbox": [883.0, 204.33, 97.3, 47.3], "category_id": 1}], "reactions": [{"reactants": [9, 8], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [10], "products": [6]}], "caption": "Figure 1. Synthesis and structure of uridopyrimidine dendimers 1-3. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 398, 409, 425], "ImageBB": [73, 52, 412, 386]}, "diagram_type": "single"}, {"id": 1409, "width": 1344, "height": 916, "file_name": "ol050791f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [10.0, 19.0, 231.5, 186.4], "category_id": 1}, {"id": 3, "bbox": [376.0, 42.0, 227.0, 144.0], "category_id": 1}, {"id": 4, "bbox": [1029.0, 0.0, 301.0, 228.0], "category_id": 1}], "reactions": [{"reactants": [0, 6], "conditions": [1, 2], "products": [7]}], "caption": "Table 1. Preparation of Fluorinated \u03b3-Amino Alcohols 2 from Propanal and Aldimines 1 ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 259, 403, 288], "ImageBB": [74, 292, 410, 521]}, "diagram_type": "single"}, {"id": 1410, "width": 1348, "height": 1708, "file_name": "jo951899j-Table-c7.png", "license": 0, "bboxes": [{"id": 1, "bbox": [747.7, 378.4, 442.9, 230.2], "category_id": 1}, {"id": 2, "bbox": [708.0, 108.0, 234.0, 192.7], "category_id": 1}, {"id": 3, "bbox": [741.6, 713.6, 446.5, 243.7], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [0, 17, 13], "products": [19, 12]}, {"reactants": [10], "conditions": [9, 3, 14], "products": [11]}, {"reactants": [2], "conditions": [4, 6, 5], "products": [15]}], "caption": "Table 7. Removal of the Saccharide Protecting Groups", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [68, 402, 393, 414], "ImageBB": [63, 423, 400, 850]}, "diagram_type": "multiple"}, {"id": 1411, "width": 2820, "height": 936, "file_name": "jo4027148-Figure-c3.png", "license": 0, "bboxes": [{"id": 4, "bbox": [366.8, 41.0, 343.2, 351.0], "category_id": 1}, {"id": 6, "bbox": [1274.3, 118.5, 346.7, 200.7], "category_id": 1}, {"id": 10, "bbox": [867.9, 592.5, 328.1, 236.2], "category_id": 1}, {"id": 11, "bbox": [372.0, 619.0, 166.0, 177.7], "category_id": 1}, {"id": 12, "bbox": [2119.1, 46.8, 327.0, 340.2], "category_id": 1}, {"id": 13, "bbox": [52.0, 596.0, 244.0, 233.0], "category_id": 1}, {"id": 14, "bbox": [1331.0, 592.0, 363.0, 241.0], "category_id": 1}, {"id": 15, "bbox": [1753.0, 599.0, 244.0, 221.0], "category_id": 1}, {"id": 16, "bbox": [2272.0, 555.0, 493.0, 315.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [5, 27], "products": [9]}, {"reactants": [9], "conditions": [6, 26], "products": [15]}, {"reactants": [16, 14], "conditions": [24, 23], "products": [13]}, {"reactants": [17, 18], "conditions": [22, 0], "products": [19]}], "caption": "Figure 3. Examples of (A) solid-state photochemistry and (B) photoredox-catalyzed [2 + 2] cycloadditions.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 870, 605, 884], "ImageBB": [82, 627, 787, 861]}, "diagram_type": "multiple"}, {"id": 1412, "width": 2820, "height": 664, "file_name": "jo401195c-Table-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1166.0, 6.4, 360.0, 254.6], "category_id": 1}, {"id": 1, "bbox": [473.0, 94.6, 215.6, 174.0], "category_id": 1}, {"id": 2, "bbox": [1983.6, 4.3, 388.4, 340.7], "category_id": 1}, {"id": 7, "bbox": [1586.0, 101.0, 290.0, 148.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [3, 2], "products": [0, 16, 4]}], "caption": "Table 8. KR of trans-Cyclohexane-1,2-diol 1 with Boc2O using Various Reaction Conditions", "pdf": {"Page": 10, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 300, 600, 320], "ImageBB": [82, 131, 787, 297]}, "diagram_type": "single"}, {"id": 1413, "width": 1352, "height": 420, "file_name": "acs.joc.5b00302-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [920.7, 4.0, 431.3, 327.0], "category_id": 1}, {"id": 2, "bbox": [2.0, 80.0, 374.0, 170.0], "category_id": 1}, {"id": 3, "bbox": [431.0, 24.0, 245.0, 264.0], "category_id": 1}], "reactions": [{"reactants": [3, 4], "conditions": [1, 6], "products": [0]}], "caption": "Table 2. Reaction with Low Catalyst Loadinga", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 712, 110], "ImageBB": [448, 116, 786, 221]}, "diagram_type": "single"}, {"id": 1414, "width": 1356, "height": 500, "file_name": "jacs.5b05415-Figure-c6.png", "license": 0, "bboxes": [{"id": 1, "bbox": [715.81, 274.38, 299.01, 167.38], "category_id": 1}, {"id": 2, "bbox": [18.76, 293.43, 239.24, 128.42], "category_id": 1}, {"id": 3, "bbox": [724.47, 55.3, 299.01, 170.86], "category_id": 1}, {"id": 4, "bbox": [17.03, 57.9, 238.39, 166.52], "category_id": 1}, {"id": 6, "bbox": [1089.88, 276.11, 229.73, 165.65], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [4, 3], "products": [7]}, {"reactants": [6], "conditions": [2, 1], "products": [5, 10]}], "caption": "Figure 6. Achieving cyclization via synergistic catalysis.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 356, 711, 370], "ImageBB": [448, 222, 787, 347]}, "diagram_type": "multiple"}, {"id": 1415, "width": 1224, "height": 1636, "file_name": "ja960062i-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [137.12, 1363.8, 660.62, 265.87], "category_id": 1}, {"id": 1, "bbox": [445.32, 895.16, 654.29, 434.75], "category_id": 1}, {"id": 2, "bbox": [27.35, 570.08, 329.2, 175.09], "category_id": 1}, {"id": 3, "bbox": [626.86, 154.21, 441.08, 434.75], "category_id": 1}, {"id": 4, "bbox": [413.65, 240.76, 215.21, 97.0], "category_id": 1}, {"id": 5, "bbox": [10.46, 122.55, 348.2, 394.64], "category_id": 1}, {"id": 6, "bbox": [93.2, 996.49, 335.12, 107.55], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [5, 7], "products": [6]}, {"reactants": [8], "conditions": [0, 9, 1], "products": [3]}], "caption": "Figure 1. Scheme for coupling CPP with amino-derivatized oligo- nucleotides via an amide bond. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 435, 774, 461], "ImageBB": [469, 21, 775, 430]}, "diagram_type": "multiple"}, {"id": 1416, "width": 1352, "height": 1396, "file_name": "ja9039289-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [647.06, 100.73, 254.18, 111.88], "category_id": 1}, {"id": 1, "bbox": [23.82, 98.93, 201.98, 110.08], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [1, 0], "products": [4, 3, 2]}], "caption": "Table 2. Screening of Cobalt and Nickel Salts in the Presence of Various NHC Ligands ", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 57, 384, 81], "ImageBB": [58, 89, 396, 438]}, "diagram_type": "single"}, {"id": 1417, "width": 1352, "height": 1820, "file_name": "ja408733f-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [523.35, 309.95, 305.23, 242.6], "category_id": 1}, {"id": 1, "bbox": [522.59, 689.56, 344.18, 377.03], "category_id": 1}, {"id": 2, "bbox": [690.63, 565.06, 167.74, 118.86], "category_id": 1}, {"id": 3, "bbox": [460.72, 565.06, 167.75, 118.86], "category_id": 1}, {"id": 4, "bbox": [25.36, 225.93, 305.23, 327.38], "category_id": 1}, {"id": 5, "bbox": [1015.24, 206.07, 305.23, 346.48], "category_id": 1}, {"id": 6, "bbox": [391.22, 2.9, 519.85, 152.47], "category_id": 1}, {"id": 7, "bbox": [29.53, 1144.91, 1292.75, 668.44], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [2], "products": [10]}, {"reactants": [1], "conditions": [5], "products": [9]}, {"reactants": [9], "conditions": [0], "products": [1]}, {"reactants": [1], "conditions": [3], "products": [11]}, {"reactants": [11], "conditions": [4], "products": [1]}, {"reactants": [1], "conditions": [8], "products": [6]}, {"reactants": [6], "conditions": [7], "products": [1]}], "caption": "Figure 2. Molecular structure of [\u03ba4-Tptm]ZnF\u00b7H2O.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 578, 338, 595], "ImageBB": [82, 116, 420, 571]}, "diagram_type": "tree"}, {"id": 1418, "width": 2264, "height": 1024, "file_name": "ja012741l-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [16.0, 74.3, 1442.33, 840.6], "category_id": 1}, {"id": 3, "bbox": [1861.0, 510.93, 393.36, 214.99], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [3, 4], "products": [5]}], "caption": "Figure 1. Structure of bleomycin A2, and conversion to catabolite deamido BLM A2 via the action of bleomycin hydrolase.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 331, 644, 344], "ImageBB": [142, 68, 708, 324]}, "diagram_type": "single"}, {"id": 1419, "width": 1340, "height": 2044, "file_name": "op800177x-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [266.2, 1424.9, 816.2, 500.1], "category_id": 1}, {"id": 1, "bbox": [124.3, 91.6, 470.0, 383.0], "category_id": 1}, {"id": 2, "bbox": [875.37, 89.2, 457.5, 385.8], "category_id": 1}, {"id": 3, "bbox": [140.9, 734.3, 454.3, 376.0], "category_id": 1}, {"id": 5, "bbox": [870.6, 736.4, 467.8, 375.5], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [], "products": [2]}, {"reactants": [3], "conditions": [], "products": [5]}], "caption": "Figure 1. Structure of the hydrogenation catalyst RuCl2[(S)- Xyl-P-Phos][(S)-DAIPEN] 9. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 559, 393, 586], "ImageBB": [59, 45, 394, 556]}, "diagram_type": "multiple"}, {"id": 1420, "width": 876, "height": 240, "file_name": "op700060e-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [552.6, 5.0, 323.4, 188.0], "category_id": 1}, {"id": 1, "bbox": [6.0, 0.0, 323.0, 156.0], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [1, 0], "products": [2]}], "caption": "Figure 2. Oxidation of 2 with concentrated sodium hypochlorite.", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 109, 394, 123], "ImageBB": [117, 46, 336, 106]}, "diagram_type": "single"}, {"id": 1421, "width": 1348, "height": 1260, "file_name": "ol8006106-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [71.37, 3.25, 503.13, 364.85], "category_id": 1}, {"id": 3, "bbox": [767.87, 2.38, 511.93, 363.82], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [], "products": [4]}], "caption": "Table 2. Conditions Tested for the Oxidative Cyclization of 8 as Well as the Yields of 9 in These Reactions ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 75, 746, 102], "ImageBB": [425, 111, 762, 426]}, "diagram_type": "single"}, {"id": 1422, "width": 1348, "height": 884, "file_name": "ol202395s-Table-c2.png", "license": 0, "bboxes": [{"id": 2, "bbox": [388.9, 31.0, 298.1, 210.1], "category_id": 1}, {"id": 3, "bbox": [955.4, 3.0, 376.6, 297.0], "category_id": 1}, {"id": 4, "bbox": [16.0, 3.0, 347.0, 254.0], "category_id": 1}], "reactions": [{"reactants": [7, 4], "conditions": [5, 3], "products": [6]}], "caption": "Table 2. Reaction of P-Alkynyl-\u03bb5-phosphazenes 4 and P- Alkynylphosphane Sulphide 5 with in-situ Generated Benzynea ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 771, 115], "ImageBB": [436, 126, 773, 347]}, "diagram_type": "single"}, {"id": 1423, "width": 1348, "height": 1180, "file_name": "ol202027k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [103.0, 71.0, 114.0, 141.0], "category_id": 1}, {"id": 1, "bbox": [1019.9, 0.0, 239.1, 309.0], "category_id": 1}, {"id": 3, "bbox": [551.1, 62.0, 319.9, 200.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [6, 5], "products": [4, 1]}], "caption": "Table 1. Screening of Metal Salts As Promoter of the Perkin  Acyl-Mannich Additiona ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 767, 114], "ImageBB": [436, 126, 773, 421]}, "diagram_type": "single"}, {"id": 1424, "width": 1344, "height": 1304, "file_name": "ol200849k-Table-c3.png", "license": 0, "bboxes": [{"id": 1, "bbox": [66.0, 15.0, 200.0, 168.0], "category_id": 1}, {"id": 2, "bbox": [302.0, 80.0, 231.0, 54.0], "category_id": 1}, {"id": 5, "bbox": [996.7, 14.0, 283.3, 228.8], "category_id": 1}], "reactions": [{"reactants": [2, 3], "conditions": [9, 8, 6, 7], "products": [10]}], "caption": "Table 3. CDC between Various Nitrones 1 and Alkynes 2 Using Oxidant 3 (15 mol %) and Dioxygen As Oxidants ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 405, 114], "ImageBB": [71, 126, 407, 452]}, "diagram_type": "single"}, {"id": 1425, "width": 3396, "height": 1520, "file_name": "op500221s-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2276.0, 337.1, 339.5, 266.7], "category_id": 1}, {"id": 1, "bbox": [1496.7, 390.0, 263.1, 217.0], "category_id": 1}, {"id": 4, "bbox": [746.0, 366.0, 258.0, 234.0], "category_id": 1}], "reactions": [{"reactants": [9], "conditions": [6, 11], "products": [1]}, {"reactants": [1], "conditions": [7, 10], "products": [0]}], "caption": "Figure 3. In situ IR monitoring of a series of shot-addition lithiation and borylation reactions at \u221265 \u00b0C.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 408, 587, 426], "ImageBB": [10, 22, 859, 402]}, "diagram_type": "single"}, {"id": 1426, "width": 1352, "height": 792, "file_name": "op3000042-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [596.1, 645.88, 281.9, 140.8], "category_id": 1}, {"id": 1, "bbox": [1081.5, 637.1, 249.8, 143.8], "category_id": 1}, {"id": 2, "bbox": [690.0, 532.2, 141.8, 46.8], "category_id": 1}, {"id": 3, "bbox": [588.7, 330.7, 189.5, 130.7], "category_id": 1}, {"id": 4, "bbox": [60.6, 322.9, 287.0, 123.1], "category_id": 1}, {"id": 5, "bbox": [889.1, 322.7, 186.2, 120.7], "category_id": 1}, {"id": 6, "bbox": [588.8, 17.7, 190.4, 133.0], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [6], "products": [4, 9]}, {"reactants": [4, 9], "conditions": [], "products": [8]}, {"reactants": [4], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [3], "products": [0]}, {"reactants": [0], "conditions": [], "products": [4]}, {"reactants": [0], "conditions": [7], "products": [2]}], "caption": "Figure 1. Proposed isobutylene/acetic acid/tert-butyl acetate equili- brium. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 550, 784, 578], "ImageBB": [448, 343, 786, 541]}, "diagram_type": "tree"}, {"id": 1427, "width": 2808, "height": 980, "file_name": "op2001047-Table-c6.png", "license": 0, "bboxes": [{"id": 3, "bbox": [1831.0, 0.0, 438.0, 227.0], "category_id": 1}, {"id": 4, "bbox": [1316.0, 0.0, 446.0, 230.0], "category_id": 1}, {"id": 5, "bbox": [524.0, 0.0, 455.0, 229.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [0, 6], "products": [5, 4]}], "caption": "Table 6. In\ufb02uence of catalyst, temperature, and \ufb02ow rate on the \ufb02ow hydrogenation of 4-aryl-3-buten-2-ones 1ba", "pdf": {"Page": 7, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 300, 694, 322], "ImageBB": [71, 330, 773, 575]}, "diagram_type": "single"}, {"id": 1428, "width": 2808, "height": 928, "file_name": "op2001047-Table-c4.png", "license": 0, "bboxes": [{"id": 2, "bbox": [437.3, 4.5, 343.7, 221.6], "category_id": 1}, {"id": 3, "bbox": [1156.5, 25.7, 433.7, 220.7], "category_id": 1}, {"id": 4, "bbox": [1627.9, 24.1, 743.5, 218.9], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [8, 7], "products": [4, 5]}], "caption": "Table 4. Reaction Optimization for the Microwave-assisted Aldol Reaction of p-Anisaldehyde (4b) with Acetonea", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 697, 109], "ImageBB": [71, 117, 773, 349]}, "diagram_type": "single"}, {"id": 1429, "width": 2808, "height": 824, "file_name": "op200052z-Table-c1.png", "license": 0, "bboxes": [{"id": 1, "bbox": [1449.0, 166.9, 548.6, 481.0], "category_id": 1}, {"id": 2, "bbox": [941.2, 286.5, 448.9, 225.5], "category_id": 1}, {"id": 3, "bbox": [271.9, 304.9, 394.2, 223.8], "category_id": 1}, {"id": 4, "bbox": [675.4, 238.1, 253.1, 180.4], "category_id": 1}, {"id": 5, "bbox": [2027.0, 0.0, 508.0, 652.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [5, 1], "products": [3, 2, 6]}], "caption": "Table 1. Carbonate base screen for the di\ufb02uoromethylation of 5a", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 432, 108], "ImageBB": [71, 117, 773, 323]}, "diagram_type": "single"}, {"id": 1430, "width": 2556, "height": 1176, "file_name": "op100108j-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 312.0, 546.0, 390.6], "category_id": 1}, {"id": 1, "bbox": [927.0, 776.6, 615.9, 382.1], "category_id": 1}, {"id": 7, "bbox": [692.9, 337.6, 563.4, 373.7], "category_id": 1}, {"id": 8, "bbox": [1330.22, 0.0, 619.0, 355.0], "category_id": 1}, {"id": 9, "bbox": [1933.0, 275.0, 623.0, 376.0], "category_id": 1}, {"id": 11, "bbox": [1618.0, 786.0, 619.0, 374.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [0], "products": [10]}, {"reactants": [9], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [14], "products": [10]}, {"reactants": [10], "conditions": [8], "products": [11]}, {"reactants": [2], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [2]}, {"reactants": [13], "conditions": [], "products": [11]}], "caption": "Figure 3. Proposed pathways for the formation of B-ring fission lactones from 1.", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 1009, 502, 1023], "ImageBB": [90, 711, 729, 1005]}, "diagram_type": "graph"}, {"id": 1431, "width": 1352, "height": 992, "file_name": "ol0604623-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [943.0, 1.0, 353.0, 273.0], "category_id": 1}, {"id": 1, "bbox": [95.0, 20.0, 322.0, 199.0], "category_id": 1}, {"id": 2, "bbox": [410.0, 32.0, 314.0, 179.0], "category_id": 1}], "reactions": [{"reactants": [0, 3, 4], "conditions": [5, 6], "products": [2]}], "caption": "Table 3. Synthesis of Fully Substituted Pyrazoles", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 786, 703, 799], "ImageBB": [439, 803, 777, 1051]}, "diagram_type": "single"}, {"id": 1432, "width": 1348, "height": 572, "file_name": "jo025690z-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [985.5, 5.0, 225.5, 199.6], "category_id": 1}, {"id": 4, "bbox": [274.0, 75.0, 140.0, 56.0], "category_id": 1}, {"id": 5, "bbox": [0.0, 32.0, 234.0, 141.0], "category_id": 1}], "reactions": [{"reactants": [7, 6], "conditions": [3, 8], "products": [0]}], "caption": "Table 3.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 620, 124, 634], "ImageBB": [75, 648, 412, 791]}, "diagram_type": "single"}, {"id": 1433, "width": 1348, "height": 1052, "file_name": "acs.orglett.6b01181-Table-c1.png", "license": 0, "bboxes": [{"id": 1, "bbox": [198.0, 19.0, 211.0, 227.0], "category_id": 1}, {"id": 3, "bbox": [481.0, 26.0, 61.8, 218.0], "category_id": 1}, {"id": 4, "bbox": [845.2, 3.0, 309.8, 245.0], "category_id": 1}], "reactions": [{"reactants": [1, 5], "conditions": [7, 2], "products": [6]}], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 349, 110], "ImageBB": [82, 116, 419, 379]}, "diagram_type": "single"}, {"id": 1434, "width": 1352, "height": 1672, "file_name": "acs.orglett.5b01077-Table-c1.png", "license": 0, "bboxes": [{"id": 2, "bbox": [44.0, 296.0, 344.0, 261.0], "category_id": 1}, {"id": 3, "bbox": [362.0, 16.0, 280.0, 195.0], "category_id": 1}, {"id": 4, "bbox": [50.0, 30.0, 242.0, 183.0], "category_id": 1}, {"id": 5, "bbox": [834.0, 3.2, 468.0, 238.8], "category_id": 1}, {"id": 6, "bbox": [894.0, 280.0, 256.1, 126.1], "category_id": 1}, {"id": 11, "bbox": [891.51, 383.44, 314.58, 131.44], "category_id": 1}], "reactions": [{"reactants": [7, 6], "conditions": [4, 3], "products": [8]}], "caption": "Table 1. Reaction Optimizationa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 265, 111], "ImageBB": [82, 116, 420, 534]}, "diagram_type": "single"}, {"id": 1435, "width": 1352, "height": 936, "file_name": "acs.oprd.5b00331-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1042.0, 54.0, 310.0, 483.0], "category_id": 1}, {"id": 1, "bbox": [31.0, 141.0, 259.0, 203.0], "category_id": 1}, {"id": 7, "bbox": [301.0, 597.0, 366.0, 311.0], "category_id": 1}, {"id": 8, "bbox": [718.0, 573.0, 353.0, 363.0], "category_id": 1}, {"id": 9, "bbox": [510.0, 86.0, 305.0, 426.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [], "products": [0]}], "caption": "Figure 1. Target compounds selected as building block in the synthesis of BCPs modulator focused libraries. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 848, 417, 876], "ImageBB": [82, 604, 420, 838]}, "diagram_type": "single"}, {"id": 1436, "width": 1348, "height": 1540, "file_name": "ol401909z-Table-c1.png", "license": 0, "bboxes": [{"id": 1, "bbox": [805.9, 2.0, 510.2, 342.1], "category_id": 1}, {"id": 2, "bbox": [30.9, 5.0, 249.2, 246.1], "category_id": 1}, {"id": 3, "bbox": [313.0, 0.0, 331.8, 246.2], "category_id": 1}], "reactions": [{"reactants": [3, 4], "conditions": [2], "products": [1]}], "caption": "Table 1. Screening of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 688, 101], "ImageBB": [436, 112, 773, 497]}, "diagram_type": "single"}, {"id": 1437, "width": 1344, "height": 2048, "file_name": "ol4013926-Table-c1.png", "license": 0, "bboxes": [{"id": 4, "bbox": [342.9, 148.1, 263.7, 293.3], "category_id": 1}, {"id": 5, "bbox": [460.2, 459.4, 422.8, 363.32], "category_id": 1}, {"id": 6, "bbox": [29.8, 461.0, 428.8, 355.3], "category_id": 1}, {"id": 7, "bbox": [883.6, 458.7, 433.4, 371.3], "category_id": 1}, {"id": 8, "bbox": [891.0, 92.0, 421.2, 242.0], "category_id": 1}, {"id": 12, "bbox": [60.4, 1.2, 430.6, 234.8], "category_id": 1}], "reactions": [{"reactants": [15, 6], "conditions": [10, 4], "products": [11]}], "caption": "Table 1. Effect of Catalystsa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 221, 101], "ImageBB": [71, 112, 407, 624]}, "diagram_type": "single"}, {"id": 1438, "width": 2816, "height": 1212, "file_name": "ol016466j-Figure-c1.png", "license": 0, "bboxes": [{"id": 2, "bbox": [126.0, 777.0, 1044.0, 429.0], "category_id": 1}, {"id": 3, "bbox": [140.0, 449.0, 869.0, 258.0], "category_id": 1}, {"id": 4, "bbox": [109.0, 174.0, 692.0, 257.1], "category_id": 1}], "reactions": [{"reactants": [14], "conditions": [6, 1], "products": [7]}, {"reactants": [2], "conditions": [13], "products": [3]}, {"reactants": [7], "conditions": [9, 12, 5], "products": [4]}], "caption": "Figure 1. Partial one-dimensional transient NOE spectra of 2 mM polymer-bound trisaccharide 5 and 5 with Verotoxin-1 (200/1) in D2O: (a) 1H NMR spectra of 5 in D2O; (b) 1D NOESY spectra of 5 and VT-1 in D2O; (c) 1D NOESY spectra of 5 in D2O. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 354, 775, 410], "ImageBB": [73, 52, 777, 355]}, "diagram_type": "tree"}, {"id": 1439, "width": 1348, "height": 704, "file_name": "ol016212y-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [923.2, 4.0, 252.8, 240.8], "category_id": 1}, {"id": 1, "bbox": [108.3, 5.0, 252.7, 234.8], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [3, 6], "products": [0]}], "caption": "Table 3. Comparison of the Fiber-Supported Amino Alcohol P3 with 3 and 5 as Catalysts in the Reduction of PhCOMe with NaBH4/Me3SiCl ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 747, 770, 791], "ImageBB": [439, 792, 776, 968]}, "diagram_type": "single"}, {"id": 1440, "width": 1308, "height": 1808, "file_name": "jo9521209-Table-c1.png", "license": 0, "bboxes": [{"id": 8, "bbox": [518.1, 1476.4, 301.9, 262.3], "category_id": 1}, {"id": 9, "bbox": [934.7, 1486.0, 302.6, 277.4], "category_id": 1}, {"id": 11, "bbox": [505.8, 195.7, 295.1, 343.8], "category_id": 1}, {"id": 12, "bbox": [914.8, 202.7, 311.8, 338.6], "category_id": 1}, {"id": 13, "bbox": [8.46, 784.69, 289.24, 309.31], "category_id": 1}, {"id": 14, "bbox": [346.0, 833.3, 120.0, 111.0], "category_id": 1}, {"id": 15, "bbox": [535.6, 766.8, 294.2, 349.2], "category_id": 1}, {"id": 16, "bbox": [945.0, 765.0, 306.0, 353.7], "category_id": 1}], "reactions": [{"reactants": [22], "conditions": [23, 18], "products": [24, 25]}, {"reactants": [24], "conditions": [15, 10], "products": [19]}, {"reactants": [25], "conditions": [21, 10], "products": [20]}, {"reactants": [24], "conditions": [8], "products": [13]}, {"reactants": [25], "conditions": [8], "products": [14]}], "caption": "Table 1. Diels-Alder reactions of 6 and 7 with               cyclopentadiene ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [459, 490, 735, 515], "ImageBB": [440, 26, 767, 478]}, "diagram_type": "tree"}, {"id": 1441, "width": 1352, "height": 1096, "file_name": "jo402763m-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1000.0, 5.0, 305.0, 230.0], "category_id": 1}, {"id": 2, "bbox": [30.0, 6.0, 337.0, 232.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0], "products": [1]}], "caption": "Table 2. Pd-Catalysis of Primary and Secondary Alcohols (2 and 9) ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 405, 125], "ImageBB": [82, 131, 420, 405]}, "diagram_type": "single"}, {"id": 1442, "width": 1348, "height": 484, "file_name": "ol503618m-Table-c1.png", "license": 0, "bboxes": [{"id": 5, "bbox": [324.7, 57.7, 192.4, 112.6], "category_id": 1}, {"id": 6, "bbox": [25.8, 8.7, 208.1, 242.0], "category_id": 1}, {"id": 7, "bbox": [1034.3, 4.4, 294.0, 208.0], "category_id": 1}], "reactions": [{"reactants": [8, 7], "conditions": [9, 5], "products": [10]}], "caption": "Table 1. Optimization of the Reaction Parametersa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 138, 372, 157], "ImageBB": [82, 162, 419, 283]}, "diagram_type": "single"}, {"id": 1443, "width": 1348, "height": 800, "file_name": "ja905415r-Table-c1.png", "license": 0, "bboxes": [{"id": 1, "bbox": [64.04, 32.04, 346.77, 242.52], "category_id": 1}, {"id": 2, "bbox": [656.55, 41.33, 306.52, 247.68], "category_id": 1}, {"id": 3, "bbox": [1019.91, 2.1, 260.06, 291.04], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [5, 6], "products": [3, 4]}], "caption": "Table 1. Au-Catalyzed [4C+2C] vs [4C+3C] Cycloaddition of 1aa", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 462, 752, 476], "ImageBB": [425, 485, 762, 685]}, "diagram_type": "single"}, {"id": 1444, "width": 1352, "height": 1604, "file_name": "ja9039289-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [646.54, 106.01, 253.81, 105.48], "category_id": 1}, {"id": 2, "bbox": [27.36, 100.84, 198.62, 105.48], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [9, 8], "products": [1, 0, 10]}], "caption": "Table 1. Effect of Iron Salts and Additives on the Cross-Coupling of Chlorobenzene with p-TolMgBr ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 57, 385, 81], "ImageBB": [58, 89, 396, 490]}, "diagram_type": "single"}, {"id": 1445, "width": 1352, "height": 1404, "file_name": "ja406383h-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [552.62, 434.38, 186.73, 190.26], "category_id": 1}, {"id": 1, "bbox": [198.98, 763.4, 169.14, 107.56], "category_id": 1}, {"id": 2, "bbox": [556.14, 1025.54, 199.05, 177.94], "category_id": 1}, {"id": 3, "bbox": [126.84, 444.94, 158.59, 63.58], "category_id": 1}, {"id": 4, "bbox": [906.26, 237.33, 170.9, 123.4], "category_id": 1}, {"id": 5, "bbox": [198.98, 233.81, 169.14, 123.4], "category_id": 1}, {"id": 6, "bbox": [1004.78, 1030.82, 250.08, 190.26], "category_id": 1}, {"id": 7, "bbox": [930.9, 759.87, 167.37, 109.33], "category_id": 1}, {"id": 8, "bbox": [123.48, 555.57, 172.49, 52.13], "category_id": 1}, {"id": 9, "bbox": [56.47, 1020.27, 200.81, 184.97], "category_id": 1}], "reactions": [{"reactants": [9], "conditions": [18], "products": [0]}, {"reactants": [8], "conditions": [16], "products": [0]}, {"reactants": [4, 12], "conditions": [17], "products": [0]}, {"reactants": [2], "conditions": [7, 1], "products": [0]}, {"reactants": [11], "conditions": [14, 15], "products": [0]}, {"reactants": [13], "conditions": [5], "products": [3]}, {"reactants": [3], "conditions": [6], "products": [10]}], "caption": "Figure 2. Some examples of natural and pharmaceutical products containing an enamide group. ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 267, 417, 295], "ImageBB": [82, 298, 420, 649]}, "diagram_type": "tree"}, {"id": 1446, "width": 1348, "height": 1816, "file_name": "ja312277g-Table-c1.png", "license": 0, "bboxes": [{"id": 2, "bbox": [802.15, 19.27, 254.22, 100.53], "category_id": 1}, {"id": 3, "bbox": [433.67, 1.54, 94.61, 49.29], "category_id": 1}, {"id": 4, "bbox": [102.62, 23.21, 193.14, 98.56], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [6, 3, 2], "products": [5]}], "caption": "Table 1. Alkylation of \u03b3-C(sp3)\u2212H Bonds with EtI", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 405, 735, 425], "ImageBB": [449, 431, 786, 885]}, "diagram_type": "single"}, {"id": 1447, "width": 1344, "height": 1024, "file_name": "ja0547477-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [715.91, 30.26, 493.52, 316.03], "category_id": 1}, {"id": 1, "bbox": [131.3, 6.68, 476.14, 363.19], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [0], "products": [1]}], "caption": "Table 2. Optimization of Ring I Cyclization", "pdf": {"Page": 12, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 290, 76], "ImageBB": [74, 80, 410, 336]}, "diagram_type": "single"}, {"id": 1448, "width": 1348, "height": 1100, "file_name": "ja001164i-Table-c5.png", "license": 0, "bboxes": [{"id": 1, "bbox": [614.47, 5.92, 200.85, 189.8], "category_id": 1}, {"id": 2, "bbox": [1026.38, 204.77, 181.91, 188.23], "category_id": 1}, {"id": 5, "bbox": [177.31, 204.77, 185.07, 188.23], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [2, 0, 9], "products": [3]}], "caption": "Table 5. Chiral LBA-catalyzed Enantioselective Protonation of 3aa", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 774, 78], "ImageBB": [439, 86, 776, 362]}, "diagram_type": "single"}, {"id": 1449, "width": 2816, "height": 1688, "file_name": "op700160a-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1409.0, 8.0, 293.0, 184.0], "category_id": 1}, {"id": 1, "bbox": [1799.0, 82.0, 176.0, 249.0], "category_id": 1}, {"id": 2, "bbox": [2061.0, 84.0, 178.0, 245.0], "category_id": 1}, {"id": 3, "bbox": [575.0, 157.0, 110.0, 121.0], "category_id": 1}, {"id": 6, "bbox": [820.0, 137.0, 303.0, 165.0], "category_id": 1}], "reactions": [{"reactants": [3, 7], "conditions": [8, 0, 9], "products": [1, 2]}], "caption": "Table 3. Use of scandium (III) catalyst and chiral ligand, 10, to directly access (\u2013)-1a", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 530, 523, 544], "ImageBB": [58, 558, 762, 980]}, "diagram_type": "single"}, {"id": 1450, "width": 1356, "height": 1024, "file_name": "op060175e-Figure-c1.png", "license": 0, "bboxes": [{"id": 3, "bbox": [3.7, 654.4, 469.3, 342.9], "category_id": 1}, {"id": 4, "bbox": [445.5, 464.7, 499.8, 338.9], "category_id": 1}, {"id": 6, "bbox": [481.6, 1.4, 477.0, 342.8], "category_id": 1}, {"id": 7, "bbox": [879.6, 681.0, 476.4, 343.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [], "products": [4]}, {"reactants": [3], "conditions": [], "products": [4]}, {"reactants": [7], "conditions": [], "products": [4]}], "caption": "Figure 1. Reported approaches.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 312, 255, 326], "ImageBB": [73, 53, 412, 309]}, "diagram_type": "tree"}, {"id": 1451, "width": 1352, "height": 1144, "file_name": "op0340816-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1024.17, 961.5, 253.6, 178.6], "category_id": 1}, {"id": 4, "bbox": [492.0, 955.9, 225.0, 182.1], "category_id": 1}, {"id": 5, "bbox": [1031.5, 434.3, 251.4, 246.0], "category_id": 1}, {"id": 6, "bbox": [501.7, 431.1, 281.1, 202.5], "category_id": 1}, {"id": 7, "bbox": [494.2, 11.0, 328.8, 197.7], "category_id": 1}, {"id": 8, "bbox": [6.0, 8.0, 252.0, 177.0], "category_id": 1}, {"id": 9, "bbox": [1044.6, 14.0, 261.4, 235.0], "category_id": 1}], "reactions": [{"reactants": [12], "conditions": [11, 10], "products": [7, 13]}, {"reactants": [7], "conditions": [8], "products": [6]}, {"reactants": [6], "conditions": [], "products": [4]}, {"reactants": [13], "conditions": [9], "products": [5]}, {"reactants": [5], "conditions": [], "products": [0]}], "caption": "Figure 2. Production of 1,3-dichloro-2-fluorobenzene from 2,3,4-trichloro-1-benzenesulfonyl chloride. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 529, 409, 557], "ImageBB": [74, 240, 412, 526]}, "diagram_type": "tree"}, {"id": 1452, "width": 1348, "height": 1124, "file_name": "ol203001w-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1032.3, 78.1, 237.7, 174.5], "category_id": 1}, {"id": 1, "bbox": [31.9, 2.9, 242.8, 327.1], "category_id": 1}, {"id": 2, "bbox": [663.8, 14.2, 286.2, 276.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [3, 4], "products": [2]}], "caption": "Table 3. Copper-Catalyzed Reaction of (E)-1g na", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 704, 101], "ImageBB": [436, 112, 773, 393]}, "diagram_type": "single"}, {"id": 1453, "width": 1348, "height": 1200, "file_name": "ol203001w-Table-c1.png", "license": 0, "bboxes": [{"id": 1, "bbox": [860.5, 6.5, 371.5, 308.8], "category_id": 1}, {"id": 3, "bbox": [116.6, 2.0, 338.4, 359.1], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [6, 5], "products": [2]}], "caption": "Table 1. Optimization of the Reaction Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 280, 703, 293], "ImageBB": [436, 305, 773, 605]}, "diagram_type": "single"}, {"id": 1454, "width": 1396, "height": 2168, "file_name": "ol1030487-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [780.0, 908.0, 267.0, 219.0], "category_id": 1}, {"id": 1, "bbox": [363.0, 920.0, 306.0, 226.0], "category_id": 1}, {"id": 3, "bbox": [54.0, 527.0, 290.0, 166.0], "category_id": 1}, {"id": 4, "bbox": [48.0, 924.0, 316.0, 218.0], "category_id": 1}, {"id": 8, "bbox": [256.0, 716.0, 203.0, 84.0], "category_id": 1}, {"id": 9, "bbox": [1194.0, 756.0, 193.0, 81.0], "category_id": 1}, {"id": 10, "bbox": [1060.0, 523.0, 281.0, 177.0], "category_id": 1}, {"id": 11, "bbox": [612.0, 248.0, 231.0, 110.0], "category_id": 1}, {"id": 12, "bbox": [650.0, 70.0, 198.0, 81.0], "category_id": 1}, {"id": 13, "bbox": [180.0, 283.0, 323.0, 214.0], "category_id": 1}, {"id": 14, "bbox": [533.0, 533.0, 294.0, 149.0], "category_id": 1}, {"id": 21, "bbox": [1116.0, 903.0, 274.0, 220.0], "category_id": 1}, {"id": 24, "bbox": [968.0, 29.0, 316.0, 218.0], "category_id": 1}, {"id": 25, "bbox": [98.0, 16.0, 475.0, 222.0], "category_id": 1}, {"id": 28, "bbox": [853.0, 556.0, 127.0, 52.0], "category_id": 1}, {"id": 29, "bbox": [387.0, 566.0, 123.0, 49.0], "category_id": 1}], "reactions": [{"reactants": [20, 19], "conditions": [4, 3], "products": [22]}, {"reactants": [22], "conditions": [37, 15], "products": [5]}, {"reactants": [5], "conditions": [14, 12, 13], "products": [6, 1]}, {"reactants": [22], "conditions": [36, 16], "products": [18]}, {"reactants": [18], "conditions": [11, 17], "products": [0, 29]}], "caption": "Table 3. Scope of the Organocatalytic Michael- Wittig-Michael-Michael Reaction ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 329, 114], "ImageBB": [71, 126, 420, 668]}, "diagram_type": "tree"}, {"id": 1455, "width": 1344, "height": 456, "file_name": "ol071385u-Table-c1.png", "license": 0, "bboxes": [{"id": 2, "bbox": [88.0, 9.0, 436.0, 203.0], "category_id": 1}, {"id": 3, "bbox": [924.0, 3.0, 342.0, 230.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0, 6], "products": [5]}], "caption": "Table 1. Optimization of the Pd-Catalyzed Cyclization of Propargylic Carbonate 1aa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 569, 379, 597], "ImageBB": [74, 599, 410, 713]}, "diagram_type": "single"}, {"id": 1456, "width": 1356, "height": 1124, "file_name": "op4003467-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [800.6, 16.6, 316.2, 281.9], "category_id": 1}, {"id": 3, "bbox": [374.7, 390.5, 302.3, 274.5], "category_id": 1}, {"id": 4, "bbox": [806.0, 391.5, 315.5, 320.5], "category_id": 1}, {"id": 5, "bbox": [220.1, 70.5, 316.9, 171.5], "category_id": 1}, {"id": 6, "bbox": [559.0, 189.6, 177.5, 91.4], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [9, 8], "products": [0]}, {"reactants": [0], "conditions": [12, 11, 14], "products": [5, 6]}, {"reactants": [5], "conditions": [2, 4], "products": [13]}], "caption": "Table 1. Dechlorination of 18", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 824, 619, 839], "ImageBB": [448, 537, 787, 818]}, "diagram_type": "tree"}, {"id": 1457, "width": 1704, "height": 3984, "file_name": "op400278d-Table-c3.png", "license": 0, "bboxes": [{"id": 8, "bbox": [83.8, 1224.8, 335.6, 268.0], "category_id": 1}, {"id": 9, "bbox": [745.5, 776.7, 553.8, 295.3], "category_id": 1}, {"id": 10, "bbox": [199.0, 761.0, 424.5, 322.4], "category_id": 1}, {"id": 11, "bbox": [526.0, 1231.5, 328.2, 270.5], "category_id": 1}, {"id": 12, "bbox": [979.4, 1209.0, 369.4, 310.4], "category_id": 1}, {"id": 16, "bbox": [132.3, 142.5, 119.7, 68.9], "category_id": 1}, {"id": 17, "bbox": [1169.4, 143.4, 172.8, 64.2], "category_id": 1}, {"id": 18, "bbox": [89.1, 345.0, 320.6, 253.0], "category_id": 1}, {"id": 19, "bbox": [943.8, 328.7, 431.9, 293.3], "category_id": 1}, {"id": 20, "bbox": [529.7, 345.0, 328.0, 257.3], "category_id": 1}, {"id": 21, "bbox": [426.1, 148.0, 120.2, 60.7], "category_id": 1}, {"id": 22, "bbox": [943.7, 1652.3, 433.5, 282.3], "category_id": 1}, {"id": 23, "bbox": [581.4, 1662.0, 332.9, 266.0], "category_id": 1}, {"id": 24, "bbox": [78.0, 1654.0, 432.6, 274.0], "category_id": 1}], "reactions": [{"reactants": [20, 27], "conditions": [16, 14, 15], "products": [23]}], "caption": "Table 3. Room temperature aryl sul\ufb01nations mediated by pre-catalyst Pd-PEPPSI-IPentCl-picoline (35) ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 773, 126], "ImageBB": [433, 131, 859, 1127]}, "diagram_type": "single"}, {"id": 1458, "width": 1688, "height": 992, "file_name": "op2001047-Table-c5.png", "license": 0, "bboxes": [{"id": 1, "bbox": [43.0, 598.3, 290.4, 177.7], "category_id": 1}, {"id": 2, "bbox": [6.0, 405.6, 364.7, 173.4], "category_id": 1}, {"id": 3, "bbox": [1023.3, 1.3, 238.4, 125.4], "category_id": 1}, {"id": 4, "bbox": [433.0, 2.3, 148.4, 126.7], "category_id": 1}, {"id": 6, "bbox": [49.6, 797.6, 275.1, 183.4], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [11, 6], "products": [3]}], "caption": "Table 5. Reaction optimization for the aldol reaction of acetone with aldehydes 4a c under microwave batch and continuous \ufb02ow conditionsa ", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 88, 770, 122], "ImageBB": [211, 133, 633, 381]}, "diagram_type": "single"}, {"id": 1459, "width": 1348, "height": 352, "file_name": "acs.orglett.5b02003-Table-c2.png", "license": 0, "bboxes": [{"id": 3, "bbox": [987.0, 1.0, 342.9, 237.0], "category_id": 1}, {"id": 4, "bbox": [20.2, 24.1, 321.7, 184.8], "category_id": 1}, {"id": 5, "bbox": [366.0, 39.0, 273.0, 156.0], "category_id": 1}], "reactions": [{"reactants": [5, 6], "conditions": [4, 7], "products": [3]}], "caption": "Table 2. Scope of Cyclopropane 1,1-Diestersa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 709, 110], "ImageBB": [449, 116, 786, 204]}, "diagram_type": "single"}, {"id": 1460, "width": 1356, "height": 1676, "file_name": "acs.oprd.6b00188-Table-c1.png", "license": 0, "bboxes": [{"id": 2, "bbox": [893.0, 6.0, 324.0, 522.0], "category_id": 1}, {"id": 3, "bbox": [1094.0, 142.0, 6.0, 6.0], "category_id": 1}, {"id": 4, "bbox": [71.2, 37.0, 283.8, 439.0], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [1, 2], "products": [6]}], "caption": "Table 1. Condensation of Racemic Tetralone 1 Mediated by Ti(IV) Alkoxides ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 309, 784, 339], "ImageBB": [448, 346, 787, 765]}, "diagram_type": "single"}, {"id": 1461, "width": 1356, "height": 300, "file_name": "acs.oprd.5b00371-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [905.0, 6.0, 338.0, 223.0], "category_id": 1}, {"id": 1, "bbox": [112.0, 39.0, 272.0, 139.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [0, 5], "products": [1]}], "caption": "Table 3. Comparison of the Amount of BF3OEt2 for the Formation of 3a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 701, 767, 731], "ImageBB": [448, 621, 787, 696]}, "diagram_type": "single"}, {"id": 1462, "width": 1264, "height": 1000, "file_name": "ol501422k-Table-c3.png", "license": 0, "bboxes": [{"id": 3, "bbox": [750.5, 13.3, 370.6, 167.3], "category_id": 1}, {"id": 8, "bbox": [38.0, 37.9, 231.6, 110.4], "category_id": 1}, {"id": 10, "bbox": [326.2, 13.6, 173.5, 161.1], "category_id": 1}, {"id": 11, "bbox": [401.0, 784.6, 403.6, 172.4], "category_id": 1}, {"id": 12, "bbox": [3.9, 785.2, 326.8, 157.9], "category_id": 1}, {"id": 13, "bbox": [3.9, 523.6, 381.1, 165.2], "category_id": 1}, {"id": 14, "bbox": [403.0, 523.2, 376.5, 163.2], "category_id": 1}, {"id": 15, "bbox": [796.6, 517.2, 462.2, 173.9], "category_id": 1}], "reactions": [{"reactants": [11, 13], "conditions": [1, 10], "products": [5]}], "caption": "Table 3. E\ufb00ect of Substituents on the Nitroso Moietya", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 383, 110], "ImageBB": [93, 116, 409, 366]}, "diagram_type": "single"}, {"id": 1463, "width": 1352, "height": 440, "file_name": "ol0487783-Figure-c1.png", "license": 0, "bboxes": [{"id": 2, "bbox": [127.0, 196.0, 136.0, 108.0], "category_id": 1}, {"id": 3, "bbox": [365.3, 268.0, 369.7, 99.0], "category_id": 1}, {"id": 4, "bbox": [780.0, 168.0, 448.6, 214.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [6, 5, 0, 8, 4], "products": [9]}], "caption": "Figure 1. One-pot preparation of C,C-dicyclopropylmethylamines.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 825, 775, 838], "ImageBB": [439, 703, 777, 813]}, "diagram_type": "single"}, {"id": 1464, "width": 1344, "height": 1104, "file_name": "ol015948s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [843.0, 115.0, 432.0, 172.6], "category_id": 1}, {"id": 1, "bbox": [76.0, 55.5, 364.0, 229.8], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [4, 3], "products": [0]}], "caption": "Table 1. Organosilane Reductants for Catalytic Reductive Amination ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 380, 104], "ImageBB": [74, 116, 410, 392]}, "diagram_type": "single"}, {"id": 1465, "width": 1348, "height": 876, "file_name": "jo990938e-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [145.0, 100.0, 264.0, 176.0], "category_id": 1}, {"id": 1, "bbox": [832.0, 93.0, 383.0, 196.0], "category_id": 1}, {"id": 4, "bbox": [491.0, 4.0, 211.0, 202.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [6, 1], "products": [2]}], "caption": "   Table 5. Variations of Solvent in Additions of Allenylindium Reagents Derived from Mesylate 7 to             Cyclohexanecarboxaldehyde ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [456, 259, 758, 296], "ImageBB": [439, 306, 776, 525]}, "diagram_type": "single"}, {"id": 1466, "width": 1356, "height": 736, "file_name": "jo502578x-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [352.0, 30.0, 293.0, 259.0], "category_id": 1}, {"id": 1, "bbox": [26.0, 36.0, 285.0, 113.2], "category_id": 1}, {"id": 3, "bbox": [1043.0, 51.0, 286.0, 164.0], "category_id": 1}, {"id": 4, "bbox": [692.0, 38.0, 289.0, 238.0], "category_id": 1}], "reactions": [{"reactants": [1, 6], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [], "products": [7]}], "caption": "Figure 3. Detailed mechanism and energy pro\ufb01le of the reaction of SIMes (2) with chloroform in chloroform (blue) and energies of the stationary points A, B, and 4 in n-hexane (green). The energy pro\ufb01le was obtained by DFT calculations at the B3LYP/6-311++G** level of theory (free energies at 25 \u00b0C including ZPE corrections in kcal/mol with the IEFPCM solvation model); see the Supporting Information for details. ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 339, 784, 436], "ImageBB": [448, 146, 787, 330]}, "diagram_type": "single"}, {"id": 1467, "width": 1352, "height": 1232, "file_name": "jo501014e-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [485.0, 930.0, 357.0, 289.0], "category_id": 1}, {"id": 1, "bbox": [761.0, 91.0, 350.0, 447.0], "category_id": 1}, {"id": 2, "bbox": [890.0, 728.0, 319.0, 220.0], "category_id": 1}, {"id": 3, "bbox": [147.0, 755.0, 327.0, 174.0], "category_id": 1}, {"id": 4, "bbox": [137.0, 154.0, 377.0, 384.0], "category_id": 1}, {"id": 5, "bbox": [521.0, 146.0, 225.0, 390.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [11], "products": [4]}, {"reactants": [5], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [4]}], "caption": "Figure 1. (a) Bioactive 2H-indazoles. (b) A typical Davis\u2212Beirut reaction proceeding through the proposed nitrosoimine intermediate.6 ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 881, 417, 909], "ImageBB": [82, 563, 420, 871]}, "diagram_type": "graph"}, {"id": 1468, "width": 1352, "height": 540, "file_name": "jo201996w-Table-c2.png", "license": 0, "bboxes": [{"id": 1, "bbox": [15.0, 61.0, 379.0, 205.0], "category_id": 1}, {"id": 2, "bbox": [955.0, 3.0, 384.0, 319.0], "category_id": 1}, {"id": 3, "bbox": [509.0, 59.0, 191.0, 201.0], "category_id": 1}], "reactions": [{"reactants": [3, 5], "conditions": [2], "products": [4]}], "caption": "Table 2. Synthesis of 2,2\u2033-Dinitrogen-Substituted Bisazo- benzenes 4 ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [436, 81, 771, 112], "ImageBB": [436, 119, 774, 254]}, "diagram_type": "single"}, {"id": 1469, "width": 1356, "height": 896, "file_name": "jo2003264-Table-c4.png", "license": 0, "bboxes": [{"id": 3, "bbox": [1050.0, 63.0, 303.0, 154.0], "category_id": 1}, {"id": 4, "bbox": [0.0, 95.0, 200.0, 101.0], "category_id": 1}, {"id": 5, "bbox": [753.0, 63.0, 263.0, 150.0], "category_id": 1}], "reactions": [{"reactants": [7, 9], "conditions": [3, 4], "products": [8, 6]}], "caption": "Table 4. Ir-Catalyzed Oxidative Methyl Esteri\ufb01cation of r,\u03c9- Diols 5a with 2a ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 88, 771, 122], "ImageBB": [436, 133, 775, 357]}, "diagram_type": "single"}, {"id": 1470, "width": 1344, "height": 528, "file_name": "jo2001534-Table-c4.png", "license": 0, "bboxes": [{"id": 1, "bbox": [33.0, 0.0, 347.0, 437.0], "category_id": 1}, {"id": 2, "bbox": [542.0, 6.0, 354.0, 422.0], "category_id": 1}, {"id": 3, "bbox": [1059.0, 2.0, 252.0, 409.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [4], "products": [2]}, {"reactants": [2], "conditions": [5], "products": [3]}], "caption": "Table 4. Yields and Substitution Pattern of 8a-e", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 279, 344, 294], "ImageBB": [71, 133, 407, 265]}, "diagram_type": "single"}, {"id": 1471, "width": 1352, "height": 368, "file_name": "acs.oprd.5b00137-Table-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [677.0, 32.0, 277.0, 145.0], "category_id": 1}, {"id": 1, "bbox": [984.0, 26.0, 197.0, 129.9], "category_id": 1}, {"id": 2, "bbox": [164.3, 28.0, 273.7, 144.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [2, 0], "products": [1, 3]}], "caption": "Table 9. Reusability of the SiliaCat Pt0 in the Selective Catalytic Hydrogenation of 4-Chloronitrobenzene [Reproduced with Permission from Ref 55, Copyright 2011 John Wiley and Sons] ", "pdf": {"Page": 10, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 92, 412, 155], "ImageBB": [82, 162, 420, 254]}, "diagram_type": "single"}, {"id": 1472, "width": 1356, "height": 688, "file_name": "jacs.5b12989-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [965.41, 10.46, 176.88, 169.79], "category_id": 1}, {"id": 1, "bbox": [624.51, 10.46, 176.0, 169.79], "category_id": 1}, {"id": 2, "bbox": [209.94, 14.9, 176.88, 165.3], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [4, 5], "products": [2]}, {"reactants": [2], "conditions": [10, 6], "products": [1]}], "caption": "Table 3. Mechanistic Insight from O-Alkyl Group Variance of the Oxyboration Reaction ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 91, 784, 125], "ImageBB": [448, 131, 787, 303]}, "diagram_type": "single"}, {"id": 1473, "width": 1340, "height": 800, "file_name": "ja312277g-Table-c4.png", "license": 0, "bboxes": [{"id": 1, "bbox": [2.92, 570.46, 273.8, 119.0], "category_id": 1}, {"id": 2, "bbox": [1073.92, 282.46, 228.78, 189.2], "category_id": 1}, {"id": 3, "bbox": [766.12, 282.46, 228.8, 187.4], "category_id": 1}, {"id": 4, "bbox": [503.32, 280.66, 189.2, 174.8], "category_id": 1}, {"id": 5, "bbox": [28.12, 280.66, 192.8, 173.0], "category_id": 1}, {"id": 6, "bbox": [1100.92, 5.26, 234.2, 180.2], "category_id": 1}, {"id": 7, "bbox": [798.52, 7.06, 234.2, 180.2], "category_id": 1}, {"id": 8, "bbox": [499.72, 52.06, 261.2, 135.2], "category_id": 1}, {"id": 9, "bbox": [4.72, 34.06, 234.2, 144.2], "category_id": 1}, {"id": 10, "bbox": [514.12, 577.66, 273.8, 115.4], "category_id": 1}, {"id": 11, "bbox": [931.72, 575.86, 290.0, 128.04], "category_id": 1}], "reactions": [{"reactants": [9], "conditions": [12, 13], "products": [8, 7, 6]}, {"reactants": [5], "conditions": [14, 15], "products": [4, 3, 2]}, {"reactants": [1], "conditions": [16, 17], "products": [10, 11]}], "caption": "Table 4. Sequential C(sp3)\u2212H Methylation", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 696, 325, 715], "ImageBB": [83, 720, 418, 920]}, "diagram_type": "multiple"}, {"id": 1474, "width": 1344, "height": 868, "file_name": "ja074044k-Table-c1.png", "license": 0, "bboxes": [{"id": 2, "bbox": [134.25, 26.2, 264.2, 118.52], "category_id": 1}, {"id": 3, "bbox": [718.56, 4.84, 328.63, 145.42], "category_id": 1}, {"id": 4, "bbox": [744.56, 239.81, 299.24, 135.48], "category_id": 1}, {"id": 6, "bbox": [161.37, 245.57, 234.82, 107.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [], "products": [3]}, {"reactants": [6], "conditions": [], "products": [4]}], "caption": "Table 1. Yields and Enantioselectivities in Allylic Alkylationsa Using Pd Catalysts Containing Ligands 1-6 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 63, 380, 88], "ImageBB": [74, 95, 410, 312]}, "diagram_type": "multiple"}, {"id": 1475, "width": 1344, "height": 1020, "file_name": "op9701245-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [895.0, 7.0, 239.0, 332.0], "category_id": 1}, {"id": 1, "bbox": [214.0, 86.0, 293.0, 257.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0, 3], "products": [2]}], "caption": "Table 1. Furfuryl alcohol rearrangement", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 327, 304, 341], "ImageBB": [74, 349, 410, 604]}, "diagram_type": "single"}, {"id": 1476, "width": 2820, "height": 1220, "file_name": "op500250b-Table-c1.png", "license": 0, "bboxes": [{"id": 11, "bbox": [387.6, 69.5, 271.0, 145.0], "category_id": 1}, {"id": 12, "bbox": [54.5, 58.9, 266.5, 147.0], "category_id": 1}, {"id": 13, "bbox": [976.4, 92.5, 396.5, 121.3], "category_id": 1}, {"id": 14, "bbox": [1570.4, 25.5, 353.6, 231.4], "category_id": 1}, {"id": 15, "bbox": [2129.0, 0.0, 641.8, 340.2], "category_id": 1}, {"id": 16, "bbox": [282.1, 398.0, 361.3, 239.0], "category_id": 1}, {"id": 17, "bbox": [774.4, 417.0, 274.1, 184.2], "category_id": 1}, {"id": 18, "bbox": [1505.5, 368.6, 589.4, 292.4], "category_id": 1}, {"id": 19, "bbox": [60.5, 843.8, 581.4, 302.9], "category_id": 1}, {"id": 20, "bbox": [960.3, 730.0, 608.6, 416.2], "category_id": 1}, {"id": 21, "bbox": [1812.6, 731.9, 618.3, 408.2], "category_id": 1}], "reactions": [{"reactants": [29, 21], "conditions": [22, 23], "products": [30]}, {"reactants": [30], "conditions": [19, 20], "products": [31]}, {"reactants": [31], "conditions": [24, 25], "products": [32]}, {"reactants": [32], "conditions": [26, 27], "products": [33, 34]}, {"reactants": [33, 34], "conditions": [28, 13], "products": [35]}, {"reactants": [35], "conditions": [3, 4], "products": [36]}, {"reactants": [36], "conditions": [12, 11], "products": [37]}, {"reactants": [37], "conditions": [10, 9], "products": [38]}], "caption": "Table 1. E\ufb00ect of solvents and additives in the [3 + 2] dipolar cycloadditiona", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 713, 521, 734], "ImageBB": [82, 407, 787, 712]}, "diagram_type": "multiple"}, {"id": 1477, "width": 1288, "height": 2192, "file_name": "ol8013717-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 0.0, 341.0, 243.0], "category_id": 1}, {"id": 9, "bbox": [96.8, 1148.7, 433.7, 253.6], "category_id": 1}, {"id": 10, "bbox": [99.9, 1523.8, 501.1, 252.2], "category_id": 1}, {"id": 11, "bbox": [649.0, 1521.92, 502.3, 252.38], "category_id": 1}, {"id": 12, "bbox": [348.77, 1870.08, 516.63, 249.22], "category_id": 1}, {"id": 16, "bbox": [946.7, 0.0, 336.3, 243.0], "category_id": 1}, {"id": 17, "bbox": [99.0, 415.0, 424.3, 248.0], "category_id": 1}, {"id": 18, "bbox": [94.0, 780.8, 487.2, 251.4], "category_id": 1}, {"id": 19, "bbox": [640.0, 406.0, 546.3, 257.0], "category_id": 1}, {"id": 20, "bbox": [646.7, 1149.5, 446.6, 251.7], "category_id": 1}, {"id": 21, "bbox": [649.0, 779.7, 484.4, 252.5], "category_id": 1}], "reactions": [{"reactants": [0, 2], "conditions": [10, 11], "products": [19]}], "caption": "Table 2. Cross-Coupling of 1 and Arylboronic Acids (2)a", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 73, 357, 88], "ImageBB": [66, 94, 388, 642]}, "diagram_type": "single"}, {"id": 1478, "width": 1344, "height": 848, "file_name": "ol302863r-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [175.8, 7.5, 490.0, 191.9], "category_id": 1}, {"id": 1, "bbox": [775.7, 3.1, 395.2, 205.4], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [], "products": [1]}], "caption": "Table 1. Anodic Disulfide Bond Formation by Peptide 1", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 154, 371, 167], "ImageBB": [71, 178, 407, 390]}, "diagram_type": "single"}, {"id": 1479, "width": 1344, "height": 696, "file_name": "ol300842d-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [107.0, 39.2, 430.2, 201.0], "category_id": 1}, {"id": 3, "bbox": [911.0, 3.0, 334.0, 237.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [1, 5, 2], "products": [7]}], "caption": "Table 1. Optimization of Reaction Condition", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 312, 100], "ImageBB": [71, 112, 407, 286]}, "diagram_type": "single"}, {"id": 1480, "width": 1344, "height": 1440, "file_name": "ol300808c-Table-c1.png", "license": 0, "bboxes": [{"id": 1, "bbox": [282.8, 312.1, 970.2, 267.4], "category_id": 1}, {"id": 2, "bbox": [88.0, 6.0, 646.0, 261.9], "category_id": 1}, {"id": 3, "bbox": [831.0, 50.7, 410.9, 116.8], "category_id": 1}], "reactions": [{"reactants": [4, 5], "conditions": [0], "products": [3]}], "caption": "Table 1. Effects of Various Alkene-Containing Sugar Deriva- tives on Solid-Phase CMa ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 433, 397, 460], "ImageBB": [71, 471, 407, 831]}, "diagram_type": "tree"}, {"id": 1481, "width": 1340, "height": 732, "file_name": "ol300387f-Table-c1.png", "license": 0, "bboxes": [{"id": 3, "bbox": [637.3, 6.9, 181.4, 194.4], "category_id": 1}, {"id": 4, "bbox": [907.2, 4.9, 236.2, 212.1], "category_id": 1}, {"id": 5, "bbox": [195.1, 3.3, 188.5, 235.6], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [6, 4], "products": [3]}, {"reactants": [8], "conditions": [6, 4], "products": [5]}], "caption": "Table 1. Addition to Geminal Dimethylated Cyclohex-2-enones", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 771, 100], "ImageBB": [437, 112, 772, 295]}, "diagram_type": "single"}, {"id": 1482, "width": 1344, "height": 1188, "file_name": "ol071386m-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [911.4, 0.0, 258.6, 139.0], "category_id": 1}, {"id": 1, "bbox": [450.9, 223.0, 239.1, 195.0], "category_id": 1}, {"id": 3, "bbox": [398.0, 82.0, 148.0, 49.0], "category_id": 1}, {"id": 7, "bbox": [175.0, 36.0, 133.0, 107.0], "category_id": 1}], "reactions": [{"reactants": [8, 4], "conditions": [3], "products": [0]}], "caption": "Table 1. Pt/SPOs-Catalyzed [2 + 1] Cycloaddition of 4a with 5a ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 141, 376, 173], "ImageBB": [74, 181, 410, 478]}, "diagram_type": "single"}, {"id": 1483, "width": 1356, "height": 1756, "file_name": "op500224x-Table-c5.png", "license": 0, "bboxes": [{"id": 8, "bbox": [848.0, 415.0, 415.0, 339.0], "category_id": 1}, {"id": 9, "bbox": [613.0, 843.0, 498.0, 353.0], "category_id": 1}, {"id": 10, "bbox": [165.0, 852.0, 376.0, 355.0], "category_id": 1}, {"id": 11, "bbox": [160.0, 1293.0, 370.0, 305.0], "category_id": 1}, {"id": 12, "bbox": [621.0, 1291.0, 483.0, 331.0], "category_id": 1}, {"id": 13, "bbox": [1033.0, 16.0, 315.0, 315.0], "category_id": 1}, {"id": 14, "bbox": [502.0, 8.0, 286.0, 313.0], "category_id": 1}, {"id": 15, "bbox": [48.0, 441.0, 318.0, 295.0], "category_id": 1}, {"id": 17, "bbox": [0.0, 3.0, 290.0, 318.0], "category_id": 1}, {"id": 18, "bbox": [452.0, 438.0, 331.0, 292.0], "category_id": 1}], "reactions": [{"reactants": [20], "conditions": [8, 22], "products": [16]}, {"reactants": [16], "conditions": [6, 19], "products": [15]}], "caption": "Table 5. Addition of carbon electrophiles and carbon nucleophiles under kinetic control ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 750, 125], "ImageBB": [448, 131, 787, 570]}, "diagram_type": "single"}, {"id": 1484, "width": 1352, "height": 2676, "file_name": "op500224x-Table-c4.png", "license": 0, "bboxes": [{"id": 1, "bbox": [3.0, 2197.0, 350.0, 358.0], "category_id": 1}, {"id": 2, "bbox": [1.0, 1734.0, 303.0, 309.0], "category_id": 1}, {"id": 3, "bbox": [308.0, 1730.0, 325.0, 299.0], "category_id": 1}, {"id": 4, "bbox": [643.0, 1718.0, 388.0, 319.0], "category_id": 1}, {"id": 5, "bbox": [1049.0, 1716.0, 297.0, 305.0], "category_id": 1}, {"id": 6, "bbox": [1053.0, 1290.0, 270.0, 302.0], "category_id": 1}, {"id": 7, "bbox": [718.0, 1294.0, 309.0, 306.0], "category_id": 1}, {"id": 8, "bbox": [328.0, 1290.0, 360.0, 315.0], "category_id": 1}, {"id": 9, "bbox": [1.0, 1292.0, 311.0, 290.0], "category_id": 1}, {"id": 10, "bbox": [324.0, 847.0, 295.0, 317.0], "category_id": 1}, {"id": 11, "bbox": [1.0, 843.0, 301.0, 335.0], "category_id": 1}, {"id": 12, "bbox": [633.0, 853.0, 321.0, 311.0], "category_id": 1}, {"id": 13, "bbox": [954.0, 845.0, 390.0, 317.0], "category_id": 1}, {"id": 14, "bbox": [1051.0, 421.0, 295.0, 298.0], "category_id": 1}, {"id": 15, "bbox": [659.0, 417.0, 368.0, 349.0], "category_id": 1}, {"id": 16, "bbox": [318.0, 423.0, 311.0, 319.0], "category_id": 1}, {"id": 17, "bbox": [0.0, 425.0, 296.0, 296.0], "category_id": 1}, {"id": 18, "bbox": [3.0, 15.0, 273.0, 298.0], "category_id": 1}, {"id": 19, "bbox": [1056.0, 6.0, 296.0, 315.0], "category_id": 1}, {"id": 20, "bbox": [451.0, 2.0, 300.0, 329.0], "category_id": 1}, {"id": 21, "bbox": [359.0, 2207.0, 369.0, 344.0], "category_id": 1}, {"id": 22, "bbox": [736.0, 2167.0, 330.0, 422.0], "category_id": 1}, {"id": 23, "bbox": [1045.0, 2157.0, 303.0, 426.0], "category_id": 1}], "reactions": [{"reactants": [18], "conditions": [27, 26], "products": [20]}, {"reactants": [20], "conditions": [24, 25], "products": [19]}], "caption": "Table 4. Tetrahydropyridines generated via kinetic iminiums from carbon electrophile addition and subsequent reduction ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [82, 131, 420, 800]}, "diagram_type": "single"}, {"id": 1485, "width": 1356, "height": 2648, "file_name": "op500224x-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [465.0, 1207.0, 302.0, 308.0], "category_id": 1}, {"id": 17, "bbox": [63.0, 27.0, 210.0, 158.0], "category_id": 1}, {"id": 18, "bbox": [2.0, 130.0, 285.0, 225.0], "category_id": 1}, {"id": 19, "bbox": [528.0, 16.0, 305.0, 314.0], "category_id": 1}, {"id": 20, "bbox": [1066.0, 27.0, 290.0, 300.0], "category_id": 1}, {"id": 24, "bbox": [13.0, 469.0, 285.0, 216.0], "category_id": 1}, {"id": 25, "bbox": [323.0, 471.0, 325.0, 225.0], "category_id": 1}, {"id": 26, "bbox": [678.0, 457.0, 302.0, 248.0], "category_id": 1}, {"id": 27, "bbox": [1011.0, 441.0, 322.0, 291.0], "category_id": 1}, {"id": 28, "bbox": [1052.0, 829.0, 304.0, 267.0], "category_id": 1}, {"id": 29, "bbox": [703.0, 821.0, 366.0, 294.0], "category_id": 1}, {"id": 30, "bbox": [287.0, 816.0, 424.0, 283.0], "category_id": 1}, {"id": 31, "bbox": [2.0, 816.0, 296.0, 283.0], "category_id": 1}, {"id": 32, "bbox": [71.0, 1232.0, 288.0, 266.0], "category_id": 1}, {"id": 33, "bbox": [853.0, 1212.0, 410.0, 286.0], "category_id": 1}, {"id": 34, "bbox": [246.0, 1632.0, 291.0, 316.0], "category_id": 1}, {"id": 35, "bbox": [709.0, 1601.0, 385.0, 353.0], "category_id": 1}, {"id": 36, "bbox": [4.0, 2078.0, 364.0, 317.0], "category_id": 1}, {"id": 37, "bbox": [434.0, 2059.0, 397.0, 325.0], "category_id": 1}, {"id": 38, "bbox": [903.0, 2029.0, 438.0, 405.0], "category_id": 1}], "reactions": [{"reactants": [17, 18], "conditions": [21, 22], "products": [19]}, {"reactants": [19], "conditions": [23, 24], "products": [20]}], "caption": "Table 1. Rh-catalyzed cyclization with kinetic protonation and reduction ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 775, 125], "ImageBB": [448, 131, 787, 793]}, "diagram_type": "single"}, {"id": 1486, "width": 1356, "height": 936, "file_name": "op400050n-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [899.3, 397.3, 240.7, 198.7], "category_id": 1}, {"id": 1, "bbox": [522.0, 401.7, 192.0, 163.3], "category_id": 1}, {"id": 2, "bbox": [505.1, 44.0, 302.9, 191.0], "category_id": 1}, {"id": 3, "bbox": [705.8, 734.0, 273.2, 195.7], "category_id": 1}, {"id": 4, "bbox": [251.9, 731.3, 325.1, 204.7], "category_id": 1}, {"id": 5, "bbox": [215.3, 391.5, 176.7, 205.5], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [8], "products": [2]}, {"reactants": [1], "conditions": [], "products": [5]}, {"reactants": [1], "conditions": [7], "products": [0]}, {"reactants": [1], "conditions": [9], "products": [4]}, {"reactants": [1], "conditions": [6], "products": [3]}], "caption": "Figure 2. Possible oxirane ring-opening reactions.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 741, 691, 755], "ImageBB": [448, 498, 787, 732]}, "diagram_type": "tree"}, {"id": 1487, "width": 1352, "height": 1260, "file_name": "ol061289d-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [222.0, 188.0, 442.0, 264.0], "category_id": 1}, {"id": 3, "bbox": [686.0, 140.9, 442.0, 358.1], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [], "products": [7]}], "caption": "Figure 3. HPLC chromatographs for the reaction of 7 with methyl bromoacetate. HPLC conditions: Kromasil C18, 15-45% B in A over 25 min, A ) H2O + 0.1% TFA, B ) CH3CN + 0.08% TFA ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 379, 775, 421], "ImageBB": [439, 52, 777, 367]}, "diagram_type": "single"}, {"id": 1488, "width": 1352, "height": 388, "file_name": "jo0109321-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [3.8, 53.5, 443.2, 77.8], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [0, 1, 6], "products": [4, 3]}], "caption": "Table 5. Hydroboration of 1-Heptene with BH3-THF in                         THF ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [78, 305, 405, 332], "ImageBB": [74, 342, 412, 439]}, "diagram_type": "single"}, {"id": 1489, "width": 1352, "height": 896, "file_name": "acs.orglett.5b01077-Table-c3.png", "license": 0, "bboxes": [{"id": 1, "bbox": [17.5, 130.0, 252.5, 200.6], "category_id": 1}, {"id": 2, "bbox": [284.8, 13.8, 197.2, 185.1], "category_id": 1}, {"id": 3, "bbox": [806.3, 4.0, 521.2, 450.1], "category_id": 1}, {"id": 4, "bbox": [300.2, 236.2, 197.5, 186.5], "category_id": 1}], "reactions": [{"reactants": [7, 8, 10], "conditions": [0, 2], "products": [9]}], "caption": "Table 3. Competition Experiments", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 542, 275, 558], "ImageBB": [82, 563, 420, 787]}, "diagram_type": "single"}, {"id": 1490, "width": 1352, "height": 460, "file_name": "acs.oprd.6b00180-Table-c9.png", "license": 0, "bboxes": [{"id": 1, "bbox": [1013.4, 3.9, 333.5, 192.2], "category_id": 1}, {"id": 2, "bbox": [0.9, 59.3, 265.1, 129.8], "category_id": 1}, {"id": 3, "bbox": [362.0, 76.2, 249.0, 124.8], "category_id": 1}], "reactions": [{"reactants": [5, 6], "conditions": [2, 3], "products": [4]}], "caption": "Table 9. Suzuki Reaction of 4-Amino-2-bromopyridine (3) and PhB(OH)2 in H2O ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 649, 412, 679], "ImageBB": [82, 685, 420, 800]}, "diagram_type": "single"}, {"id": 1491, "width": 2820, "height": 3484, "file_name": "acs.oprd.6b00117-Table-c2.png", "license": 0, "bboxes": [{"id": 1, "bbox": [475.11, 41.06, 329.0, 230.0], "category_id": 1}, {"id": 4, "bbox": [1893.0, 1292.0, 471.0, 285.0], "category_id": 1}, {"id": 8, "bbox": [914.1, 1343.0, 215.6, 199.1], "category_id": 1}, {"id": 9, "bbox": [453.11, 1340.0, 333.0, 219.0], "category_id": 1}, {"id": 10, "bbox": [1871.89, 0.0, 468.61, 276.1], "category_id": 1}, {"id": 11, "bbox": [914.11, 49.83, 229.59, 204.97], "category_id": 1}], "reactions": [{"reactants": [1, 16], "conditions": [2, 3], "products": [15]}, {"reactants": [14, 13], "conditions": [8, 9], "products": [7]}], "caption": "Table 2. Solvent Screening for the Radical Arylation of Quinoline N-Oxide 16", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 513, 111], "ImageBB": [82, 116, 787, 987]}, "diagram_type": "multiple"}, {"id": 1492, "width": 2820, "height": 1572, "file_name": "acs.oprd.6b00011-Table-c1.png", "license": 0, "bboxes": [{"id": 1, "bbox": [1847.1, 1101.5, 550.2, 415.7], "category_id": 1}, {"id": 3, "bbox": [1100.1, 1137.0, 368.4, 355.1], "category_id": 1}, {"id": 4, "bbox": [425.6, 1097.0, 389.0, 429.4], "category_id": 1}, {"id": 5, "bbox": [1397.4, 944.5, 409.7, 267.0], "category_id": 1}, {"id": 7, "bbox": [461.6, 90.9, 272.6, 242.0], "category_id": 1}, {"id": 8, "bbox": [791.4, 63.0, 128.7, 140.2], "category_id": 1}, {"id": 9, "bbox": [968.7, 31.6, 322.6, 347.4], "category_id": 1}, {"id": 10, "bbox": [1378.5, 43.0, 123.9, 182.7], "category_id": 1}, {"id": 11, "bbox": [1592.7, 2.7, 321.4, 447.8], "category_id": 1}, {"id": 12, "bbox": [1441.2, 505.4, 392.0, 341.5], "category_id": 1}, {"id": 13, "bbox": [747.7, 445.0, 394.1, 456.2], "category_id": 1}], "reactions": [{"reactants": [11], "conditions": [12, 3], "products": [13]}, {"reactants": [13], "conditions": [14, 2], "products": [15]}, {"reactants": [15], "conditions": [31, 4], "products": [17]}, {"reactants": [17], "conditions": [30, 5], "products": [16]}, {"reactants": [16], "conditions": [27, 29], "products": [8]}, {"reactants": [8], "conditions": [28, 21], "products": [7]}, {"reactants": [7], "conditions": [9, 20, 26], "products": [1]}], "caption": "Table 1. Optimization of Annulation To Form Fused Morpholine 7", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 515, 464, 530], "ImageBB": [82, 116, 787, 509]}, "diagram_type": "multiple"}, {"id": 1493, "width": 1348, "height": 1100, "file_name": "ol501165h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [574.1, 746.0, 261.9, 258.2], "category_id": 1}, {"id": 1, "bbox": [221.0, 475.0, 286.6, 211.8], "category_id": 1}, {"id": 2, "bbox": [830.88, 130.0, 318.7, 261.0], "category_id": 1}, {"id": 3, "bbox": [273.1, 154.0, 266.9, 210.7], "category_id": 1}, {"id": 4, "bbox": [337.0, 25.6, 170.0, 52.4], "category_id": 1}, {"id": 5, "bbox": [555.0, 148.0, 269.0, 219.2], "category_id": 1}, {"id": 8, "bbox": [581.0, 475.0, 247.0, 179.0], "category_id": 1}, {"id": 9, "bbox": [887.0, 437.0, 258.0, 206.0], "category_id": 1}, {"id": 10, "bbox": [273.0, 716.0, 250.0, 213.0], "category_id": 1}, {"id": 13, "bbox": [880.0, 743.0, 262.0, 225.7], "category_id": 1}], "reactions": [{"reactants": [23, 4], "conditions": [9, 8], "products": [10]}], "caption": "Table 1. Cyclocarbopalladation/Stille Coupling", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 347, 110], "ImageBB": [82, 116, 419, 391]}, "diagram_type": "single"}, {"id": 1494, "width": 1348, "height": 1052, "file_name": "ol4017854-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [165.87, 4.87, 215.23, 211.83], "category_id": 1}, {"id": 1, "bbox": [988.9, 1.0, 193.9, 227.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [5, 4], "products": [1]}], "caption": "Table 1. Conditions Optimization", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 617, 100], "ImageBB": [436, 112, 773, 375]}, "diagram_type": "single"}, {"id": 1495, "width": 1348, "height": 492, "file_name": "jo971595s-Table-c2.png", "license": 0, "bboxes": [{"id": 1, "bbox": [669.0, 8.0, 318.0, 145.0], "category_id": 1}, {"id": 2, "bbox": [1028.0, 9.0, 289.0, 153.0], "category_id": 1}, {"id": 3, "bbox": [31.0, 4.0, 333.0, 144.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [7], "products": [2, 3]}], "caption": "Table 2. Synperiplanar versus Antiperiplanar Attack in                the Radical Reductiona ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [441, 49, 772, 74], "ImageBB": [438, 79, 775, 202]}, "diagram_type": "single"}, {"id": 1496, "width": 1032, "height": 1784, "file_name": "jo502752u-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [680.0, 0.0, 168.0, 106.0], "category_id": 1}, {"id": 1, "bbox": [387.0, 1544.0, 247.0, 126.0], "category_id": 1}, {"id": 2, "bbox": [723.7, 730.6, 198.3, 155.6], "category_id": 1}, {"id": 3, "bbox": [764.6, 1309.2, 202.4, 154.0], "category_id": 1}, {"id": 4, "bbox": [348.8, 1038.8, 275.2, 159.6], "category_id": 1}, {"id": 5, "bbox": [42.0, 719.0, 215.1, 166.7], "category_id": 1}, {"id": 6, "bbox": [675.0, 394.0, 245.5, 150.5], "category_id": 1}, {"id": 7, "bbox": [64.8, 1546.4, 187.1, 116.4], "category_id": 1}, {"id": 8, "bbox": [648.0, 1568.6, 348.3, 95.1], "category_id": 1}, {"id": 9, "bbox": [648.0, 1023.0, 273.3, 181.4], "category_id": 1}, {"id": 10, "bbox": [76.5, 1307.4, 208.8, 153.3], "category_id": 1}, {"id": 11, "bbox": [420.3, 1309.4, 208.4, 153.0], "category_id": 1}, {"id": 12, "bbox": [3.2, 1034.7, 278.6, 161.3], "category_id": 1}, {"id": 13, "bbox": [395.0, 397.0, 228.2, 149.4], "category_id": 1}, {"id": 14, "bbox": [12.0, 394.0, 247.4, 156.8], "category_id": 1}, {"id": 16, "bbox": [357.0, 724.4, 269.0, 147.6], "category_id": 1}, {"id": 17, "bbox": [60.2, 170.8, 204.0, 151.2], "category_id": 1}, {"id": 18, "bbox": [681.0, 166.8, 239.4, 161.6], "category_id": 1}, {"id": 20, "bbox": [352.0, 169.0, 271.5, 155.4], "category_id": 1}, {"id": 37, "bbox": [153.1, 42.0, 130.9, 40.0], "category_id": 1}], "reactions": [{"reactants": [39], "conditions": [9, 21], "products": [0]}], "caption": "Table 2. KOtBu-Promoted Hydration of the Nitriles", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 90, 743, 110], "ImageBB": [488, 116, 746, 562]}, "diagram_type": "single"}, {"id": 1497, "width": 1344, "height": 468, "file_name": "jo2008675-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [980.0, 3.0, 361.0, 259.0], "category_id": 1}, {"id": 3, "bbox": [386.1, 87.3, 311.9, 127.6], "category_id": 1}, {"id": 5, "bbox": [9.1, 35.0, 339.5, 222.0], "category_id": 1}], "reactions": [{"reactants": [8, 6], "conditions": [0, 2], "products": [1]}], "caption": "Table 2. Reaction Scopes of 2-Hydroxyaryl-r,\u03b2-unsaturated Ketones in the Domino Reactiona ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 403, 122], "ImageBB": [71, 133, 407, 250]}, "diagram_type": "single"}, {"id": 1498, "width": 1352, "height": 632, "file_name": "ol701624y-Table-c6.png", "license": 0, "bboxes": [{"id": 1, "bbox": [852.0, 0.0, 354.0, 251.2], "category_id": 1}, {"id": 3, "bbox": [150.8, 2.0, 366.2, 326.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [2, 6], "products": [3]}], "caption": "Table 6.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 260, 486, 273], "ImageBB": [439, 276, 777, 434]}, "diagram_type": "single"}, {"id": 1499, "width": 2816, "height": 1832, "file_name": "op900102a-Table-c15.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1803.0, 803.0, 496.0, 124.0], "category_id": 1, "id": 1}, {"bbox": [1826.0, 1135.0, 461.0, 417.0], "category_id": 1, "id": 2}, {"bbox": [569.0, 832.0, 348.0, 68.0], "category_id": 1, "id": 3}, {"bbox": [1056.0, 836.0, 339.0, 68.0], "category_id": 1, "id": 7}, {"bbox": [1471.0, 766.0, 259.0, 198.0], "category_id": 1, "id": 8}, {"bbox": [1068.0, 1204.0, 320.0, 287.0], "category_id": 1, "id": 12}, {"bbox": [516.0, 1301.0, 452.0, 84.0], "category_id": 1, "id": 13}, {"bbox": [1488.0, 1249.0, 228.0, 187.0], "category_id": 1, "id": 15}], "caption": "Table 15. Lab-scale prices of selected reagents and precursors of resin-based scavengersa", "pdf": {"Page": 11, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 45, 547, 59], "ImageBB": [58, 61, 762, 519]}}, {"id": 1500, "width": 448, "height": 276, "file_name": "op034024c-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [3.0, 1.0, 440.0, 212.0], "category_id": 1, "id": 1}], "caption": "Figure 1.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 441, 495, 455], "ImageBB": [552, 368, 664, 437]}}, {"id": 1501, "width": 1416, "height": 736, "file_name": "ol8027253-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [409.8, 215.3, 659.7, 481.2], "category_id": 1, "id": 0}], "caption": "Figure 1. Structure of bryostatin 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 935, 608, 950], "ImageBB": [408, 745, 762, 929]}}, {"id": 1502, "width": 1352, "height": 708, "file_name": "ol801791g-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [270.2, 116.3, 205.5, 188.8], "category_id": 1, "id": 4}, {"bbox": [788.1, 153.5, 214.2, 150.7], "category_id": 1, "id": 5}, {"bbox": [252.3, 424.9, 328.6, 259.1], "category_id": 1, "id": 6}, {"bbox": [763.1, 492.8, 337.7, 114.3], "category_id": 1, "id": 7}], "caption": "Figure 2. Carbocyclic intermediates in the synthesis of carbocyclic nucleosides. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 370, 393, 398], "ImageBB": [58, 186, 396, 363]}}, {"id": 1503, "width": 1352, "height": 904, "file_name": "ol061715v-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [220.6, 140.5, 917.1, 763.5], "category_id": 1, "id": 0}], "caption": "Figure 2. X-ray crystal structure of 12a.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 376, 288, 389], "ImageBB": [73, 138, 411, 364]}}, {"id": 1504, "width": 1424, "height": 816, "file_name": "ol060868f-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [823.0, 385.0, 390.0, 342.0], "category_id": 1, "id": 1}, {"bbox": [256.0, 221.0, 471.0, 531.0], "category_id": 1, "id": 2}], "caption": "Figure 1. Iron-containing nucleoside analogues.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 874, 691, 887], "ImageBB": [424, 658, 780, 862]}}, {"id": 1505, "width": 1352, "height": 340, "file_name": "acs.orglett.5b02498-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [56.0, 47.0, 429.0, 233.0], "category_id": 1, "id": 0}, {"bbox": [528.0, 75.0, 323.0, 193.0], "category_id": 1, "id": 1}, {"bbox": [891.0, 100.0, 401.0, 170.0], "category_id": 1, "id": 2}], "caption": "Figure 1. Examples of eight-membered ethers possessing biological activities. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 594, 417, 622], "ImageBB": [82, 500, 420, 585]}}, {"id": 1506, "width": 1352, "height": 268, "file_name": "acs.oprd.5b00256-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [133.4, 39.1, 854.6, 228.9], "category_id": 1, "id": 0}], "caption": "Figure 1. Chemical structure of acotiamide.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 850, 295, 864], "ImageBB": [82, 773, 420, 840]}}, {"id": 1507, "width": 1344, "height": 776, "file_name": "ol401881n-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [163.0, 161.0, 636.0, 615.0], "category_id": 1, "id": 0}, {"bbox": [861.0, 561.0, 314.0, 165.0], "category_id": 1, "id": 1}], "caption": "Figure 1. ORTEP drawing of 2n.", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 266, 612, 279], "ImageBB": [437, 59, 773, 253]}}, {"id": 1508, "width": 1148, "height": 680, "file_name": "ol0067989-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 204.0, 343.0, 263.0], "category_id": 1, "id": 2}, {"bbox": [570.0, 148.0, 400.0, 318.0], "category_id": 1, "id": 3}], "caption": "Figure 1.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 597, 125, 610], "ImageBB": [124, 454, 411, 624]}}, {"id": 1509, "width": 912, "height": 896, "file_name": "jo9519672-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [18.0, 221.4, 189.5, 301.4], "category_id": 1, "id": 0}, {"bbox": [391.2, 3.8, 520.8, 663.0], "category_id": 1, "id": 3}], "caption": "Figure 1.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [63, 291, 120, 304], "ImageBB": [117, 55, 345, 279]}}, {"id": 1510, "width": 2820, "height": 1132, "file_name": "jo3026753-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1751.8, 86.8, 448.0, 344.2], "category_id": 1, "id": 1}, {"bbox": [560.0, 561.0, 500.4, 344.0], "category_id": 1, "id": 2}, {"bbox": [1133.6, 83.5, 509.4, 351.5], "category_id": 1, "id": 3}, {"bbox": [1735.0, 549.0, 498.0, 366.3], "category_id": 1, "id": 4}, {"bbox": [1176.4, 556.0, 392.3, 365.1], "category_id": 1, "id": 5}, {"bbox": [600.1, 90.0, 404.1, 340.7], "category_id": 1, "id": 10}], "caption": "Figure 2. Morphinans, their sulfur analogues, and proposed analogues of hydrocodone.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 685, 505, 699], "ImageBB": [82, 392, 787, 675]}}, {"id": 1511, "width": 2820, "height": 2260, "file_name": "acs.joc.5b00632-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [170.0, 21.5, 445.0, 209.5], "category_id": 1, "id": 1}, {"bbox": [1027.0, 27.3, 438.0, 199.7], "category_id": 1, "id": 2}, {"bbox": [1736.0, 21.4, 431.1, 227.6], "category_id": 1, "id": 3}, {"bbox": [875.6, 302.4, 464.6, 217.6], "category_id": 1, "id": 4}, {"bbox": [1855.0, 303.0, 368.6, 236.0], "category_id": 1, "id": 5}, {"bbox": [1815.0, 651.7, 412.5, 216.3], "category_id": 1, "id": 6}, {"bbox": [873.8, 654.0, 465.3, 210.0], "category_id": 1, "id": 7}, {"bbox": [1602.0, 991.0, 568.0, 298.2], "category_id": 1, "id": 8}, {"bbox": [1091.0, 1309.4, 448.0, 308.6], "category_id": 1, "id": 9}, {"bbox": [2225.45, 649.6, 416.47, 212.57], "category_id": 1, "id": 10}, {"bbox": [1348.83, 652.48, 468.89, 209.69], "category_id": 1, "id": 11}, {"bbox": [1363.39, 305.91, 454.33, 206.78], "category_id": 1, "id": 12}, {"bbox": [2269.14, 314.65, 369.87, 212.6], "category_id": 1, "id": 13}, {"bbox": [1078.0, 1012.0, 473.0, 294.0], "category_id": 1, "id": 16}, {"bbox": [170.0, 643.0, 452.0, 207.0], "category_id": 1, "id": 17}, {"bbox": [181.0, 296.0, 430.0, 206.0], "category_id": 1, "id": 18}, {"bbox": [549.0, 1265.0, 528.0, 343.0], "category_id": 1, "id": 27}, {"bbox": [1613.0, 1297.0, 476.0, 319.0], "category_id": 1, "id": 28}], "caption": "Figure 3. Energy-minimized structures and 1H NMR spectra for stereochemical assignment of 3Z-isomers.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 688, 599, 704], "ImageBB": [82, 116, 787, 681]}}, {"id": 1512, "width": 1356, "height": 920, "file_name": "acs.joc.5b01204-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [0.0, 584.31, 966.63, 284.34], "category_id": 1, "id": 0}, {"bbox": [39.34, 2.71, 341.89, 269.42], "category_id": 1, "id": 3}, {"bbox": [560.99, 4.07, 341.88, 268.06], "category_id": 1, "id": 4}, {"bbox": [99.04, 295.89, 770.59, 266.02], "category_id": 1, "id": 5}], "caption": "Scheme 3. Synthesis of Probe 5b", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 477, 636, 492], "ImageBB": [448, 498, 787, 728]}, "diagram_type": "multiple"}, {"id": 1513, "width": 2820, "height": 1096, "file_name": "acs.joc.5b02237-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1433.28, 616.57, 272.26, 274.13], "category_id": 1, "id": 1}, {"bbox": [804.1, 0.0, 272.27, 279.36], "category_id": 1, "id": 4}, {"bbox": [1958.06, 613.74, 276.5, 280.77], "category_id": 1, "id": 5}, {"bbox": [536.07, 613.74, 266.62, 275.13], "category_id": 1, "id": 9}, {"bbox": [1059.44, 620.8, 259.57, 245.5], "category_id": 1, "id": 10}, {"bbox": [1254.12, 0.0, 265.21, 280.77], "category_id": 1, "id": 11}], "caption": "Scheme 1. Photochemical Transformations of Stilbenes/Diarylethenes", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 476, 110], "ImageBB": [82, 116, 787, 390]}, "diagram_type": "multiple"}, {"id": 1514, "width": 1416, "height": 1020, "file_name": "acs.oprd.5b00144-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [451.93, 0.0, 401.64, 165.79], "category_id": 1, "id": 0}, {"bbox": [784.86, 252.94, 494.43, 291.9], "category_id": 1, "id": 1}, {"bbox": [1117.07, 662.46, 298.93, 230.97], "category_id": 1, "id": 3}, {"bbox": [534.1, 339.38, 201.88, 77.22], "category_id": 1, "id": 5}, {"bbox": [448.39, 667.42, 461.85, 226.01], "category_id": 1, "id": 7}, {"bbox": [1126.99, 0.0, 289.01, 165.79], "category_id": 1, "id": 8}], "caption": "Scheme 1. Initial Synthesis of 1, Lorcaserin", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 322, 110], "ImageBB": [82, 129, 436, 384]}, "diagram_type": "multiple"}, {"id": 1515, "width": 1356, "height": 536, "file_name": "jo200877k-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [752.28, 88.85, 186.54, 148.53], "category_id": 1, "id": 0}, {"bbox": [361.55, 61.72, 183.16, 155.99], "category_id": 1, "id": 2}, {"bbox": [0.0, 73.93, 136.35, 160.73], "category_id": 1, "id": 3}, {"bbox": [1024.29, 61.72, 139.06, 78.67], "category_id": 1, "id": 5}, {"bbox": [1191.84, 198.04, 164.16, 185.83], "category_id": 1, "id": 7}, {"bbox": [1191.84, 2.71, 153.98, 126.15], "category_id": 1, "id": 9}], "caption": "Scheme 2. Photolysis of 4", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 233, 219, 248], "ImageBB": [71, 258, 410, 392]}, "diagram_type": "single"}, {"id": 1516, "width": 2820, "height": 1108, "file_name": "jo501180a-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [129.78, 4.23, 465.54, 311.61], "category_id": 1, "id": 0}, {"bbox": [898.62, 0.0, 789.99, 313.02], "category_id": 1, "id": 1}, {"bbox": [2076.56, 0.0, 619.3, 315.84], "category_id": 1, "id": 3}, {"bbox": [0.0, 655.66, 739.21, 317.26], "category_id": 1, "id": 4}, {"bbox": [1067.9, 664.12, 605.2, 317.26], "category_id": 1, "id": 7}, {"bbox": [2075.15, 668.35, 744.85, 314.44], "category_id": 1, "id": 9}], "caption": "Scheme 2. Synthesis of Regioisomerically Pure 1,7-Dibromo-Substituted Compounds 4\u22128 from 3", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 583, 630, 598], "ImageBB": [82, 605, 787, 882]}, "diagram_type": "tree"}, {"id": 1517, "width": 1276, "height": 1140, "file_name": "jo961049j-Scheme-c8.png", "license": 0, "bboxes": [{"bbox": [783.22, 0.0, 479.38, 251.48], "category_id": 1, "id": 1}, {"bbox": [7.66, 30.64, 477.46, 290.41], "category_id": 1, "id": 2}, {"bbox": [764.71, 755.08, 478.74, 280.92], "category_id": 1, "id": 3}, {"bbox": [7.66, 792.1, 430.23, 287.23], "category_id": 1, "id": 6}], "caption": "Scheme 8", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [572, 603, 635, 617], "ImageBB": [447, 623, 766, 908]}, "diagram_type": "tree"}, {"id": 1518, "width": 1352, "height": 644, "file_name": "ol0513995-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [848.8, 2.71, 499.14, 150.13], "category_id": 1, "id": 0}, {"bbox": [879.24, 367.9, 450.44, 154.87], "category_id": 1, "id": 1}, {"bbox": [85.89, 57.48, 420.69, 94.01], "category_id": 1, "id": 2}, {"bbox": [4.06, 367.9, 512.66, 206.94], "category_id": 1, "id": 3}], "caption": "Scheme 1", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 75, 265, 88], "ImageBB": [73, 93, 411, 254]}, "diagram_type": "tree"}, {"id": 1519, "width": 1348, "height": 956, "file_name": "ol800523j-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [758.63, 254.32, 542.17, 116.71], "category_id": 1, "id": 0}, {"bbox": [720.19, 665.15, 540.82, 124.13], "category_id": 1, "id": 1}, {"bbox": [38.44, 32.38, 238.71, 89.72], "category_id": 1, "id": 8}, {"bbox": [38.44, 431.74, 475.4, 400.04], "category_id": 1, "id": 9}, {"bbox": [441.02, 24.96, 323.68, 74.88], "category_id": 1, "id": 10}, {"bbox": [61.36, 263.09, 541.5, 111.99], "category_id": 1, "id": 11}], "caption": "Scheme 3. Trapping of Isomerization Intermediate", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [462, 242, 723, 257], "ImageBB": [425, 264, 762, 503]}, "diagram_type": "tree"}, {"id": 1520, "width": 1216, "height": 824, "file_name": "op050040t-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [911.24, 3.65, 206.21, 136.91], "category_id": 1, "id": 0}, {"bbox": [897.86, 558.6, 318.14, 177.68], "category_id": 1, "id": 1}, {"bbox": [55.36, 568.94, 315.1, 172.82], "category_id": 1, "id": 3}, {"bbox": [0.0, 68.15, 236.63, 74.85], "category_id": 1, "id": 4}, {"bbox": [775.59, 338.93, 235.41, 77.28], "category_id": 1, "id": 5}], "caption": "Scheme 2. Formation of ester 4 in the oxidation of activated alcohols 2 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 361, 81], "ImageBB": [90, 85, 394, 291]}, "diagram_type": "tree"}, {"id": 1521, "width": 1416, "height": 1212, "file_name": "ja075824w-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [210.45, 141.65, 104.58, 246.61], "category_id": 1, "id": 2}, {"bbox": [369.84, 193.72, 140.88, 117.21], "category_id": 1, "id": 3}, {"bbox": [691.78, 141.65, 104.58, 215.04], "category_id": 1, "id": 4}, {"bbox": [874.84, 193.72, 155.08, 117.21], "category_id": 1, "id": 5}, {"bbox": [208.88, 686.1, 316.04, 369.7], "category_id": 1, "id": 6}, {"bbox": [857.48, 678.21, 125.1, 305.0], "category_id": 1, "id": 7}, {"bbox": [1038.97, 765.01, 140.87, 115.62], "category_id": 1, "id": 9}], "caption": "Figure 1. Proposed mechanism of the DMAP-catalyzed acylation.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 341, 381, 353], "ImageBB": [74, 35, 427, 338]}}, {"id": 1522, "width": 820, "height": 340, "file_name": "op900272d-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [7.0, 9.0, 809.0, 323.0], "category_id": 1, "id": 0}], "caption": "Figure 1. Structure of montelukast sodium (Singulair).", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 328, 728, 342], "ImageBB": [491, 240, 696, 325]}}, {"id": 1523, "width": 684, "height": 340, "file_name": "op900197r-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 0.0, 684.0, 334.0], "category_id": 1, "id": 0}], "caption": "Figure 1. DPP-4 Inhibitor ABT-279 (1).", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 338, 646, 352], "ImageBB": [508, 249, 679, 334]}}, {"id": 1524, "width": 2556, "height": 568, "file_name": "op9001643-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [2126.3, 2.6, 427.7, 222.6], "category_id": 1, "id": 0}, {"bbox": [6.0, 1.0, 432.4, 215.0], "category_id": 1, "id": 1}, {"bbox": [2069.2, 336.6, 256.7, 164.9], "category_id": 1, "id": 2}, {"bbox": [1039.5, 6.0, 432.9, 216.6], "category_id": 1, "id": 3}, {"bbox": [977.7, 340.0, 254.2, 162.4], "category_id": 1, "id": 4}, {"bbox": [226.3, 341.6, 255.3, 162.4], "category_id": 1, "id": 5}, {"bbox": [1342.2, 346.4, 248.6, 154.7], "category_id": 1, "id": 6}], "caption": "Figure 1. Biocatalytic reduction of 2,5-hexanedione with substrate-coupled cofactor regeneration.", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 192, 591, 206], "ImageBB": [90, 47, 729, 189]}}, {"id": 1525, "width": 1688, "height": 1004, "file_name": "op8002932-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [597.5, 633.1, 514.4, 294.8], "category_id": 1, "id": 0}, {"bbox": [683.3, 0.0, 349.7, 355.6], "category_id": 1, "id": 1}, {"bbox": [1264.9, 2.0, 423.1, 353.9], "category_id": 1, "id": 2}, {"bbox": [45.6, 0.0, 358.3, 355.4], "category_id": 1, "id": 3}], "caption": "Figure 1. Approved, commercially available MRI contrast agents based on 1,4,7,10-tetraazacyclododecane ligands, 1-3, and structure of protected tetraazamacrocyclic ligand 4. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 302, 761, 329], "ImageBB": [199, 48, 621, 299]}}, {"id": 1526, "width": 1196, "height": 892, "file_name": "op800136f-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [149.4, 647.5, 1022.7, 224.2], "category_id": 1, "id": 0}, {"bbox": [152.4, 306.2, 1035.2, 228.5], "category_id": 1, "id": 1}, {"bbox": [0.0, 1.24, 1196.0, 206.56], "category_id": 1, "id": 2}], "caption": "Figure 1", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 445, 476, 459], "ImageBB": [444, 219, 743, 442]}}, {"id": 1527, "width": 1284, "height": 1112, "file_name": "op700249f-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [792.0, 863.4, 367.0, 248.6], "category_id": 1, "id": 0}, {"bbox": [1.0, 405.0, 588.0, 383.0], "category_id": 1, "id": 1}, {"bbox": [939.0, 407.0, 342.0, 384.0], "category_id": 1, "id": 2}, {"bbox": [741.0, 563.0, 182.0, 228.0], "category_id": 1, "id": 3}, {"bbox": [964.0, 0.0, 315.0, 378.0], "category_id": 1, "id": 4}, {"bbox": [604.0, 0.0, 335.0, 380.0], "category_id": 1, "id": 5}], "caption": "Figure 2. Strategies for the preparation of peptides containing multiple triazole-linked carbohydrate moieties. ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 329, 393, 356], "ImageBB": [66, 47, 387, 325]}}, {"id": 1528, "width": 532, "height": 292, "file_name": "op7001886-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [3.0, 3.0, 529.0, 236.0], "category_id": 1, "id": 0}], "caption": "Figure 4", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 123, 476, 137], "ImageBB": [527, 46, 660, 119]}}, {"id": 1529, "width": 420, "height": 560, "file_name": "op700009t-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [4.0, 5.0, 413.0, 422.0], "category_id": 1, "id": 0}], "caption": "Figure 1. HTS hit - 10,11-dimethoxy-4-methyldibenzo[c,f]-2,7- naphthyridine-3,6-diamine. ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 421, 775, 449], "ImageBB": [555, 278, 660, 418]}}, {"id": 1530, "width": 1356, "height": 544, "file_name": "op500338d-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [797.2, 110.2, 551.6, 323.2], "category_id": 1, "id": 1}, {"bbox": [51.5, 111.2, 527.9, 324.9], "category_id": 1, "id": 2}], "caption": "Figure 2. Predicted reduction of ketone 1c.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 890, 662, 904], "ImageBB": [448, 744, 787, 880]}}, {"id": 1531, "width": 1096, "height": 316, "file_name": "op500250b-Figure-c5.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [680.6, 1.0, 412.9, 307.6], "category_id": 1, "id": 0}, {"bbox": [0.0, 7.0, 535.9, 309.0], "category_id": 1, "id": 1}], "caption": "Figure 5. N-acylurea side products.", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 269, 621, 283], "ImageBB": [480, 181, 754, 260]}}, {"id": 1532, "width": 912, "height": 460, "file_name": "op060204l-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 195.4, 910.0, 262.6], "category_id": 1, "id": 0}], "caption": "Figure 3. Explanation of the observed stereochemistry in (+)-25. ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 172, 409, 200], "ImageBB": [128, 54, 356, 169]}}, {"id": 1533, "width": 900, "height": 760, "file_name": "op0601464-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1.0, 0.0, 669.0, 367.0], "category_id": 1, "id": 0}], "caption": "Figure 2. Thioester-thion equilibrium of 5.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 264, 320, 278], "ImageBB": [202, 71, 427, 261]}}, {"id": 1534, "width": 1272, "height": 816, "file_name": "op0601316-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [970.0, 413.0, 159.0, 150.0], "category_id": 1, "id": 0}, {"bbox": [942.0, 14.0, 330.0, 244.0], "category_id": 1, "id": 1}, {"bbox": [1.0, 12.0, 275.0, 245.0], "category_id": 1, "id": 2}, {"bbox": [451.0, 548.0, 453.0, 268.0], "category_id": 1, "id": 3}, {"bbox": [1120.0, 288.0, 111.0, 110.0], "category_id": 1, "id": 4}, {"bbox": [189.0, 341.8, 162.0, 151.2], "category_id": 1, "id": 5}, {"bbox": [610.0, 5.0, 116.0, 120.6], "category_id": 1, "id": 6}], "caption": "Figure 4. Reaction scheme based on the postulated mecha- nism9 for BAL-catalyzed acyloin formation and cleavage. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 546, 775, 574], "ImageBB": [449, 339, 767, 543]}}, {"id": 1535, "width": 704, "height": 320, "file_name": "op050223f-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [6.0, 0.0, 698.0, 255.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Chemical structure of adapalene.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 277, 683, 291], "ImageBB": [520, 194, 696, 274]}}, {"id": 1536, "width": 1352, "height": 684, "file_name": "op050040t-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [929.1, 76.9, 201.3, 118.9], "category_id": 1, "id": 1}, {"bbox": [958.08, 510.96, 176.12, 115.84], "category_id": 1, "id": 2}, {"bbox": [342.2, 538.0, 205.8, 59.9], "category_id": 1, "id": 3}], "caption": "Figure 1. Tube reactor for the synthesis of activated aldehydes 3 from alcohols 2. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 227, 775, 255], "ImageBB": [439, 53, 777, 224]}}, {"id": 1537, "width": 904, "height": 488, "file_name": "op049950l-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [5.0, 2.0, 895.0, 364.0], "category_id": 1, "id": 1}], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 320, 495, 334], "ImageBB": [495, 194, 721, 316]}}, {"id": 1538, "width": 1356, "height": 708, "file_name": "op049889k-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [614.0, 16.0, 446.0, 341.0], "category_id": 1, "id": 3}, {"bbox": [688.0, 372.0, 337.0, 291.0], "category_id": 1, "id": 4}, {"bbox": [0.0, 113.0, 653.0, 489.0], "category_id": 1, "id": 5}, {"bbox": [1107.0, 2.0, 247.0, 206.0], "category_id": 1, "id": 6}], "caption": "Figure 2. Retrosynthesis of fiduxosin.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 233, 286, 247], "ImageBB": [73, 53, 412, 230]}}, {"id": 1539, "width": 632, "height": 460, "file_name": "op034198u-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [7.0, 12.0, 623.0, 417.0], "category_id": 1, "id": 0}], "caption": "Figure 3.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 285, 495, 299], "ImageBB": [529, 167, 687, 282]}}, {"id": 1540, "width": 1036, "height": 1928, "file_name": "op025620u-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [391.9, 98.0, 248.1, 287.0], "category_id": 1, "id": 0}, {"bbox": [8.0, 505.0, 397.0, 379.0], "category_id": 1, "id": 2}, {"bbox": [239.0, 1062.0, 561.0, 384.0], "category_id": 1, "id": 3}, {"bbox": [0.0, 1589.0, 185.0, 270.0], "category_id": 1, "id": 4}, {"bbox": [772.0, 4.0, 164.0, 273.0], "category_id": 1, "id": 9}], "caption": "Table 1", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 576, 486, 590], "ImageBB": [424, 72, 683, 554]}}, {"id": 1541, "width": 1068, "height": 388, "file_name": "op010097p-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [406.5, 3.9, 652.5, 343.1], "category_id": 1, "id": 0}, {"bbox": [4.0, 4.0, 260.0, 339.0], "category_id": 1, "id": 3}], "caption": "Figure 2.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 452, 495, 466], "ImageBB": [475, 348, 742, 445]}}, {"id": 1542, "width": 1148, "height": 368, "file_name": "op000086g-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [659.0, 74.0, 386.0, 252.0], "category_id": 1, "id": 0}, {"bbox": [6.0, 90.0, 386.0, 278.0], "category_id": 1, "id": 1}], "caption": "Figure 1.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 274, 129, 288], "ImageBB": [140, 103, 427, 195]}}, {"id": 1543, "width": 1352, "height": 804, "file_name": "ol901760a-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1040.0, 639.6, 256.9, 139.9], "category_id": 1, "id": 0}, {"bbox": [430.0, 412.4, 248.0, 165.6], "category_id": 1, "id": 1}, {"bbox": [747.4, 247.2, 239.6, 162.8], "category_id": 1, "id": 2}, {"bbox": [590.1, 326.4, 229.9, 148.6], "category_id": 1, "id": 3}, {"bbox": [52.0, 469.0, 294.9, 137.2], "category_id": 1, "id": 4}, {"bbox": [230.2, 117.0, 256.8, 185.8], "category_id": 1, "id": 5}, {"bbox": [934.1, 313.3, 263.8, 165.2], "category_id": 1, "id": 6}], "caption": "Figure 2. Free energy profile (kcal/mol, 298 K) for the concerted pathway from enynylpiridines E-1a, E-1b, and E-1c to the corre- sponding indolizines. ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 522, 393, 564], "ImageBB": [58, 315, 396, 516]}}, {"id": 1544, "width": 1352, "height": 876, "file_name": "ol802556f-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [889.4, 551.0, 173.0, 193.0], "category_id": 1, "id": 0}, {"bbox": [733.0, 360.0, 193.0, 193.0], "category_id": 1, "id": 1}, {"bbox": [800.4, 126.5, 152.5, 119.6], "category_id": 1, "id": 2}, {"bbox": [1202.0, 592.9, 104.0, 147.5], "category_id": 1, "id": 3}, {"bbox": [597.0, 657.5, 204.5, 101.1], "category_id": 1, "id": 4}, {"bbox": [91.9, 118.4, 199.9, 166.6], "category_id": 1, "id": 5}, {"bbox": [119.5, 383.3, 204.5, 263.2], "category_id": 1, "id": 6}], "caption": "Figure 1. Possible mechanism.", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 887, 219, 902], "ImageBB": [58, 661, 396, 880]}}, {"id": 1545, "width": 1352, "height": 1860, "file_name": "ol801919q-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [734.0, 356.0, 112.0, 377.0], "category_id": 1, "id": 0}, {"bbox": [208.0, 353.0, 110.0, 374.0], "category_id": 1, "id": 3}], "caption": "Figure 4. Cyclophane distribution at varying added [TCNE] and at fixed 1.03 mM overall cyclophane concentration, as affected by the presence of 1.03 mM methylviologen dihexafluorophosphate. The notations \u201c3\u201d, \u201c5\u201d, and \u201c6\u201d indicate the points and the lines corresponding to the total concentrations of these species. Points are experimental, and solid lines merely interpolate them. ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 517, 393, 601], "ImageBB": [58, 46, 396, 511]}}, {"id": 1546, "width": 1348, "height": 1392, "file_name": "ol801919q-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [186.4, 106.1, 965.3, 667.5], "category_id": 1, "id": 0}, {"bbox": [226.9, 864.3, 893.9, 527.7], "category_id": 1, "id": 1}], "caption": "Figure 2. Two views of the single-crystal X-ray structure of the pseudorotaxane complex 4b, between 3 and propylviologen di- hexafluorophosphate. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 751, 760, 793], "ImageBB": [425, 396, 762, 744]}}, {"id": 1547, "width": 1352, "height": 1148, "file_name": "ol801919q-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [227.5, 113.0, 893.4, 551.3], "category_id": 1, "id": 0}, {"bbox": [203.2, 722.4, 944.8, 425.6], "category_id": 1, "id": 1}], "caption": "Figure 1. Two views of the single-crystal X-ray structure of compound 3. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 612, 393, 640], "ImageBB": [58, 318, 396, 605]}}, {"id": 1548, "width": 1352, "height": 484, "file_name": "ol800086s-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 175.0, 206.0, 204.0], "category_id": 1, "id": 3}, {"bbox": [354.0, 210.0, 251.0, 166.0], "category_id": 1, "id": 5}, {"bbox": [620.0, 142.0, 300.0, 277.0], "category_id": 1, "id": 6}, {"bbox": [897.0, 143.0, 455.0, 267.0], "category_id": 1, "id": 7}], "caption": "Figure 1. Indolizidines bearing quaternary substituted stereo- centers. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 184, 775, 211], "ImageBB": [439, 51, 777, 172]}}, {"id": 1549, "width": 1344, "height": 1092, "file_name": "ol202880y-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [771.5, 160.9, 485.7, 374.3], "category_id": 1, "id": 2}, {"bbox": [88.3, 161.0, 491.5, 382.8], "category_id": 1, "id": 3}, {"bbox": [482.3, 651.7, 485.1, 385.3], "category_id": 1, "id": 4}], "caption": "Figure 1. Brevianamide E (1), iso-brevianamide E (iso-1), and deoxybrevianamide E (2). ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 561, 405, 588], "ImageBB": [71, 275, 407, 548]}}, {"id": 1550, "width": 2820, "height": 592, "file_name": "op500175v-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1781.0, 244.0, 411.0, 64.6], "category_id": 1, "id": 0}, {"bbox": [551.0, 73.0, 963.0, 112.0], "category_id": 1, "id": 1}, {"bbox": [1646.0, 0.0, 550.0, 229.0], "category_id": 1, "id": 2}], "caption": "Table 1. Solubility of Common Sodium, Potassium, and Calcium Inorganic Salts in Methanol (Grams/100 Grams Solvent) at 25 \u00b0Ca ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 269, 784, 300], "ImageBB": [82, 116, 787, 264]}}, {"id": 1551, "width": 1352, "height": 500, "file_name": "op400292m-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [73.0, 45.0, 308.0, 379.0], "category_id": 1, "id": 0}, {"bbox": [530.0, 183.0, 307.0, 245.0], "category_id": 1, "id": 1}, {"bbox": [965.0, 32.0, 312.0, 388.0], "category_id": 1, "id": 2}], "caption": "Figure 1. Building blocks for the synthesis of Kv1.5 ion channel blockers such as AZD-2502. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 739, 417, 767], "ImageBB": [82, 605, 420, 730]}}, {"id": 1552, "width": 1352, "height": 432, "file_name": "op400242j-Figure-c5.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [722.9, 34.3, 598.5, 350.8], "category_id": 1, "id": 2}, {"bbox": [20.1, 35.4, 704.9, 343.6], "category_id": 1, "id": 3}], "caption": "Figure 5. Self-condensation side products from chlorination.", "pdf": {"Page": 8, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 431, 376, 445], "ImageBB": [82, 314, 420, 422]}}, {"id": 1553, "width": 1356, "height": 512, "file_name": "op400242j-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [457.0, 109.0, 386.0, 343.0], "category_id": 1, "id": 0}, {"bbox": [849.0, 28.0, 506.0, 484.0], "category_id": 1, "id": 1}, {"bbox": [4.0, 121.0, 442.0, 304.0], "category_id": 1, "id": 2}], "caption": "Figure 2. Oligomers of \ufb02uoroindole 4.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 784, 638, 802], "ImageBB": [448, 650, 787, 778]}}, {"id": 1554, "width": 1352, "height": 392, "file_name": "op400215h-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [744.0, 43.0, 593.0, 303.0], "category_id": 1, "id": 0}, {"bbox": [18.0, 67.0, 638.0, 279.0], "category_id": 1, "id": 2}], "caption": "Figure 1. Structures of compounds A and 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 716, 300, 730], "ImageBB": [82, 609, 420, 707]}}, {"id": 1555, "width": 1352, "height": 316, "file_name": "op400179f-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [354.0, 38.0, 628.0, 237.0], "category_id": 1, "id": 0}], "caption": "Figure 1. Structure of the N-oxide impurity.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 901, 298, 915], "ImageBB": [82, 813, 420, 892]}}, {"id": 1556, "width": 1352, "height": 320, "file_name": "op400039d-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [395.4, 39.1, 554.3, 278.9], "category_id": 1, "id": 1}], "caption": "Figure 2. Impurity generated by reaction of Grignard reagent of 10 with 21. ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 773, 417, 801], "ImageBB": [82, 684, 420, 764]}}, {"id": 1557, "width": 2820, "height": 664, "file_name": "op300363s-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [546.9, 383.2, 112.5, 124.4], "category_id": 1, "id": 1}, {"bbox": [489.1, 0.0, 276.0, 218.5], "category_id": 1, "id": 2}, {"bbox": [2112.1, 60.3, 207.4, 377.2], "category_id": 1, "id": 3}], "caption": "Table 1. Yields of 7-ET for Flow Reactions Performed at Di\ufb00erent Reaction Temperatures and Residence Times with 1 equiv of DHF and 1.2 equiv of H2SO4 (Scheme 2)a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 436, 784, 466], "ImageBB": [82, 264, 787, 430]}}, {"id": 1558, "width": 1352, "height": 440, "file_name": "op200340c-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [22.4, 213.1, 381.4, 143.5], "category_id": 1, "id": 0}, {"bbox": [949.2, 42.3, 379.3, 321.3], "category_id": 1, "id": 1}, {"bbox": [513.5, 219.2, 385.1, 142.5], "category_id": 1, "id": 2}], "caption": "Figure 1. GABAB agonists under development or on the market.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 659, 398, 674], "ImageBB": [82, 539, 420, 649]}}, {"id": 1559, "width": 1356, "height": 1208, "file_name": "op200278q-Table-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1108.0, 83.0, 218.0, 99.0], "category_id": 1, "id": 0}, {"bbox": [392.0, 88.0, 172.0, 86.0], "category_id": 1, "id": 1}, {"bbox": [600.0, 88.0, 245.0, 89.0], "category_id": 1, "id": 2}, {"bbox": [873.0, 86.0, 208.0, 91.0], "category_id": 1, "id": 3}, {"bbox": [149.0, 172.0, 185.0, 81.0], "category_id": 1, "id": 4}, {"bbox": [142.0, 263.0, 220.0, 73.0], "category_id": 1, "id": 5}, {"bbox": [147.0, 336.0, 172.0, 97.0], "category_id": 1, "id": 6}, {"bbox": [154.0, 463.0, 185.0, 71.0], "category_id": 1, "id": 7}, {"bbox": [147.0, 541.0, 202.0, 84.0], "category_id": 1, "id": 8}, {"bbox": [142.0, 625.0, 207.0, 79.0], "category_id": 1, "id": 9}, {"bbox": [142.0, 711.0, 220.0, 117.0], "category_id": 1, "id": 10}, {"bbox": [144.0, 835.0, 205.0, 64.0], "category_id": 1, "id": 11}, {"bbox": [147.0, 899.0, 162.0, 96.0], "category_id": 1, "id": 12}, {"bbox": [154.0, 1007.0, 175.0, 71.0], "category_id": 1, "id": 13}, {"bbox": [147.0, 1081.0, 200.0, 111.0], "category_id": 1, "id": 14}], "caption": "Table 2. Suzuki Miyaura coupling of di\ufb00erent aryl chlorides run in MiniBlock mediated by SiliaCat DPP-Pda ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 405, 122], "ImageBB": [71, 133, 410, 435]}}, {"id": 1560, "width": 728, "height": 608, "file_name": "op200176f-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [2.0, 0.0, 679.8, 275.0], "category_id": 1, "id": 2}, {"bbox": [36.9, 276.0, 688.1, 282.0], "category_id": 1, "id": 3}], "caption": "Figure 4. Minor reductive alkylation products.", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 478, 660, 492], "ImageBB": [514, 313, 696, 465]}}, {"id": 1561, "width": 1352, "height": 748, "file_name": "op100113j-Table-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [], "caption": "Table 2", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 851, 471, 865], "ImageBB": [425, 866, 763, 1053]}}, {"id": 1562, "width": 1160, "height": 356, "file_name": "op100103v-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 3.0, 303.0, 281.0], "category_id": 1, "id": 1}, {"bbox": [860.7, 1.0, 297.3, 312.7], "category_id": 1, "id": 4}, {"bbox": [399.1, 2.0, 380.9, 254.8], "category_id": 1, "id": 5}], "caption": "Figure 1. Products of the reduction of the nitrophenoxyacetate 18.", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 138, 394, 152], "ImageBB": [82, 46, 372, 135]}}, {"id": 1563, "width": 572, "height": 492, "file_name": "op100072y-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [6.0, 9.0, 566.0, 407.0], "category_id": 1, "id": 0}], "caption": "Figure 1. Structure of target EP1 antagonist GSK269984B.", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 336, 749, 350], "ImageBB": [522, 210, 665, 333]}}, {"id": 1564, "width": 756, "height": 416, "file_name": "op100063h-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [4.0, 4.0, 748.0, 342.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Chemical structure of FU-23 (1).", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 332, 662, 346], "ImageBB": [499, 225, 688, 329]}}, {"id": 1565, "width": 1412, "height": 1332, "file_name": "op100031u-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [838.0, 25.0, 198.0, 217.0], "category_id": 1, "id": 1}, {"bbox": [1137.9, 2.0, 204.1, 266.0], "category_id": 1, "id": 3}], "caption": "Table 1. Ionic liquid phase-transfer catalysts", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 306, 60], "ImageBB": [58, 65, 411, 398]}}, {"id": 1566, "width": 1148, "height": 704, "file_name": "op100010n-Figure-c7.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1.0, 3.0, 555.0, 568.0], "category_id": 1, "id": 1}, {"bbox": [714.0, 9.0, 434.0, 566.0], "category_id": 1, "id": 3}], "caption": "Figure 7. Process impurities observed in the final step.", "pdf": {"Page": 10, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 861, 360, 875], "ImageBB": [83, 682, 370, 858]}}, {"id": 1567, "width": 1352, "height": 736, "file_name": "ol061985d-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [130.0, 441.0, 520.0, 271.0], "category_id": 1, "id": 0}, {"bbox": [700.0, 419.0, 523.0, 297.0], "category_id": 1, "id": 3}, {"bbox": [448.0, 146.0, 381.0, 222.0], "category_id": 1, "id": 4}], "caption": "Figure 1. Quinoidal oligothiophenes with dicyanomethylene terminals. ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 929, 409, 956], "ImageBB": [73, 739, 411, 923]}}, {"id": 1568, "width": 1296, "height": 1380, "file_name": "jo016363e-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [422.0, 111.0, 427.0, 232.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Experimental 13C NMR (100.6 MHz in CD2Cl2) signals of the aromatic region of 1 as a function of temperature (left). The assignment of the ortho and meta 13C lines was obtained by means of 2D correlations (gHSQC sequence) with the corresponding doublet and triplet 1H signals. On the right is shown the computer simulation with the reported rate constants. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 391, 775, 484], "ImageBB": [452, 35, 776, 380]}}, {"id": 1569, "width": 1348, "height": 572, "file_name": "jo0056489-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1056.0, 1.0, 135.0, 215.0], "category_id": 1, "id": 0}, {"bbox": [153.1, 2.0, 275.8, 207.1], "category_id": 1, "id": 1}, {"bbox": [673.4, 4.0, 119.6, 202.0], "category_id": 1, "id": 2}], "caption": "Table 1. Reaction of 2a-c and 3 in the Absence (A) and           in the Presence of (CH3)3SiOTf (B)a ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [78, 427, 405, 453], "ImageBB": [74, 461, 411, 604]}}, {"id": 1570, "width": 1352, "height": 376, "file_name": "acs.orglett.6b00222-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [732.0, 49.0, 517.0, 263.0], "category_id": 1, "id": 0}, {"bbox": [102.0, 43.0, 553.0, 243.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Structures of DPTAP and TPHA with IUPAC numbering.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 769, 417, 783], "ImageBB": [82, 666, 420, 760]}}, {"id": 1571, "width": 1352, "height": 528, "file_name": "acs.orglett.5b02983-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [862.27, 179.22, 404.53, 262.38], "category_id": 1, "id": 0}, {"bbox": [82.4, 47.0, 386.2, 413.0], "category_id": 1, "id": 1}, {"bbox": [469.16, 50.02, 601.34, 389.88], "category_id": 1, "id": 2}], "caption": "Figure 1. Representative examples of natural compounds having nonracemic chiral cyclohexane ring. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 707, 417, 735], "ImageBB": [82, 566, 420, 698]}}, {"id": 1572, "width": 1352, "height": 864, "file_name": "acs.orglett.5b02709-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [794.2, 45.0, 449.5, 364.5], "category_id": 1, "id": 0}, {"bbox": [743.3, 376.5, 594.9, 485.5], "category_id": 1, "id": 1}, {"bbox": [9.5, 47.0, 606.5, 482.2], "category_id": 1, "id": 2}], "caption": "Figure 1. Pyrrole-imidazole alkaloids.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 829, 263, 843], "ImageBB": [82, 604, 420, 820]}}, {"id": 1573, "width": 1352, "height": 896, "file_name": "acs.oprd.6b00128-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [992.0, 123.1, 359.0, 397.9], "category_id": 1, "id": 0}, {"bbox": [61.0, 572.0, 532.0, 235.0], "category_id": 1, "id": 3}, {"bbox": [711.0, 555.0, 473.0, 302.0], "category_id": 1, "id": 4}, {"bbox": [2.0, 150.0, 940.0, 316.0], "category_id": 1, "id": 5}], "caption": "Figure 1. (a) Amino acids in transport of imaging agents for tumor detection. (b) Large neutral amino acids (LAT1)\ue0d5transporter of melphalan and analogues. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 870, 417, 912], "ImageBB": [82, 637, 420, 861]}}, {"id": 1574, "width": 1220, "height": 1012, "file_name": "acs.oprd.6b00066-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [762.7, 5.0, 457.3, 311.3], "category_id": 1, "id": 0}, {"bbox": [4.0, 22.0, 458.0, 293.9], "category_id": 1, "id": 1}, {"bbox": [461.71, 568.11, 288.69, 318.59], "category_id": 1, "id": 2}], "caption": "Figure 1. Molecular structures of (a) 4,10-dinitro-2,6,8,12-tetraoxa- 4,10-diazaisowurtzitane (TEX); (b) hexanitrohexaazaisowurtzitane (HNIW, CL-20); (c) 1,4-diformyl-2,3,5,6-tetrahydroxypiperazine (DFTHP). ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 585, 784, 641], "ImageBB": [465, 323, 770, 576]}}, {"id": 1575, "width": 1356, "height": 476, "file_name": "acs.oprd.6b00011-Figure-c7.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [388.2, 48.2, 579.5, 400.7], "category_id": 1, "id": 0}], "caption": "Figure 7. Solubility of GDC-0084 in ternary solvent systems at 50 \u00b0C.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 871, 784, 889], "ImageBB": [448, 892, 787, 1011]}}, {"id": 1576, "width": 3396, "height": 1420, "file_name": "acs.oprd.5b00370-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [847.5, 622.9, 421.5, 388.1], "category_id": 1, "id": 2}, {"bbox": [1913.0, 626.9, 428.8, 330.7], "category_id": 1, "id": 3}, {"bbox": [1141.2, 281.7, 407.8, 332.3], "category_id": 1, "id": 4}, {"bbox": [1588.4, 325.9, 402.9, 329.5], "category_id": 1, "id": 5}, {"bbox": [2377.6, 853.9, 421.8, 338.4], "category_id": 1, "id": 7}], "caption": "Figure 2. HPLC-UV/vis chromatogram (215 nm) of the thebaine reduction with diimide at 10 bar and 120 \u00b0C in the presence of dimethyl sul\ufb01de (Table 3, entry 3). ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 383, 784, 414], "ImageBB": [10, 22, 859, 377]}}, {"id": 1577, "width": 1356, "height": 496, "file_name": "acs.oprd.5b00273-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [930.1, 40.0, 422.9, 291.0], "category_id": 1, "id": 0}, {"bbox": [2.0, 48.0, 432.0, 290.0], "category_id": 1, "id": 3}], "caption": "Figure 3. Proposed structures of unstable intermediates formed during the reduction of nitrobenzene by CO/H2O. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 820, 784, 849], "ImageBB": [448, 686, 787, 810]}}, {"id": 1578, "width": 1352, "height": 800, "file_name": "ol5007604-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [677.7, 186.0, 596.1, 614.0], "category_id": 1, "id": 0}, {"bbox": [76.0, 47.0, 406.0, 753.0], "category_id": 1, "id": 1}], "caption": "Figure 2. The attempt to close the ring via alkene metathesis was not successful. Also, changing the order in the reaction sequence, building up \ufb01rst the bisaryl ethylene glycol chain and then closing the macrocycle via Sonogashira coupling, did not lead to the desired product. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 284, 417, 360], "ImageBB": [82, 116, 420, 276]}}, {"id": 1579, "width": 1352, "height": 788, "file_name": "ol048273c-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [7.0, 141.0, 486.0, 547.0], "category_id": 1, "id": 1}, {"bbox": [809.0, 218.0, 538.0, 393.0], "category_id": 1, "id": 2}], "caption": "Figure 1. Natural (1, tellimagrandin I) and nonnatural (2, modula- tor of zebrafish cardiovascular development) biaryl-containing medium-ring compounds. ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 962, 775, 1003], "ImageBB": [439, 753, 777, 950]}}, {"id": 1580, "width": 1352, "height": 1504, "file_name": "ol035711r-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [127.0, 733.0, 481.0, 285.0], "category_id": 1, "id": 0}, {"bbox": [658.0, 460.0, 493.0, 182.0], "category_id": 1, "id": 2}, {"bbox": [648.0, 142.0, 432.0, 219.0], "category_id": 1, "id": 5}, {"bbox": [194.0, 144.0, 403.0, 221.0], "category_id": 1, "id": 6}, {"bbox": [656.0, 734.0, 522.0, 292.0], "category_id": 1, "id": 7}, {"bbox": [284.0, 1048.0, 682.0, 448.0], "category_id": 1, "id": 10}, {"bbox": [158.0, 453.0, 467.0, 188.0], "category_id": 1, "id": 13}], "caption": "Figure 2. Proline derivatives.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 531, 231, 544], "ImageBB": [73, 139, 411, 515]}}, {"id": 1581, "width": 1352, "height": 680, "file_name": "ol0356688-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [354.0, 0.0, 638.0, 235.0], "category_id": 1, "id": 1}], "caption": "Table 1. Photophysical Properties of 1, 2, and 13", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 244, 703, 257], "ImageBB": [439, 260, 777, 430]}}, {"id": 1582, "width": 1352, "height": 2268, "file_name": "ol025887d-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [143.0, 1369.4, 347.0, 263.6], "category_id": 1, "id": 0}, {"bbox": [596.0, 1389.0, 284.0, 252.0], "category_id": 1, "id": 1}, {"bbox": [159.0, 647.0, 531.0, 592.0], "category_id": 1, "id": 2}, {"bbox": [92.0, 232.0, 429.0, 411.0], "category_id": 1, "id": 3}, {"bbox": [888.0, 1359.0, 365.0, 412.0], "category_id": 1, "id": 4}, {"bbox": [554.0, 253.0, 348.0, 412.0], "category_id": 1, "id": 5}, {"bbox": [133.0, 1671.0, 487.0, 597.0], "category_id": 1, "id": 6}, {"bbox": [916.0, 372.0, 344.0, 252.0], "category_id": 1, "id": 7}], "caption": "Figure 1. Potential glycosylation stategies.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 842, 299, 855], "ImageBB": [73, 262, 411, 829]}}, {"id": 1583, "width": 1352, "height": 1308, "file_name": "ol016976d-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [117.8, 750.0, 247.9, 116.2], "category_id": 1, "id": 0}, {"bbox": [787.0, 144.5, 255.0, 267.5], "category_id": 1, "id": 1}, {"bbox": [785.5, 416.7, 271.5, 194.3], "category_id": 1, "id": 2}, {"bbox": [796.5, 747.8, 244.5, 136.7], "category_id": 1, "id": 3}, {"bbox": [797.0, 977.8, 242.2, 164.9], "category_id": 1, "id": 4}, {"bbox": [119.5, 969.3, 242.5, 159.7], "category_id": 1, "id": 5}, {"bbox": [118.5, 413.0, 261.2, 164.0], "category_id": 1, "id": 6}, {"bbox": [115.8, 146.5, 250.2, 229.0], "category_id": 1, "id": 7}], "caption": "Table 1. N-Formylation of N-Hydroxylamines with 2,2,2-Trifluoroethyl Formate (TFEF) ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 712, 104], "ImageBB": [439, 106, 777, 433]}}, {"id": 1584, "width": 1352, "height": 520, "file_name": "ol016867z-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [334.0, 137.0, 325.0, 329.0], "category_id": 1, "id": 1}, {"bbox": [731.0, 138.0, 316.0, 326.0], "category_id": 1, "id": 3}], "caption": "Figure 3. Schematic representation of the two reactive forms involved in the hydrolysis process. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 310, 775, 337], "ImageBB": [439, 168, 777, 298]}}, {"id": 1585, "width": 1352, "height": 900, "file_name": "ol0059899-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [71.6, 134.2, 994.4, 603.8], "category_id": 1, "id": 0}, {"bbox": [61.0, 544.3, 647.5, 334.7], "category_id": 1, "id": 1}], "caption": "Figure 1. Careful examination of the crystal structures of peptide- PapD complexes has resulted in the design of a rigid \u03b2-lactam framework. These compounds superimpose well with the two C-terminal amino acids (a), which allows hydrophobic interactions via the R-group and mediates a possibility of forming an imine with a lysine residue in the chaperone. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 474, 409, 557], "ImageBB": [73, 237, 411, 462]}}, {"id": 1586, "width": 1256, "height": 1292, "file_name": "jo9708497-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [332.7, 172.9, 513.3, 326.5], "category_id": 1, "id": 0}], "caption": "Figure 1. Inhibition of S. typhimurium sialidase by (()-5b. Double reciprocal plot with 2-O-(p-nitrophenyl)-R-D-N-acetyl- neuraminic acid at varying concentrations (100-2000 \u00b5M) with fixed concentrations of inhibitor (()-5b: (9) 0, (b); 0.4, and (4) 2 mM. Reactions were initiated with 3.6 \u00b5g of sialidase. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 355, 774, 421], "ImageBB": [462, 20, 776, 343]}}, {"id": 1587, "width": 1224, "height": 2424, "file_name": "jo962055i-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [806.0, 1993.0, 364.0, 309.0], "category_id": 1, "id": 0}, {"bbox": [465.0, 1609.0, 489.0, 252.0], "category_id": 1, "id": 1}, {"bbox": [237.0, 2033.0, 453.0, 255.0], "category_id": 1, "id": 2}, {"bbox": [919.0, 1157.0, 303.0, 309.0], "category_id": 1, "id": 6}, {"bbox": [241.0, 1197.0, 556.0, 220.0], "category_id": 1, "id": 7}], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 701, 496, 714], "ImageBB": [424, 83, 730, 689]}}, {"id": 1588, "width": 1012, "height": 1236, "file_name": "jo961901m-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [534.0, 753.0, 405.0, 376.0], "category_id": 1, "id": 0}, {"bbox": [0.0, 0.0, 427.0, 551.0], "category_id": 1, "id": 1}, {"bbox": [30.0, 783.0, 307.0, 292.0], "category_id": 1, "id": 2}, {"bbox": [519.66, 10.03, 490.0, 554.1], "category_id": 1, "id": 3}], "caption": "Figure 2.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 875, 496, 888], "ImageBB": [481, 555, 734, 864]}}, {"id": 1589, "width": 1352, "height": 296, "file_name": "jo401318g-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [696.2, 40.1, 325.4, 194.9], "category_id": 1, "id": 1}, {"bbox": [328.3, 41.0, 323.7, 197.9], "category_id": 1, "id": 2}], "caption": "Figure 1. Comparison of phosphines 1 and 2.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 733, 307, 747], "ImageBB": [82, 650, 420, 724]}}, {"id": 1590, "width": 1352, "height": 488, "file_name": "jo401195c-Figure-c5.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [545.0, 50.1, 255.1, 264.9], "category_id": 1, "id": 0}, {"bbox": [913.0, 49.0, 255.9, 268.0], "category_id": 1, "id": 1}, {"bbox": [186.0, 48.3, 254.0, 261.7], "category_id": 1, "id": 2}], "caption": "Figure 5. KR of the racemic monoacetylated substrates 2, 22, and 23.", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 587, 417, 601], "ImageBB": [82, 456, 420, 578]}}, {"id": 1591, "width": 3396, "height": 2808, "file_name": "jo401195c-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [686.9, 1781.0, 762.6, 407.0], "category_id": 1, "id": 0}, {"bbox": [1967.0, 292.0, 877.1, 389.0], "category_id": 1, "id": 1}, {"bbox": [1746.2, 1285.5, 1069.5, 413.6], "category_id": 1, "id": 2}, {"bbox": [579.4, 1290.1, 1072.3, 420.8], "category_id": 1, "id": 3}, {"bbox": [628.1, 306.0, 452.8, 347.4], "category_id": 1, "id": 4}, {"bbox": [694.3, 801.3, 874.8, 398.7], "category_id": 1, "id": 5}, {"bbox": [1874.9, 790.3, 923.0, 404.2], "category_id": 1, "id": 9}, {"bbox": [1269.2, 2348.3, 1024.8, 418.3], "category_id": 1, "id": 12}, {"bbox": [1613.6, 1799.5, 1177.5, 347.8], "category_id": 1, "id": 18}, {"bbox": [1313.0, 348.0, 543.0, 305.0], "category_id": 1, "id": 19}], "caption": "Figure 3. Starting sequences for the search of a selective acyl transfer catalyst.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 734, 462, 748], "ImageBB": [10, 22, 859, 724]}}, {"id": 1592, "width": 3396, "height": 1312, "file_name": "jo400755q-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1166.0, 289.0, 290.0, 217.0], "category_id": 1, "id": 0}, {"bbox": [1470.0, 324.0, 316.0, 179.0], "category_id": 1, "id": 1}, {"bbox": [1800.0, 300.0, 382.0, 209.0], "category_id": 1, "id": 2}, {"bbox": [836.0, 856.0, 240.0, 313.0], "category_id": 1, "id": 3}, {"bbox": [2185.0, 292.0, 371.0, 226.0], "category_id": 1, "id": 4}, {"bbox": [2292.0, 625.0, 232.0, 194.0], "category_id": 1, "id": 5}, {"bbox": [1815.0, 601.0, 406.0, 180.0], "category_id": 1, "id": 6}, {"bbox": [1207.0, 839.0, 373.0, 376.0], "category_id": 1, "id": 7}, {"bbox": [830.0, 306.0, 333.0, 211.0], "category_id": 1, "id": 8}, {"bbox": [842.0, 578.0, 304.0, 203.0], "category_id": 1, "id": 9}, {"bbox": [1175.0, 544.0, 324.0, 240.0], "category_id": 1, "id": 10}, {"bbox": [1505.0, 567.0, 264.0, 214.0], "category_id": 1, "id": 11}, {"bbox": [2197.0, 845.0, 301.0, 347.0], "category_id": 1, "id": 12}, {"bbox": [1719.0, 908.0, 365.0, 278.0], "category_id": 1, "id": 13}], "caption": "Figure 1. Examples of di\ufb00erent diverse directing groups for C\u2212H activation reactions.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 359, 500, 373], "ImageBB": [10, 22, 859, 350]}}, {"id": 1593, "width": 3396, "height": 1536, "file_name": "jo4007046-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [821.0, 328.0, 784.0, 406.0], "category_id": 1, "id": 0}, {"bbox": [1016.0, 988.0, 452.0, 473.7], "category_id": 1, "id": 1}, {"bbox": [1840.2, 320.8, 731.3, 531.0], "category_id": 1, "id": 2}, {"bbox": [1947.0, 949.0, 474.0, 497.4], "category_id": 1, "id": 3}], "caption": "Figure 1. Geometries, spin densities, and ESP atomic charges (in parentheses) calculated in bulk MeOH at the CPCM-UB3LYP/6-311+G(2d,p)// UB3LYP/6-311+G(2d,p) level of theory for (a) 31 (Ar\u2212Cl bond length: 1.84 \u00c5) and (b) 31 upon stretching the Ar\u2212Cl bond up to 4.00 \u00c5. Bond lengths (\u00c5), angles (\u2220, in degrees), and dihedral angles (\u2220, in degrees) for (c) 11+ and (d) 31+. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 415, 784, 457], "ImageBB": [10, 22, 859, 406]}}, {"id": 1594, "width": 2820, "height": 856, "file_name": "jo400461c-Table-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [430.5, 57.6, 459.5, 181.3], "category_id": 1, "id": 0}], "caption": "Table 1. C\u2212S Fragmentation Products and Yields in the 3-CN-NMQ+ Photosensitized Oxidation of Alkyl Phenyl Sulfoxides (1\u2212 4) in N2-Saturated CD3CNa ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 92, 784, 125], "ImageBB": [82, 131, 787, 345]}}, {"id": 1595, "width": 1356, "height": 1336, "file_name": "jo201996w-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [760.0, 40.0, 576.0, 445.0], "category_id": 1, "id": 2}, {"bbox": [23.0, 36.0, 452.0, 310.0], "category_id": 1, "id": 3}], "caption": "Figure 3. Absorption spectra of the disubstitued tris- and tetra-ortho- azobenzenes in chloroform. ", "pdf": {"Page": 7, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [70, 756, 405, 784], "ImageBB": [69, 413, 408, 747]}}, {"id": 1596, "width": 1352, "height": 912, "file_name": "jo201654h-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [158.0, 40.6, 1046.1, 871.4], "category_id": 1, "id": 0}], "caption": "Figure 1. Interfragment HMBC correlations observed for scabellone B (3). ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [436, 769, 771, 797], "ImageBB": [436, 532, 774, 760]}}, {"id": 1597, "width": 1116, "height": 232, "file_name": "jo201098c-Figure-c6.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [761.0, 2.0, 350.0, 225.0], "category_id": 1, "id": 0}, {"bbox": [374.0, 10.0, 346.0, 214.0], "category_id": 1, "id": 1}, {"bbox": [5.0, 4.0, 346.0, 225.0], "category_id": 1, "id": 2}], "caption": "Figure 6. Free rotation of the ethyl substituent does not average out the environment for the two methylene protons HA and HB. The bold line represents a side view of benziporphyrinoid system 24, and the methyl and hydroxyl units for the tertiary alcohol moiety di\ufb00erentiate between the two faces of the macrocycle. Each consecutive Newman projection represents a 120\u00b0 rotation about the benziporphyrin CH2 bond. The same analysis also applies to structures 26, 28, and 30. ", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 404, 405, 501], "ImageBB": [100, 333, 379, 391]}}, {"id": 1598, "width": 2808, "height": 564, "file_name": "jo2008675-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1824.0, 196.0, 472.0, 204.0], "category_id": 1, "id": 0}, {"bbox": [1197.0, 138.0, 538.0, 323.0], "category_id": 1, "id": 1}, {"bbox": [520.0, 266.0, 571.0, 179.0], "category_id": 1, "id": 2}], "caption": "Figure 1. Natural products and pharmaceuticals that contain dihydrobenzofuran rings.", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 203, 482, 217], "ImageBB": [70, 56, 772, 197]}}, {"id": 1599, "width": 1352, "height": 376, "file_name": "ol7019636-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [334.0, 144.0, 218.0, 229.0], "category_id": 1, "id": 0}], "caption": "Figure 3. pKa values of some N-methylpiperidinium ions (ref 18).", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 218, 775, 232], "ImageBB": [439, 112, 777, 206]}}, {"id": 1600, "width": 1352, "height": 272, "file_name": "ol503587n-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [511.2, 45.0, 324.4, 217.5], "category_id": 1, "id": 1}], "caption": "Figure 2. Iron cyclone complex with benzylamine.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 913, 328, 927], "ImageBB": [82, 836, 420, 904]}}, {"id": 1601, "width": 1352, "height": 912, "file_name": "ol502842f-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [149.2, 47.6, 195.9, 381.3], "category_id": 1, "id": 0}, {"bbox": [867.9, 49.7, 302.3, 391.6], "category_id": 1, "id": 1}, {"bbox": [444.3, 47.6, 378.6, 268.1], "category_id": 1, "id": 2}, {"bbox": [47.7, 628.6, 296.6, 169.0], "category_id": 1, "id": 9}, {"bbox": [363.7, 631.5, 298.3, 161.7], "category_id": 1, "id": 10}, {"bbox": [1005.5, 575.4, 294.5, 287.6], "category_id": 1, "id": 11}, {"bbox": [679.0, 570.0, 281.0, 290.0], "category_id": 1, "id": 12}, {"bbox": [477.0, 323.0, 312.0, 117.0], "category_id": 1, "id": 13}], "caption": "Figure 1. Selected isoindolinones and tetrahydroisoquinolines.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 924, 380, 938], "ImageBB": [82, 686, 420, 914]}}, {"id": 1602, "width": 1352, "height": 2044, "file_name": "acs.oprd.5b00137-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [728.0, 42.07, 585.0, 333.0], "category_id": 1, "id": 0}, {"bbox": [104.6, 399.0, 604.4, 523.0], "category_id": 1, "id": 1}, {"bbox": [182.4, 957.8, 250.7, 170.2], "category_id": 1, "id": 2}, {"bbox": [49.0, 52.0, 597.0, 310.0], "category_id": 1, "id": 5}, {"bbox": [844.0, 440.0, 425.0, 408.0], "category_id": 1, "id": 6}], "caption": "Figure 4. Structures of the (a) polymer-bound Pd Tetrakis, (b) FiberCat 1001, (c) EnCat TPP30, and (d) SiliaCat immobilized catalysts used in the continuous Mizoroki\u2212Heck and Suzuki\u2212Miyaura cross-coupling reactions carried out under \ufb02ow in a ThalesNano X-Cube reactor. [Reproduced from ref 1, with kind permission. Copyright 2015 American Chemical Society.] ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 865, 417, 948], "ImageBB": [82, 345, 420, 856]}}, {"id": 1603, "width": 1352, "height": 392, "file_name": "acs.oprd.5b00023-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [326.0, 39.0, 692.0, 260.0], "category_id": 1, "id": 0}], "caption": "Figure 1. Chemical structure of S-2367 (1).", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 818, 297, 832], "ImageBB": [82, 711, 420, 809]}}, {"id": 1604, "width": 3396, "height": 1100, "file_name": "acs.joc.5b02345-Figure-c3.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [749.0, 287.0, 1890.0, 813.0], "category_id": 1, "id": 0}], "caption": "Figure 3. Thermal ellipsoidal plot of molecule 18 (30% probability). Hydrogen atoms have been omitted for clarity.", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 307, 647, 321], "ImageBB": [10, 22, 859, 297]}}, {"id": 1605, "width": 3396, "height": 1344, "file_name": "acs.joc.5b02237-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [1462.0, 274.0, 440.1, 378.6], "category_id": 1, "id": 0}, {"bbox": [1499.0, 742.0, 438.0, 350.0], "category_id": 1, "id": 1}], "caption": "Figure 1. 1H NMR monitoring of diarylethene 3d photoreaction under UV irradiation (\u03bb = 365 nm) in CDCl3 solution: before irradiation (A) and after 1 h irradiation (B). ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 365, 784, 395], "ImageBB": [10, 22, 859, 358]}}, {"id": 1606, "width": 1352, "height": 1124, "file_name": "acs.joc.5b01703-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [968.5, 550.2, 383.5, 359.9], "category_id": 1, "id": 6}, {"bbox": [517.4, 569.0, 358.0, 334.6], "category_id": 1, "id": 7}, {"bbox": [0.0, 569.0, 346.4, 402.0], "category_id": 1, "id": 8}, {"bbox": [903.7, 40.5, 393.0, 319.7], "category_id": 1, "id": 9}, {"bbox": [464.6, 37.3, 355.5, 313.7], "category_id": 1, "id": 10}, {"bbox": [2.8, 75.1, 358.5, 310.9], "category_id": 1, "id": 11}], "caption": "Figure 1. Representative Leucetta alkaloids.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1038, 292, 1052], "ImageBB": [82, 747, 420, 1028]}}, {"id": 1607, "width": 1352, "height": 1100, "file_name": "acs.joc.5b00632-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [144.06, 470.53, 332.08, 130.48], "category_id": 1, "id": 0}, {"bbox": [562.71, 675.38, 230.63, 199.43], "category_id": 1, "id": 7}, {"bbox": [122.42, 799.77, 426.09, 200.79], "category_id": 1, "id": 8}, {"bbox": [165.03, 47.32, 248.89, 118.31], "category_id": 1, "id": 9}, {"bbox": [761.56, 482.7, 297.59, 123.72], "category_id": 1, "id": 10}, {"bbox": [859.63, 853.18, 371.31, 124.39], "category_id": 1, "id": 11}, {"bbox": [775.08, 43.27, 237.4, 125.74], "category_id": 1, "id": 12}], "caption": "Scheme 3. Preparation of 2", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 202, 238, 217], "ImageBB": [82, 223, 420, 498]}, "diagram_type": "tree"}, {"id": 1608, "width": 2820, "height": 2340, "file_name": "acs.oprd.5b00209-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [1697.08, 584.09, 280.73, 166.48], "category_id": 1, "id": 0}, {"bbox": [1146.9, 577.03, 239.82, 213.04], "category_id": 1, "id": 1}, {"bbox": [1560.24, 18.34, 218.66, 218.68], "category_id": 1, "id": 2}, {"bbox": [935.3, 998.88, 238.41, 338.6], "category_id": 1, "id": 3}, {"bbox": [572.75, 550.23, 272.26, 234.2], "category_id": 1, "id": 4}, {"bbox": [277.91, 990.41, 225.71, 152.37], "category_id": 1, "id": 5}, {"bbox": [1939.72, 1189.34, 215.84, 111.46], "category_id": 1, "id": 6}, {"bbox": [1471.37, 1653.51, 502.21, 650.39], "category_id": 1, "id": 7}, {"bbox": [1237.19, 960.78, 647.51, 665.92], "category_id": 1, "id": 8}, {"bbox": [571.34, 981.95, 172.1, 205.98], "category_id": 1, "id": 9}, {"bbox": [2258.54, 18.34, 269.44, 225.74], "category_id": 1, "id": 10}, {"bbox": [541.71, 1704.3, 465.53, 555.87], "category_id": 1, "id": 11}, {"bbox": [311.72, 188.12, 196.64, 137.64], "category_id": 1, "id": 12}, {"bbox": [327.28, 0.0, 118.5, 110.05], "category_id": 1, "id": 13}, {"bbox": [2106.75, 370.71, 219.11, 188.21], "category_id": 1, "id": 14}, {"bbox": [792.82, 46.56, 260.98, 179.17], "category_id": 1, "id": 15}, {"bbox": [356.91, 1224.61, 434.5, 308.97], "category_id": 1, "id": 16}, {"bbox": [1124.1, 1772.02, 299.3, 124.15], "category_id": 1, "id": 17}, {"bbox": [327.28, 0.0, 119.91, 110.05], "category_id": 1, "id": 18}], "caption": "Scheme 2. Retrosynthetic Analysis of Compound 1 (Free Base of Pevonedistat)", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 707, 531, 722], "ImageBB": [82, 116, 787, 701]}, "diagram_type": "multiple"}, {"id": 1609, "width": 1352, "height": 728, "file_name": "acs.orglett.5b01872-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [878.5, 491.3, 257.3, 132.7], "category_id": 1, "id": 3}, {"bbox": [68.99, 3.2, 442.32, 324.04], "category_id": 1, "id": 4}, {"bbox": [72.0, 376.5, 586.3, 286.77], "category_id": 1, "id": 5}, {"bbox": [1028.03, 75.73, 252.95, 163.62], "category_id": 1, "id": 6}, {"bbox": [595.18, 22.31, 397.01, 256.25], "category_id": 1, "id": 9}, {"bbox": [767.76, 421.61, 120.32, 46.9], "category_id": 1, "id": 10}], "caption": "Scheme 1. Retrosynthesis of v-Coelenterazine", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 339, 111], "ImageBB": [82, 116, 420, 298]}, "diagram_type": "tree"}, {"id": 1610, "width": 1356, "height": 1784, "file_name": "acs.orglett.5b02003-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [813.18, 714.85, 383.83, 262.38], "category_id": 1, "id": 0}, {"bbox": [353.48, 1061.12, 668.57, 340.91], "category_id": 1, "id": 1}, {"bbox": [994.87, 1404.99, 334.1, 235.59], "category_id": 1, "id": 6}, {"bbox": [22.32, 1429.7, 332.94, 190.98], "category_id": 1, "id": 8}, {"bbox": [22.32, 49.08, 362.4, 208.84], "category_id": 1, "id": 9}, {"bbox": [969.39, 0.0, 364.19, 264.16], "category_id": 1, "id": 10}, {"bbox": [813.18, 374.83, 448.09, 262.38], "category_id": 1, "id": 11}, {"bbox": [22.32, 532.79, 374.0, 270.41], "category_id": 1, "id": 13}, {"bbox": [321.34, 38.38, 294.57, 173.13], "category_id": 1, "id": 16}, {"bbox": [353.48, 1435.95, 253.5, 170.45], "category_id": 1, "id": 18}], "caption": "Scheme 2. Gram-Scale Synthesis and Further Transformations of the Cycloadduct ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 703, 125], "ImageBB": [448, 131, 787, 577]}, "diagram_type": "tree"}, {"id": 1611, "width": 1352, "height": 744, "file_name": "acs.orglett.5b02498-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [864.36, 449.49, 343.58, 204.8], "category_id": 1, "id": 0}, {"bbox": [277.97, 0.0, 183.29, 137.21], "category_id": 1, "id": 1}, {"bbox": [277.97, 220.35, 292.86, 157.49], "category_id": 1, "id": 2}, {"bbox": [60.19, 227.78, 177.88, 138.57], "category_id": 1, "id": 3}, {"bbox": [785.9, 2.7, 248.22, 133.84], "category_id": 1, "id": 5}, {"bbox": [280.0, 488.69, 294.89, 157.49], "category_id": 1, "id": 6}, {"bbox": [61.55, 494.77, 179.9, 139.24], "category_id": 1, "id": 7}, {"bbox": [819.72, 180.47, 327.35, 222.38], "category_id": 1, "id": 8}], "caption": "Scheme 3. Control Experiments", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 262, 110], "ImageBB": [82, 116, 420, 302]}, "diagram_type": "multiple"}, {"id": 1612, "width": 1212, "height": 1112, "file_name": "ja040054z-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [0.0, 181.29, 375.3, 323.77], "category_id": 1, "id": 1}, {"bbox": [546.89, 726.36, 506.86, 319.53], "category_id": 1, "id": 2}, {"bbox": [503.84, 180.68, 524.45, 326.8], "category_id": 1, "id": 3}, {"bbox": [0.0, 731.82, 387.3, 317.7], "category_id": 1, "id": 7}], "caption": "Scheme 1", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 125, 76], "ImageBB": [124, 35, 427, 313]}, "diagram_type": "graph"}, {"id": 1613, "width": 1232, "height": 572, "file_name": "ja0551382-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [4.31, 19.1, 247.76, 178.08], "category_id": 1, "id": 0}, {"bbox": [696.43, 179.93, 483.8, 219.98], "category_id": 1, "id": 1}, {"bbox": [103.54, 372.19, 404.91, 194.1], "category_id": 1, "id": 2}, {"bbox": [824.62, 2.46, 403.68, 138.65], "category_id": 1, "id": 4}, {"bbox": [104.77, 182.4, 479.49, 222.44], "category_id": 1, "id": 7}, {"bbox": [335.27, 2.46, 427.72, 138.65], "category_id": 1, "id": 10}], "caption": "Scheme 1. Synthesis of E-Olefin Isosterea", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 457, 656, 470], "ImageBB": [454, 475, 762, 618]}, "diagram_type": "multiple"}, {"id": 1614, "width": 1356, "height": 692, "file_name": "ja200818w-Scheme-c8.png", "license": 0, "bboxes": [{"bbox": [4.07, 2.71, 282.19, 245.66], "category_id": 1, "id": 0}, {"bbox": [1029.04, 67.86, 281.51, 199.51], "category_id": 1, "id": 2}, {"bbox": [490.44, 350.84, 280.83, 197.47], "category_id": 1, "id": 3}], "caption": "Scheme 8. CO-Release and Regeneration of 25 and *25", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 474, 746, 489], "ImageBB": [436, 499, 775, 672]}, "diagram_type": "graph"}, {"id": 1615, "width": 1356, "height": 980, "file_name": "ja2031294-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1183.02, 118.76, 172.98, 244.97], "category_id": 1, "id": 2}, {"bbox": [1176.92, 582.24, 168.9, 239.55], "category_id": 1, "id": 3}, {"bbox": [757.03, 156.76, 371.73, 203.58], "category_id": 1, "id": 4}, {"bbox": [841.82, 619.57, 292.36, 201.54], "category_id": 1, "id": 5}, {"bbox": [0.0, 456.02, 356.81, 386.81], "category_id": 1, "id": 6}, {"bbox": [0.0, 0.0, 362.23, 389.52], "category_id": 1, "id": 7}], "caption": "Scheme 1. UP-Catalyzed (A) Phosphorolysis and (B) Arsenolysis of Uridine ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 369, 122], "ImageBB": [71, 133, 410, 378]}, "diagram_type": "multiple"}, {"id": 1616, "width": 2824, "height": 2448, "file_name": "ja204366b-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1271.07, 332.13, 390.86, 235.1], "category_id": 1, "id": 0}, {"bbox": [4.46, 323.31, 452.57, 235.11], "category_id": 1, "id": 1}, {"bbox": [680.92, 964.48, 572.15, 242.88], "category_id": 1, "id": 2}, {"bbox": [464.5, 1269.49, 484.84, 248.54], "category_id": 1, "id": 4}, {"bbox": [627.2, 679.23, 386.3, 244.3], "category_id": 1, "id": 6}, {"bbox": [779.81, 0.0, 412.51, 240.06], "category_id": 1, "id": 8}, {"bbox": [0.0, 0.0, 409.68, 240.06], "category_id": 1, "id": 11}, {"bbox": [0.0, 1938.84, 446.42, 251.35], "category_id": 1, "id": 12}, {"bbox": [0.0, 963.06, 453.48, 241.48], "category_id": 1, "id": 13}, {"bbox": [1385.3, 1854.11, 1108.13, 429.28], "category_id": 1, "id": 14}, {"bbox": [639.8, 316.31, 409.84, 249.95], "category_id": 1, "id": 15}, {"bbox": [1338.4, 679.23, 481.2, 245.71], "category_id": 1, "id": 16}, {"bbox": [1426.83, 965.89, 487.39, 234.41], "category_id": 1, "id": 17}, {"bbox": [456.3, 1588.63, 497.28, 242.89], "category_id": 1, "id": 20}, {"bbox": [1230.47, 1592.87, 566.49, 240.06], "category_id": 1, "id": 23}, {"bbox": [1967.9, 679.23, 491.62, 247.12], "category_id": 1, "id": 27}, {"bbox": [2119.06, 965.89, 480.32, 238.65], "category_id": 1, "id": 28}, {"bbox": [1230.47, 1273.73, 518.46, 240.06], "category_id": 1, "id": 31}, {"bbox": [556.61, 1951.55, 491.62, 228.76], "category_id": 1, "id": 38}, {"bbox": [2400.19, 326.2, 423.81, 255.59], "category_id": 1, "id": 39}, {"bbox": [1841.19, 338.01, 396.74, 232.16], "category_id": 1, "id": 41}], "caption": "Scheme 1. Synthesis of the First-Generation Self-Assembling Dendrons and of the Corresponding Dendronized PBI (3,4,5)12G1-m-PBI with m = 0, 1, 2, 3, 4 ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 714, 123], "ImageBB": [71, 133, 777, 745]}, "diagram_type": "tree"}, {"id": 1617, "width": 1704, "height": 1388, "file_name": "ja3058138-Scheme-c10.png", "license": 0, "bboxes": [{"bbox": [874.59, 946.87, 267.66, 121.02], "category_id": 1, "id": 0}, {"bbox": [596.7, 0.0, 314.54, 292.33], "category_id": 1, "id": 1}, {"bbox": [1060.42, 433.81, 322.22, 261.64], "category_id": 1, "id": 3}, {"bbox": [535.32, 395.45, 352.91, 321.15], "category_id": 1, "id": 4}, {"bbox": [135.54, 913.8, 397.23, 187.33], "category_id": 1, "id": 5}, {"bbox": [136.39, 46.0, 306.02, 248.89], "category_id": 1, "id": 6}, {"bbox": [643.58, 923.86, 179.86, 174.72], "category_id": 1, "id": 11}, {"bbox": [178.7, 399.71, 223.1, 316.2], "category_id": 1, "id": 12}, {"bbox": [1039.96, 23.01, 318.81, 266.76], "category_id": 1, "id": 14}], "caption": "Scheme 10. Retrosynthetic Analysis of Aspidospermidine", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 748, 770, 763], "ImageBB": [433, 780, 859, 1127]}, "diagram_type": "tree"}, {"id": 1618, "width": 1352, "height": 564, "file_name": "ja3058138-Scheme-c9.png", "license": 0, "bboxes": [{"bbox": [418.65, 4.06, 308.41, 249.6], "category_id": 1, "id": 1}], "caption": "Scheme 9. Kinetic Model of the Reaction", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 634, 316, 649], "ImageBB": [82, 655, 420, 796]}, "diagram_type": "tree"}, {"id": 1619, "width": 1252, "height": 1516, "file_name": "ja9612413-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [585.4, 1178.52, 459.52, 337.48], "category_id": 1, "id": 0}, {"bbox": [532.32, 4.55, 434.5, 336.72], "category_id": 1, "id": 1}, {"bbox": [0.0, 1102.68, 294.97, 76.6], "category_id": 1, "id": 2}, {"bbox": [734.78, 339.75, 301.04, 78.88], "category_id": 1, "id": 3}, {"bbox": [89.48, 714.39, 217.63, 194.15], "category_id": 1, "id": 4}, {"bbox": [532.32, 550.58, 507.29, 336.72], "category_id": 1, "id": 5}], "caption": "Scheme 1. Proposed Mechanism for Organolanthanide-Catalyzed Aminoolefin Hydroamination/Cyclization ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 50, 298, 92], "ImageBB": [85, 97, 398, 476]}, "diagram_type": "graph"}, {"id": 1620, "width": 1308, "height": 1472, "file_name": "jacs.5b05792-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [50.83, 534.6, 256.27, 151.7], "category_id": 1, "id": 0}, {"bbox": [78.1, 1112.5, 257.0, 135.9], "category_id": 1, "id": 4}, {"bbox": [1013.66, 1128.85, 271.09, 155.38], "category_id": 1, "id": 6}, {"bbox": [25.05, 238.58, 270.35, 117.82], "category_id": 1, "id": 7}, {"bbox": [761.72, 2.21, 271.09, 146.54], "category_id": 1, "id": 8}, {"bbox": [1021.76, 430.78, 262.99, 151.69], "category_id": 1, "id": 10}, {"bbox": [1093.96, 211.34, 191.53, 152.43], "category_id": 1, "id": 11}, {"bbox": [327.82, 248.16, 142.18, 110.45], "category_id": 1, "id": 12}, {"bbox": [724.15, 1130.33, 265.94, 153.9], "category_id": 1, "id": 14}, {"bbox": [776.45, 210.6, 262.99, 148.01], "category_id": 1, "id": 16}, {"bbox": [1021.76, 760.67, 262.99, 153.9], "category_id": 1, "id": 19}, {"bbox": [327.82, 37.55, 135.55, 110.46], "category_id": 1, "id": 20}, {"bbox": [1021.76, 430.78, 262.99, 151.69], "category_id": 1, "id": 21}, {"bbox": [1081.43, 29.45, 144.39, 110.46], "category_id": 1, "id": 22}, {"bbox": [25.05, 29.45, 265.2, 113.41], "category_id": 1, "id": 23}, {"bbox": [724.15, 428.57, 260.04, 148.01], "category_id": 1, "id": 26}, {"bbox": [724.15, 760.67, 260.04, 149.48], "category_id": 1, "id": 29}], "caption": "Scheme 3. Comparison between Asymmetric Permanganate Oxidation and Sharpless ADa ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 235, 417, 265], "ImageBB": [87, 272, 414, 640]}, "diagram_type": "multiple"}, {"id": 1621, "width": 2820, "height": 1624, "file_name": "jacs.5b07904-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [983.26, 761.44, 237.0, 249.58], "category_id": 1, "id": 0}, {"bbox": [2420.77, 954.62, 196.09, 188.95], "category_id": 1, "id": 1}, {"bbox": [538.89, 342.65, 173.52, 181.9], "category_id": 1, "id": 2}, {"bbox": [313.18, 349.7, 166.46, 149.47], "category_id": 1, "id": 3}, {"bbox": [403.46, 1198.56, 253.93, 256.64], "category_id": 1, "id": 4}, {"bbox": [909.9, 1294.45, 162.24, 142.42], "category_id": 1, "id": 5}, {"bbox": [1083.42, 38.07, 179.16, 194.59], "category_id": 1, "id": 6}, {"bbox": [1763.38, 650.04, 258.16, 249.59], "category_id": 1, "id": 7}, {"bbox": [2413.72, 305.99, 203.14, 197.41], "category_id": 1, "id": 8}, {"bbox": [2018.72, 1238.05, 232.77, 249.58], "category_id": 1, "id": 9}, {"bbox": [1763.38, 0.0, 239.82, 252.4], "category_id": 1, "id": 10}, {"bbox": [2011.67, 0.0, 244.05, 252.4], "category_id": 1, "id": 11}, {"bbox": [2011.67, 0.0, 245.46, 249.58], "category_id": 1, "id": 12}, {"bbox": [1297.24, 45.25, 180.77, 185.03], "category_id": 1, "id": 13}, {"bbox": [2028.8, 655.62, 244.59, 240.31], "category_id": 1, "id": 14}, {"bbox": [1340.8, 1280.35, 179.94, 188.95], "category_id": 1, "id": 15}, {"bbox": [876.59, 57.4, 156.11, 139.3], "category_id": 1, "id": 16}, {"bbox": [1125.8, 1278.94, 181.92, 190.36], "category_id": 1, "id": 17}, {"bbox": [1248.47, 760.03, 231.36, 250.99], "category_id": 1, "id": 18}, {"bbox": [399.23, 764.26, 248.28, 256.63], "category_id": 1, "id": 19}, {"bbox": [1760.56, 1233.82, 237.0, 253.81], "category_id": 1, "id": 20}], "caption": "Scheme 2. Enantioselectively Competing Reaction Pathways Involving Kinetic Resolution ((S)-Pathway) and Chiral Catalysis ((R)-Pathway) for the (S)-Pr-Mediated Asymmetric Hydrogenation of IP on Supported Pd Catalyst ", "pdf": {"Page": 8, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 784, 125], "ImageBB": [82, 131, 787, 537]}, "diagram_type": "graph"}, {"id": 1622, "width": 1148, "height": 1292, "file_name": "jo000585f-Scheme-c22.png", "license": 0, "bboxes": [{"bbox": [763.59, 1016.67, 271.55, 168.04], "category_id": 1, "id": 2}, {"bbox": [740.31, 3.88, 334.27, 209.41], "category_id": 1, "id": 3}, {"bbox": [0.0, 666.36, 287.07, 215.87], "category_id": 1, "id": 4}, {"bbox": [15.52, 82.73, 219.83, 75.62], "category_id": 1, "id": 5}, {"bbox": [374.36, 341.26, 336.85, 211.99], "category_id": 1, "id": 8}], "caption": "Scheme 22", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [570, 64, 641, 78], "ImageBB": [464, 84, 751, 407]}, "diagram_type": "multiple"}, {"id": 1623, "width": 1268, "height": 1716, "file_name": "jo001614p-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [420.63, 262.68, 266.97, 197.44], "category_id": 1, "id": 0}, {"bbox": [0.0, 1072.18, 237.78, 86.7], "category_id": 1, "id": 2}, {"bbox": [830.09, 739.97, 333.07, 189.71], "category_id": 1, "id": 3}, {"bbox": [0.0, 664.42, 363.11, 123.62], "category_id": 1, "id": 4}, {"bbox": [830.09, 265.25, 293.58, 194.87], "category_id": 1, "id": 5}, {"bbox": [0.0, 265.25, 265.25, 195.73], "category_id": 1, "id": 6}, {"bbox": [420.63, 664.42, 349.37, 123.62], "category_id": 1, "id": 7}, {"bbox": [1017.23, 48.93, 159.67, 141.64], "category_id": 1, "id": 8}, {"bbox": [13.73, 1416.41, 517.63, 299.59], "category_id": 1, "id": 12}, {"bbox": [529.65, 1044.71, 230.05, 145.07], "category_id": 1, "id": 13}, {"bbox": [420.63, 460.12, 289.28, 194.0], "category_id": 1, "id": 15}, {"bbox": [0.0, 463.55, 303.88, 190.57], "category_id": 1, "id": 17}, {"bbox": [73.82, 88.42, 161.39, 71.25], "category_id": 1, "id": 18}, {"bbox": [1018.95, 1044.71, 235.2, 145.07], "category_id": 1, "id": 24}, {"bbox": [830.09, 617.21, 391.91, 120.18], "category_id": 1, "id": 29}, {"bbox": [830.09, 470.42, 354.01, 126.19], "category_id": 1, "id": 30}, {"bbox": [545.96, 47.21, 184.56, 143.36], "category_id": 1, "id": 31}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 385, 636, 399], "ImageBB": [449, 405, 766, 834]}, "diagram_type": "multiple"}, {"id": 1624, "width": 1132, "height": 728, "file_name": "jo001614p-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [104.2, 457.7, 229.91, 199.96], "category_id": 1, "id": 1}, {"bbox": [855.09, 451.47, 195.37, 229.98], "category_id": 1, "id": 2}, {"bbox": [536.27, 5.1, 115.52, 47.01], "category_id": 1, "id": 3}, {"bbox": [769.58, 10.76, 161.92, 63.14], "category_id": 1, "id": 4}, {"bbox": [190.84, 45.88, 182.34, 143.32], "category_id": 1, "id": 6}], "caption": "Scheme 4", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [101, 83, 384, 265]}, "diagram_type": "graph"}, {"id": 1625, "width": 2488, "height": 1480, "file_name": "jo010230b-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1942.86, 843.79, 545.14, 201.62], "category_id": 1, "id": 0}, {"bbox": [497.5, 48.54, 358.8, 197.88], "category_id": 1, "id": 2}, {"bbox": [1286.94, 509.01, 507.81, 200.37], "category_id": 1, "id": 4}, {"bbox": [0.0, 59.74, 344.76, 131.92], "category_id": 1, "id": 6}, {"bbox": [0.0, 837.57, 158.07, 192.9], "category_id": 1, "id": 7}, {"bbox": [581.24, 426.87, 598.66, 339.76], "category_id": 1, "id": 9}, {"bbox": [441.84, 840.06, 430.64, 160.54], "category_id": 1, "id": 10}, {"bbox": [576.26, 1237.06, 883.68, 204.11], "category_id": 1, "id": 11}, {"bbox": [1712.6, 38.58, 358.45, 212.82], "category_id": 1, "id": 15}, {"bbox": [1202.31, 836.33, 632.26, 209.08], "category_id": 1, "id": 17}, {"bbox": [2290.11, 53.51, 182.95, 133.17], "category_id": 1, "id": 20}, {"bbox": [1942.86, 505.28, 545.14, 197.88], "category_id": 1, "id": 21}, {"bbox": [1138.83, 3.73, 420.68, 334.78], "category_id": 1, "id": 22}, {"bbox": [1641.66, 1228.35, 838.87, 204.11], "category_id": 1, "id": 24}], "caption": "Scheme 1. Synthesis of (5Z,8Z)-[10,11,12,12-2H]Tetradeca-5,8-dienoic Acid (13)a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [167, 63, 682, 77], "ImageBB": [115, 84, 737, 454]}, "diagram_type": "tree"}, {"id": 1626, "width": 2808, "height": 824, "file_name": "jo2001534-Scheme-c8.png", "license": 0, "bboxes": [{"bbox": [1210.85, 26.7, 325.89, 309.17], "category_id": 1, "id": 1}, {"bbox": [2211.0, 22.48, 328.7, 316.2], "category_id": 1, "id": 2}, {"bbox": [266.89, 43.56, 325.89, 451.1], "category_id": 1, "id": 5}, {"bbox": [1695.48, 22.48, 328.7, 316.2], "category_id": 1, "id": 6}, {"bbox": [733.25, 33.73, 334.32, 363.97], "category_id": 1, "id": 9}], "caption": "Scheme 8. Calculated 6-Exo-Trig Cyclization of 1d- as Model for the Formation of Type 8 Compounds from 5d-h for the Gas Phase and SCRF-CPCM(UAKS) Solution-Phase Simulations (THF) (Relative Energies: SCS-MP2/6-311\u00feG(d,p)//B3LYP/6- 31\u00feG(d,p) (Corrected for Zero-Point Energies) [kcal/mol]; See the Supporting Information for Optimized Structures) ", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 770, 138], "ImageBB": [71, 148, 773, 354]}, "diagram_type": "single"}, {"id": 1627, "width": 1344, "height": 1140, "file_name": "jo200666z-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [732.85, 667.43, 535.85, 379.09], "category_id": 1, "id": 2}, {"bbox": [83.37, 343.46, 290.45, 270.2], "category_id": 1, "id": 3}, {"bbox": [839.75, 373.71, 307.93, 229.2], "category_id": 1, "id": 5}, {"bbox": [810.84, 34.28, 379.2, 210.38], "category_id": 1, "id": 6}, {"bbox": [87.4, 674.16, 385.25, 352.2], "category_id": 1, "id": 8}, {"bbox": [83.37, 4.03, 328.1, 345.48], "category_id": 1, "id": 10}], "caption": "Scheme 1. Removing the Directing Group", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 308, 107], "ImageBB": [71, 117, 407, 402]}, "diagram_type": "multiple"}, {"id": 1628, "width": 1356, "height": 1408, "file_name": "jo302142v-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [1146.2, 929.7, 180.88, 192.69], "category_id": 1, "id": 0}, {"bbox": [454.23, 1098.09, 197.18, 203.55], "category_id": 1, "id": 2}, {"bbox": [90.85, 36.63, 320.42, 211.3], "category_id": 1, "id": 6}, {"bbox": [1079.58, 636.73, 192.25, 253.57], "category_id": 1, "id": 9}, {"bbox": [232.39, 1098.09, 201.41, 206.37], "category_id": 1, "id": 11}, {"bbox": [660.56, 1099.49, 194.37, 235.96], "category_id": 1, "id": 12}, {"bbox": [938.73, 901.0, 191.97, 228.08], "category_id": 1, "id": 13}, {"bbox": [521.83, 757.18, 245.78, 250.75], "category_id": 1, "id": 15}, {"bbox": [810.56, 0.0, 325.36, 249.34], "category_id": 1, "id": 17}, {"bbox": [16.9, 1098.09, 200.71, 205.67], "category_id": 1, "id": 18}], "caption": "Scheme 2. Synthesis of Aldehydes 5a\u2212c", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 422, 673, 437], "ImageBB": [448, 444, 787, 796]}, "diagram_type": "tree"}, {"id": 1629, "width": 1136, "height": 1488, "file_name": "jo960401q-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [0.0, 1129.21, 343.04, 262.77], "category_id": 1, "id": 0}, {"bbox": [785.8, 577.63, 346.76, 267.23], "category_id": 1, "id": 3}, {"bbox": [32.0, 6.7, 352.71, 238.94], "category_id": 1, "id": 6}, {"bbox": [52.09, 538.18, 310.3, 288.82], "category_id": 1, "id": 9}, {"bbox": [838.9, 0.0, 297.1, 259.04], "category_id": 1, "id": 10}, {"bbox": [828.21, 1142.61, 293.19, 249.37], "category_id": 1, "id": 11}], "caption": "Scheme 2", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [563, 521, 626, 535], "ImageBB": [455, 541, 739, 913]}, "diagram_type": "tree"}, {"id": 1630, "width": 1288, "height": 684, "file_name": "jo981125d-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [869.19, 365.28, 405.28, 192.62], "category_id": 1, "id": 1}, {"bbox": [0.0, 389.11, 402.7, 172.66], "category_id": 1, "id": 2}, {"bbox": [849.22, 5.8, 269.32, 189.4], "category_id": 1, "id": 4}, {"bbox": [440.72, 387.18, 399.48, 175.88], "category_id": 1, "id": 6}, {"bbox": [94.72, 38.01, 199.09, 165.57], "category_id": 1, "id": 9}, {"bbox": [467.78, 35.43, 248.71, 166.21], "category_id": 1, "id": 11}], "caption": "Scheme 3a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 203, 276, 217], "ImageBB": [81, 222, 403, 393]}, "diagram_type": "multiple"}, {"id": 1631, "width": 1200, "height": 1196, "file_name": "jo981397g-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [178.89, 670.31, 563.08, 436.27], "category_id": 1, "id": 0}, {"bbox": [958.08, 672.71, 241.92, 438.68], "category_id": 1, "id": 3}, {"bbox": [941.27, 54.61, 255.13, 359.46], "category_id": 1, "id": 5}, {"bbox": [662.13, 2.4, 205.3, 463.28], "category_id": 1, "id": 8}, {"bbox": [344.57, 14.4, 229.92, 437.48], "category_id": 1, "id": 10}, {"bbox": [0.0, 15.0, 230.52, 437.48], "category_id": 1, "id": 11}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [91, 84, 391, 383]}, "diagram_type": "tree"}, {"id": 1632, "width": 1328, "height": 1696, "file_name": "jo982024i-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [343.53, 424.21, 354.57, 400.46], "category_id": 1, "id": 1}, {"bbox": [413.94, 850.12, 309.6, 367.37], "category_id": 1, "id": 2}, {"bbox": [982.25, 426.76, 326.57, 318.16], "category_id": 1, "id": 3}, {"bbox": [966.99, 0.0, 359.65, 404.7], "category_id": 1, "id": 7}, {"bbox": [982.25, 853.51, 326.57, 315.62], "category_id": 1, "id": 8}, {"bbox": [0.0, 60.24, 305.36, 263.86], "category_id": 1, "id": 9}, {"bbox": [965.29, 1287.06, 329.96, 312.22], "category_id": 1, "id": 13}, {"bbox": [363.04, 0.0, 349.48, 404.7], "category_id": 1, "id": 16}, {"bbox": [295.18, 1275.18, 343.54, 313.07], "category_id": 1, "id": 17}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [77, 86, 409, 510]}, "diagram_type": "multiple"}, {"id": 1633, "width": 1244, "height": 1660, "file_name": "jo991681n-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [0.0, 823.77, 638.56, 499.91], "category_id": 1, "id": 2}, {"bbox": [577.94, 3.32, 434.28, 495.76], "category_id": 1, "id": 4}, {"bbox": [739.03, 818.79, 504.97, 502.4], "category_id": 1, "id": 5}], "caption": "Scheme 4a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [572, 63, 641, 77], "ImageBB": [453, 85, 764, 500]}, "diagram_type": "multiple"}, {"id": 1634, "width": 1188, "height": 1100, "file_name": "jo9919409-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [481.97, 0.0, 322.71, 256.79], "category_id": 1, "id": 0}, {"bbox": [755.95, 315.64, 325.67, 337.63], "category_id": 1, "id": 1}, {"bbox": [164.62, 324.55, 325.18, 337.04], "category_id": 1, "id": 2}], "caption": "Scheme 3", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 532, 270, 546], "ImageBB": [94, 551, 391, 826]}, "diagram_type": "multiple"}, {"id": 1635, "width": 1144, "height": 656, "file_name": "ol0069002-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [755.42, 27.48, 388.58, 242.77], "category_id": 1, "id": 2}, {"bbox": [231.78, 2.29, 358.25, 245.06], "category_id": 1, "id": 3}, {"bbox": [57.8, 351.56, 325.06, 245.06], "category_id": 1, "id": 6}, {"bbox": [517.35, 316.06, 390.87, 334.95], "category_id": 1, "id": 7}], "caption": "Scheme 2a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 437, 269, 451], "ImageBB": [100, 455, 386, 619]}, "diagram_type": "multiple"}, {"id": 1636, "width": 1036, "height": 544, "file_name": "ol016689+-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [603.25, 289.69, 421.87, 206.25], "category_id": 1, "id": 0}, {"bbox": [23.84, 323.89, 376.77, 128.0], "category_id": 1, "id": 3}, {"bbox": [0.0, 16.06, 355.53, 118.68], "category_id": 1, "id": 6}, {"bbox": [518.78, 0.0, 352.41, 120.75], "category_id": 1, "id": 7}], "caption": "Scheme 1a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [578, 74, 635, 88], "ImageBB": [479, 93, 738, 229]}, "diagram_type": "multiple"}, {"id": 1637, "width": 1228, "height": 1964, "file_name": "ol016689+-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [238.88, 0.0, 358.81, 120.85], "category_id": 1, "id": 0}, {"bbox": [706.8, 647.46, 393.22, 240.71], "category_id": 1, "id": 3}, {"bbox": [117.96, 647.46, 390.27, 234.82], "category_id": 1, "id": 5}, {"bbox": [614.4, 1549.39, 594.74, 270.18], "category_id": 1, "id": 6}, {"bbox": [820.84, 5.89, 404.03, 141.48], "category_id": 1, "id": 7}, {"bbox": [190.71, 265.27, 386.33, 192.57], "category_id": 1, "id": 8}, {"bbox": [813.96, 271.17, 410.91, 191.58], "category_id": 1, "id": 14}, {"bbox": [395.18, 1064.04, 410.91, 239.73], "category_id": 1, "id": 15}, {"bbox": [0.0, 1556.27, 586.87, 268.22], "category_id": 1, "id": 17}], "caption": "Scheme 2a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 74, 269, 88], "ImageBB": [89, 94, 396, 585]}, "diagram_type": "tree"}, {"id": 1638, "width": 1352, "height": 1168, "file_name": "ol048585f-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [899.53, 36.51, 424.06, 307.62], "category_id": 1, "id": 0}, {"bbox": [300.97, 413.77, 442.33, 306.95], "category_id": 1, "id": 1}, {"bbox": [301.65, 795.09, 465.32, 315.06], "category_id": 1, "id": 3}, {"bbox": [850.83, 401.6, 441.65, 313.03], "category_id": 1, "id": 7}, {"bbox": [853.54, 793.74, 449.09, 314.38], "category_id": 1, "id": 8}, {"bbox": [411.89, 43.27, 366.58, 288.02], "category_id": 1, "id": 9}], "caption": "Scheme 1. Synthesis of hin(2S4R7R9R) Monomer", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [106, 75, 376, 88], "ImageBB": [73, 93, 411, 385]}, "diagram_type": "multiple"}, {"id": 1639, "width": 1352, "height": 1080, "file_name": "ol050019c-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [484.26, 271.17, 374.01, 327.29], "category_id": 1, "id": 0}, {"bbox": [112.27, 42.6, 183.97, 242.77], "category_id": 1, "id": 1}, {"bbox": [169.08, 696.51, 294.89, 236.68], "category_id": 1, "id": 4}, {"bbox": [837.31, 0.0, 386.19, 319.18], "category_id": 1, "id": 5}, {"bbox": [350.34, 36.52, 261.07, 246.82], "category_id": 1, "id": 6}, {"bbox": [856.24, 646.47, 295.56, 321.21], "category_id": 1, "id": 8}], "caption": "Scheme 1. Synthesis of Fused Tetracyclics", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [124, 75, 357, 88], "ImageBB": [73, 93, 411, 363]}, "diagram_type": "tree"}, {"id": 1640, "width": 1348, "height": 3324, "file_name": "ol202528k-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [61.48, 79.82, 322.34, 154.64], "category_id": 1, "id": 0}, {"bbox": [867.32, 475.57, 390.46, 151.32], "category_id": 1, "id": 2}, {"bbox": [86.4, 863.01, 425.35, 186.24], "category_id": 1, "id": 5}, {"bbox": [86.4, 437.32, 400.43, 181.25], "category_id": 1, "id": 6}, {"bbox": [792.55, 866.34, 490.16, 186.23], "category_id": 1, "id": 8}, {"bbox": [706.15, 41.57, 571.57, 166.28], "category_id": 1, "id": 10}, {"bbox": [616.66, 897.21, 140.2, 49.07], "category_id": 1, "id": 11}, {"bbox": [422.9, 189.56, 225.1, 269.38], "category_id": 1, "id": 13}, {"bbox": [524.3, 851.37, 216.0, 43.93], "category_id": 1, "id": 14}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 205, 488, 218], "ImageBB": [436, 229, 773, 1060]}, "diagram_type": "tree"}, {"id": 1641, "width": 2808, "height": 1700, "file_name": "ol301852m-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [920.08, 1116.76, 417.2, 314.66], "category_id": 1, "id": 0}, {"bbox": [622.28, 0.0, 501.48, 309.04], "category_id": 1, "id": 1}, {"bbox": [1163.09, 365.23, 431.25, 304.83], "category_id": 1, "id": 3}, {"bbox": [1472.13, 726.25, 428.43, 309.04], "category_id": 1, "id": 4}, {"bbox": [920.08, 722.03, 412.98, 311.85], "category_id": 1, "id": 9}, {"bbox": [1764.31, 0.0, 373.65, 278.14], "category_id": 1, "id": 10}, {"bbox": [1472.13, 1125.19, 431.24, 313.25], "category_id": 1, "id": 11}, {"bbox": [2036.82, 932.74, 377.86, 273.92], "category_id": 1, "id": 13}, {"bbox": [481.81, 439.68, 184.02, 96.93], "category_id": 1, "id": 15}, {"bbox": [656.0, 380.68, 369.43, 272.52], "category_id": 1, "id": 16}, {"bbox": [1472.13, 726.25, 428.43, 311.85], "category_id": 1, "id": 17}, {"bbox": [1216.47, 0.0, 502.89, 311.85], "category_id": 1, "id": 18}, {"bbox": [398.19, 61.27, 273.17, 93.18], "category_id": 1, "id": 21}, {"bbox": [1745.01, 374.68, 421.41, 292.24], "category_id": 1, "id": 22}, {"bbox": [419.4, 802.1, 186.03, 94.12], "category_id": 1, "id": 26}, {"bbox": [419.4, 925.72, 367.23, 272.51], "category_id": 1, "id": 27}], "caption": "Scheme 2. Synthetic Routes of Butterfly-Shaped Fused Heteroacenes 1 6", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 89, 463, 102], "ImageBB": [71, 113, 773, 538]}, "diagram_type": "graph"}, {"id": 1642, "width": 1344, "height": 772, "file_name": "ol401443a-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [99.51, 319.9, 313.3, 176.75], "category_id": 1, "id": 0}, {"bbox": [888.83, 79.3, 200.35, 78.63], "category_id": 1, "id": 1}, {"bbox": [913.7, 338.04, 197.67, 76.62], "category_id": 1, "id": 2}, {"bbox": [600.4, 73.25, 242.04, 201.62], "category_id": 1, "id": 3}, {"bbox": [601.07, 318.55, 271.62, 180.79], "category_id": 1, "id": 6}, {"bbox": [135.14, 2.02, 299.86, 224.46], "category_id": 1, "id": 8}], "caption": "Scheme 3. Proposed Mechanism", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 307, 244, 320], "ImageBB": [71, 330, 407, 523]}, "diagram_type": "multiple"}, {"id": 1643, "width": 1704, "height": 652, "file_name": "ol5000692-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [302.61, 79.28, 167.08, 43.48], "category_id": 1, "id": 0}, {"bbox": [1023.76, 7.67, 243.8, 292.41], "category_id": 1, "id": 1}, {"bbox": [588.17, 34.1, 274.49, 235.29], "category_id": 1, "id": 2}, {"bbox": [1379.23, 23.02, 245.49, 261.72], "category_id": 1, "id": 3}], "caption": "Scheme 1. Formation of Iridium Amino-carbenes", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 943, 360, 958], "ImageBB": [10, 964, 436, 1127]}, "diagram_type": "single"}, {"id": 1644, "width": 1356, "height": 1276, "file_name": "ol500444z-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [1010.73, 6.11, 189.93, 273.45], "category_id": 1, "id": 2}, {"bbox": [88.7, 961.9, 228.3, 142.4], "category_id": 1, "id": 4}, {"bbox": [85.8, 452.3, 229.63, 154.31], "category_id": 1, "id": 5}, {"bbox": [112.7, 111.8, 229.5, 152.15], "category_id": 1, "id": 7}, {"bbox": [317.4, 352.2, 214.2, 174.1], "category_id": 1, "id": 8}, {"bbox": [942.4, 388.5, 179.2, 268.1], "category_id": 1, "id": 11}, {"bbox": [1103.81, 847.08, 185.35, 263.47], "category_id": 1, "id": 13}, {"bbox": [316.5, 851.67, 209.81, 174.63], "category_id": 1, "id": 14}, {"bbox": [1129.85, 390.6, 186.88, 268.06], "category_id": 1, "id": 15}, {"bbox": [342.5, 6.11, 211.39, 173.1], "category_id": 1, "id": 16}], "caption": "Scheme 2. Optimization of Conditions for the Synthesis of Tetrahydroquinoxaline 4 ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 471, 782, 501], "ImageBB": [448, 507, 787, 826]}, "diagram_type": "multiple"}, {"id": 1645, "width": 1356, "height": 888, "file_name": "ol501019y-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [974.77, 539.24, 161.45, 135.66], "category_id": 1, "id": 0}, {"bbox": [583.37, 436.14, 139.06, 409.69], "category_id": 1, "id": 1}, {"bbox": [139.06, 643.7, 350.02, 129.55], "category_id": 1, "id": 3}, {"bbox": [824.86, 374.42, 390.05, 128.87], "category_id": 1, "id": 4}, {"bbox": [875.06, 107.85, 152.44, 128.85], "category_id": 1, "id": 5}], "caption": "Scheme 2. Plausible Mechanism for the Homecoupling", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 542, 759, 557], "ImageBB": [448, 563, 787, 785]}, "diagram_type": "graph"}, {"id": 1646, "width": 2816, "height": 836, "file_name": "ol501514b-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [30.99, 94.32, 142.28, 43.64], "category_id": 1, "id": 2}, {"bbox": [178.91, 580.0, 202.85, 128.1], "category_id": 1, "id": 3}, {"bbox": [14.09, 242.13, 277.51, 260.44], "category_id": 1, "id": 4}, {"bbox": [709.99, 315.34, 197.22, 187.23], "category_id": 1, "id": 5}, {"bbox": [1097.38, 29.56, 239.48, 181.6], "category_id": 1, "id": 6}, {"bbox": [478.96, 67.57, 249.34, 132.33], "category_id": 1, "id": 7}], "caption": "Scheme 3. Synthesis of 3-Methyl-4-phenyl-1H-pyrrol-2(5H)- one ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 562, 416, 592], "ImageBB": [82, 591, 786, 800]}, "diagram_type": "tree"}, {"id": 1647, "width": 1356, "height": 552, "file_name": "ol502842f-Scheme-c6.png", "license": 0, "bboxes": [{"bbox": [36.63, 260.31, 206.22, 228.45], "category_id": 1, "id": 1}, {"bbox": [1117.9, 6.1, 192.65, 215.57], "category_id": 1, "id": 3}, {"bbox": [1105.01, 260.99, 214.36, 223.02], "category_id": 1, "id": 4}, {"bbox": [590.83, 140.32, 215.04, 213.54], "category_id": 1, "id": 5}, {"bbox": [36.63, 2.71, 210.29, 225.74], "category_id": 1, "id": 6}], "caption": "Scheme 6. Synthesis of Useful Synthetic Intermediates", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 750, 110], "ImageBB": [448, 116, 787, 254]}, "diagram_type": "tree"}, {"id": 1648, "width": 1348, "height": 792, "file_name": "ol800418m-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [904.29, 12.14, 341.89, 233.38], "category_id": 1, "id": 0}, {"bbox": [103.85, 0.0, 339.19, 245.52], "category_id": 1, "id": 4}, {"bbox": [504.4, 435.73, 337.85, 244.84], "category_id": 1, "id": 5}, {"bbox": [103.85, 433.03, 338.52, 245.52], "category_id": 1, "id": 7}, {"bbox": [902.26, 430.33, 338.52, 240.12], "category_id": 1, "id": 9}], "caption": "Scheme 3. Attempted Ring-Closing Metathesis of Enyne 5", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [440, 463, 744, 478], "ImageBB": [425, 485, 762, 683]}, "diagram_type": "graph"}, {"id": 1649, "width": 1348, "height": 1668, "file_name": "ol8005198-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [792.05, 4.1, 292.35, 88.11], "category_id": 1, "id": 0}, {"bbox": [695.24, 211.11, 307.14, 184.4], "category_id": 1, "id": 1}, {"bbox": [25.04, 0.0, 550.85, 126.0], "category_id": 1, "id": 3}, {"bbox": [25.04, 0.0, 551.69, 126.0], "category_id": 1, "id": 7}, {"bbox": [469.89, 707.59, 796.24, 141.85], "category_id": 1, "id": 8}, {"bbox": [267.91, 1336.74, 924.77, 208.6], "category_id": 1, "id": 12}, {"bbox": [1016.57, 211.11, 311.32, 184.4], "category_id": 1, "id": 15}, {"bbox": [394.78, 450.59, 799.57, 142.68], "category_id": 1, "id": 17}, {"bbox": [272.92, 994.63, 919.76, 207.77], "category_id": 1, "id": 19}], "caption": "Scheme 1. Synthesis of (2S,3\u2032R)- and (2R,3\u2032R)-1", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [467, 224, 718, 239], "ImageBB": [425, 247, 762, 664]}, "diagram_type": "tree"}, {"id": 1650, "width": 1352, "height": 816, "file_name": "ol801788t-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [577.59, 391.37, 257.01, 102.07], "category_id": 1, "id": 0}, {"bbox": [106.19, 602.94, 287.44, 139.92], "category_id": 1, "id": 1}, {"bbox": [1046.97, 604.3, 239.43, 154.11], "category_id": 1, "id": 2}, {"bbox": [68.99, 0.0, 357.78, 133.16], "category_id": 1, "id": 3}, {"bbox": [614.12, 504.26, 182.61, 52.04], "category_id": 1, "id": 4}, {"bbox": [65.6, 171.01, 142.71, 52.05], "category_id": 1, "id": 5}, {"bbox": [1046.97, 0.0, 239.43, 135.87], "category_id": 1, "id": 6}], "caption": "Scheme 2. Disilylation via Cross-Coupling", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [115, 74, 337, 89], "ImageBB": [58, 96, 396, 300]}, "diagram_type": "graph"}, {"id": 1651, "width": 1352, "height": 1196, "file_name": "ol9005322-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [676.34, 516.81, 129.86, 431.57], "category_id": 1, "id": 0}, {"bbox": [158.26, 976.79, 93.34, 161.67], "category_id": 1, "id": 1}, {"bbox": [522.13, 0.0, 137.3, 486.37], "category_id": 1, "id": 2}, {"bbox": [543.78, 978.14, 140.67, 163.03], "category_id": 1, "id": 3}, {"bbox": [158.26, 546.57, 136.62, 209.7], "category_id": 1, "id": 4}, {"bbox": [256.33, 133.26, 123.77, 233.38], "category_id": 1, "id": 5}, {"bbox": [1030.74, 1028.88, 180.58, 56.82], "category_id": 1, "id": 8}, {"bbox": [835.28, 48.03, 242.8, 302.37], "category_id": 1, "id": 10}], "caption": "Scheme 3. (a) Nitrile Oxide Precursors 9-11, (b) Synthesis of  the Dabcyl-Oxime 10, and (c) Depiction of the Nitrile Oxide            Preparation via Hydroximoyl Chlorides ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [64, 179, 388, 221], "ImageBB": [58, 229, 396, 528]}, "diagram_type": "multiple"}, {"id": 1652, "width": 1148, "height": 800, "file_name": "op010068e-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [638.03, 392.78, 478.96, 354.88], "category_id": 1, "id": 2}, {"bbox": [103.37, 465.71, 353.76, 281.95], "category_id": 1, "id": 4}, {"bbox": [420.95, 18.95, 287.72, 258.98], "category_id": 1, "id": 6}, {"bbox": [792.52, 24.69, 252.68, 280.23], "category_id": 1, "id": 7}, {"bbox": [0.0, 3.45, 332.51, 210.17], "category_id": 1, "id": 8}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 382, 135, 396], "ImageBB": [99, 401, 386, 601]}, "diagram_type": "multiple"}, {"id": 1653, "width": 1232, "height": 1512, "file_name": "op010097p-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [0.0, 565.77, 326.04, 312.39], "category_id": 1, "id": 0}, {"bbox": [34.8, 1126.25, 271.57, 312.38], "category_id": 1, "id": 2}, {"bbox": [680.83, 30.26, 283.68, 254.89], "category_id": 1, "id": 4}, {"bbox": [925.93, 572.58, 221.65, 235.99], "category_id": 1, "id": 7}, {"bbox": [991.75, 4.54, 236.02, 134.63], "category_id": 1, "id": 9}, {"bbox": [37.07, 37.06, 229.97, 235.24], "category_id": 1, "id": 10}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 501, 67], "ImageBB": [455, 74, 763, 452]}, "diagram_type": "tree"}, {"id": 1654, "width": 984, "height": 1740, "file_name": "op049803n-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [0.0, 115.77, 414.24, 310.23], "category_id": 1, "id": 0}, {"bbox": [0.0, 1399.66, 389.87, 329.89], "category_id": 1, "id": 1}, {"bbox": [19.98, 536.8, 350.92, 317.46], "category_id": 1, "id": 2}, {"bbox": [734.49, 987.94, 249.51, 161.03], "category_id": 1, "id": 3}, {"bbox": [610.04, 629.32, 325.47, 378.64], "category_id": 1, "id": 4}, {"bbox": [609.17, 207.16, 326.34, 273.32], "category_id": 1, "id": 5}, {"bbox": [610.04, 1138.53, 340.27, 601.47], "category_id": 1, "id": 6}, {"bbox": [2.1, 962.3, 375.2, 323.0], "category_id": 1, "id": 7}], "caption": "Scheme 5", "pdf": {"Page": 12, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 135, 67], "ImageBB": [181, 71, 427, 506]}, "diagram_type": "tree"}, {"id": 1655, "width": 1184, "height": 848, "file_name": "op049899l-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [781.83, 2.37, 274.23, 293.69], "category_id": 1, "id": 0}, {"bbox": [5.33, 21.32, 270.68, 271.78], "category_id": 1, "id": 3}, {"bbox": [959.52, 442.91, 224.48, 308.49], "category_id": 1, "id": 4}, {"bbox": [455.48, 459.49, 280.15, 317.96], "category_id": 1, "id": 5}], "caption": "Scheme 3", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 253, 135, 267], "ImageBB": [94, 272, 390, 484]}, "diagram_type": "multiple"}, {"id": 1656, "width": 1176, "height": 1368, "file_name": "op049899l-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [258.66, 483.15, 223.76, 293.58], "category_id": 1, "id": 0}, {"bbox": [815.67, 1003.25, 360.33, 276.47], "category_id": 1, "id": 2}, {"bbox": [842.36, 427.71, 273.03, 355.86], "category_id": 1, "id": 3}, {"bbox": [210.08, 984.77, 226.5, 306.58], "category_id": 1, "id": 5}, {"bbox": [4.11, 15.06, 270.29, 271.68], "category_id": 1, "id": 6}, {"bbox": [575.49, 6.84, 268.92, 270.32], "category_id": 1, "id": 11}, {"bbox": [884.1, 144.4, 192.29, 125.23], "category_id": 1, "id": 12}], "caption": "Scheme 4", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 375, 501, 389], "ImageBB": [461, 393, 755, 735]}, "diagram_type": "tree"}, {"id": 1657, "width": 1356, "height": 1592, "file_name": "op050061n-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [348.94, 1109.38, 326.64, 326.53], "category_id": 1, "id": 1}, {"bbox": [90.82, 684.11, 235.02, 268.38], "category_id": 1, "id": 2}, {"bbox": [0.0, 1105.4, 296.36, 328.12], "category_id": 1, "id": 3}, {"bbox": [86.04, 425.28, 319.47, 160.87], "category_id": 1, "id": 4}, {"bbox": [1131.28, 1112.57, 224.72, 285.11], "category_id": 1, "id": 8}, {"bbox": [696.29, 1052.04, 301.94, 384.66], "category_id": 1, "id": 11}, {"bbox": [839.7, 3.19, 489.15, 453.94], "category_id": 1, "id": 12}, {"bbox": [579.18, 595.71, 461.28, 269.18], "category_id": 1, "id": 14}], "caption": "Scheme 2. New synthesis route for 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 285, 67], "ImageBB": [73, 71, 412, 469]}, "diagram_type": "tree"}, {"id": 1658, "width": 968, "height": 316, "file_name": "op050077d-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [0.0, 70.72, 108.47, 64.43], "category_id": 1, "id": 0}, {"bbox": [184.98, 4.36, 341.39, 239.3], "category_id": 1, "id": 2}, {"bbox": [641.14, 6.3, 326.86, 234.45], "category_id": 1, "id": 4}], "caption": "Scheme 3.13 Activation mechanism", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 273, 67], "ImageBB": [185, 74, 427, 153]}, "diagram_type": "single"}, {"id": 1659, "width": 1012, "height": 2308, "file_name": "op050193g-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [489.95, 1711.08, 513.06, 513.79], "category_id": 1, "id": 0}, {"bbox": [82.07, 1812.1, 293.69, 324.17], "category_id": 1, "id": 1}, {"bbox": [0.0, 18.47, 420.62, 424.89], "category_id": 1, "id": 2}, {"bbox": [630.92, 804.74, 287.73, 282.87], "category_id": 1, "id": 3}, {"bbox": [119.02, 810.51, 287.73, 280.57], "category_id": 1, "id": 4}, {"bbox": [581.24, 0.0, 429.86, 447.98], "category_id": 1, "id": 5}], "caption": "Scheme 5", "pdf": {"Page": 9, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 135, 67], "ImageBB": [117, 71, 370, 648]}, "diagram_type": "graph"}, {"id": 1660, "width": 1356, "height": 1856, "file_name": "op060114g-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [593.22, 0.0, 279.44, 425.24], "category_id": 1, "id": 0}, {"bbox": [964.57, 1371.34, 280.37, 417.81], "category_id": 1, "id": 4}, {"bbox": [1036.98, 0.0, 282.22, 415.95], "category_id": 1, "id": 5}, {"bbox": [38.99, 718.63, 273.87, 417.81], "category_id": 1, "id": 8}, {"bbox": [38.99, 42.71, 262.73, 225.62], "category_id": 1, "id": 9}, {"bbox": [1073.19, 697.28, 282.81, 423.38], "category_id": 1, "id": 10}, {"bbox": [38.99, 1371.34, 273.87, 422.45], "category_id": 1, "id": 11}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 357, 135, 371], "ImageBB": [73, 375, 412, 839]}, "diagram_type": "tree"}, {"id": 1661, "width": 2120, "height": 1432, "file_name": "op100072y-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [48.78, 674.8, 440.12, 216.45], "category_id": 1, "id": 3}, {"bbox": [746.61, 978.25, 567.39, 409.55], "category_id": 1, "id": 7}, {"bbox": [802.82, 667.37, 425.27, 213.27], "category_id": 1, "id": 8}, {"bbox": [1564.28, 669.49, 414.67, 213.27], "category_id": 1, "id": 9}, {"bbox": [1729.72, 0.0, 383.92, 558.09], "category_id": 1, "id": 11}, {"bbox": [865.39, 4.24, 156.96, 264.19], "category_id": 1, "id": 13}, {"bbox": [551.48, 140.05, 180.29, 291.78], "category_id": 1, "id": 14}, {"bbox": [1114.62, 0.0, 234.37, 559.15], "category_id": 1, "id": 15}, {"bbox": [48.78, 146.42, 174.99, 292.84], "category_id": 1, "id": 16}, {"bbox": [1552.62, 971.88, 567.38, 409.55], "category_id": 1, "id": 20}, {"bbox": [1406.26, 291.78, 221.65, 192.04], "category_id": 1, "id": 21}, {"bbox": [0.0, 1119.36, 412.55, 214.32], "category_id": 1, "id": 22}], "caption": "Scheme 1. Medicinal Chemistry route (conversion of sodium salt 12 to target acid 1 not shown)", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 394, 587, 408], "ImageBB": [145, 413, 675, 771]}, "diagram_type": "multiple"}, {"id": 1662, "width": 2032, "height": 932, "file_name": "op100103v-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [1616.25, 591.99, 311.05, 288.88], "category_id": 1, "id": 1}, {"bbox": [735.95, 90.53, 398.47, 258.36], "category_id": 1, "id": 2}, {"bbox": [0.0, 90.53, 243.96, 258.36], "category_id": 1, "id": 6}, {"bbox": [355.78, 287.86, 255.14, 140.37], "category_id": 1, "id": 7}, {"bbox": [1609.13, 100.7, 395.42, 254.29], "category_id": 1, "id": 8}], "caption": "Scheme 4. Stage one: telescoped procedure for 3-oxo-1,4-benzoxazine-8-carbaldehyde 16", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 184, 546, 198], "ImageBB": [156, 203, 664, 436]}, "diagram_type": "tree"}, {"id": 1663, "width": 2096, "height": 1076, "file_name": "op100103v-Scheme-c7.png", "license": 0, "bboxes": [{"bbox": [1625.21, 332.53, 470.79, 675.55], "category_id": 1, "id": 1}, {"bbox": [48.23, 467.85, 470.79, 398.62], "category_id": 1, "id": 2}, {"bbox": [1342.11, 420.65, 187.69, 265.39], "category_id": 1, "id": 4}, {"bbox": [791.64, 510.86, 482.32, 309.45], "category_id": 1, "id": 6}, {"bbox": [687.83, 32.52, 376.42, 336.73], "category_id": 1, "id": 8}, {"bbox": [0.0, 62.94, 303.02, 283.23], "category_id": 1, "id": 10}], "caption": "Scheme 7. Pilot scale-up of stage two, five-step synthesis of imidazo[5,1-c][1,4]benzoxazine-3-carboxylate 9", "pdf": {"Page": 7, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 643, 60], "ImageBB": [148, 65, 672, 334]}, "diagram_type": "multiple"}, {"id": 1664, "width": 1356, "height": 856, "file_name": "op100197g-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [977.49, 420.13, 378.51, 294.57], "category_id": 1, "id": 1}, {"bbox": [4.07, 6.11, 316.11, 289.81], "category_id": 1, "id": 4}, {"bbox": [257.77, 417.42, 316.1, 299.99], "category_id": 1, "id": 5}], "caption": "Scheme 1", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 210, 486, 224], "ImageBB": [424, 228, 763, 442]}, "diagram_type": "multiple"}, {"id": 1665, "width": 968, "height": 1376, "file_name": "op100210s-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [723.26, 0.0, 244.74, 450.18], "category_id": 1, "id": 1}, {"bbox": [0.0, 522.45, 118.36, 186.54], "category_id": 1, "id": 2}, {"bbox": [679.9, 842.53, 278.71, 450.87], "category_id": 1, "id": 3}, {"bbox": [90.84, 46.12, 225.03, 333.85], "category_id": 1, "id": 6}, {"bbox": [52.3, 809.49, 238.1, 452.93], "category_id": 1, "id": 7}], "caption": "Scheme 2. Postulated preparation of imidazolidinone 7", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 421, 365, 435], "ImageBB": [106, 440, 348, 784]}, "diagram_type": "graph"}, {"id": 1666, "width": 1344, "height": 972, "file_name": "op200019k-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [230.61, 396.7, 155.31, 174.81], "category_id": 1, "id": 0}, {"bbox": [847.82, 393.33, 220.52, 213.15], "category_id": 1, "id": 2}, {"bbox": [932.53, 0.0, 209.77, 200.37], "category_id": 1, "id": 3}, {"bbox": [227.92, 30.93, 178.17, 172.8], "category_id": 1, "id": 6}, {"bbox": [485.43, 691.87, 188.25, 208.43], "category_id": 1, "id": 7}], "caption": "Scheme 4. Wittig route to \ufb02uoromethyl butenolide 13", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 371, 372, 391], "ImageBB": [71, 400, 407, 643]}, "diagram_type": "graph"}, {"id": 1667, "width": 1688, "height": 1280, "file_name": "op2001832-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [671.32, 415.38, 366.47, 197.55], "category_id": 1, "id": 1}, {"bbox": [1296.19, 0.0, 237.28, 174.76], "category_id": 1, "id": 2}, {"bbox": [433.19, 969.21, 411.23, 233.86], "category_id": 1, "id": 3}, {"bbox": [226.31, 42.21, 343.67, 130.86], "category_id": 1, "id": 5}, {"bbox": [1242.15, 415.38, 445.85, 206.84], "category_id": 1, "id": 7}, {"bbox": [83.6, 431.42, 359.72, 192.49], "category_id": 1, "id": 8}, {"bbox": [804.73, 35.46, 363.11, 130.86], "category_id": 1, "id": 9}, {"bbox": [1134.9, 962.46, 403.64, 231.32], "category_id": 1, "id": 11}, {"bbox": [0.0, 974.28, 408.7, 236.39], "category_id": 1, "id": 12}], "caption": "Scheme 4. Mandelic acid resolution route to (3S,5R)-3-(aminomethyl)-5-methyloctanoic acida", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 644, 595, 665], "ImageBB": [211, 675, 633, 995]}, "diagram_type": "tree"}, {"id": 1668, "width": 2820, "height": 944, "file_name": "op300171m-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [1934.08, 501.05, 386.53, 210.3], "category_id": 1, "id": 0}, {"bbox": [1426.22, 46.58, 382.3, 224.41], "category_id": 1, "id": 2}, {"bbox": [490.93, 64.93, 283.55, 169.36], "category_id": 1, "id": 4}, {"bbox": [490.93, 262.52, 410.51, 611.15], "category_id": 1, "id": 5}, {"bbox": [1433.28, 396.61, 486.69, 153.84], "category_id": 1, "id": 7}, {"bbox": [1897.4, 4.23, 387.94, 245.59], "category_id": 1, "id": 8}, {"bbox": [1098.94, 280.87, 462.71, 612.56], "category_id": 1, "id": 10}, {"bbox": [836.55, 60.69, 303.3, 125.62], "category_id": 1, "id": 12}], "caption": "Scheme 2. Over-Reduction of Indole to Indoline under the Acidic Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 358, 521, 373], "ImageBB": [82, 116, 787, 352]}, "diagram_type": "tree"}, {"id": 1669, "width": 1356, "height": 1792, "file_name": "op300213s-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [475.86, 1068.7, 305.59, 275.97], "category_id": 1, "id": 0}, {"bbox": [148.76, 0.0, 316.35, 290.7], "category_id": 1, "id": 1}, {"bbox": [516.19, 504.1, 306.49, 291.05], "category_id": 1, "id": 2}, {"bbox": [0.0, 1052.43, 326.2, 284.17], "category_id": 1, "id": 3}, {"bbox": [1011.77, 992.37, 319.03, 285.07], "category_id": 1, "id": 4}, {"bbox": [660.47, 24.2, 320.83, 330.79], "category_id": 1, "id": 5}, {"bbox": [1031.48, 488.56, 315.45, 300.31], "category_id": 1, "id": 6}, {"bbox": [589.67, 1514.1, 236.59, 240.25], "category_id": 1, "id": 7}, {"bbox": [56.46, 503.8, 312.76, 285.07], "category_id": 1, "id": 8}], "caption": "Scheme 3. Reaction mechanism showing base hydrolysis of TACDNB ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 413, 783, 443], "ImageBB": [448, 449, 787, 897]}, "diagram_type": "tree"}, {"id": 1670, "width": 1352, "height": 1308, "file_name": "op3003097-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [856.24, 0.0, 401.75, 128.47], "category_id": 1, "id": 1}, {"bbox": [408.51, 827.59, 382.81, 379.99], "category_id": 1, "id": 2}, {"bbox": [24.35, 396.22, 385.51, 375.93], "category_id": 1, "id": 6}, {"bbox": [589.77, 36.51, 261.06, 285.33], "category_id": 1, "id": 7}, {"bbox": [894.8, 391.48, 376.04, 378.64], "category_id": 1, "id": 9}, {"bbox": [41.26, 54.77, 220.48, 211.63], "category_id": 1, "id": 10}, {"bbox": [1031.42, 824.21, 298.26, 383.37], "category_id": 1, "id": 12}], "caption": "Scheme 2. The Discovery Chemistry synthesis of 3", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 370, 110], "ImageBB": [82, 116, 420, 443]}, "diagram_type": "multiple"}, {"id": 1671, "width": 1352, "height": 376, "file_name": "op300363s-Scheme-c4.png", "license": 0, "bboxes": [{"bbox": [549.86, 22.3, 263.77, 275.06], "category_id": 1, "id": 0}, {"bbox": [19.61, 83.8, 271.89, 217.62], "category_id": 1, "id": 2}, {"bbox": [349.67, 18.25, 108.21, 120.97], "category_id": 1, "id": 3}, {"bbox": [1061.17, 0.0, 270.54, 300.06], "category_id": 1, "id": 5}], "caption": "Scheme 4. Equilibration of Hydrazone and Hydrazine/DHF in Non-Solvolytic Solvents ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 534, 417, 564], "ImageBB": [82, 571, 420, 665]}, "diagram_type": "single"}, {"id": 1672, "width": 1352, "height": 1664, "file_name": "op700175d-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [459.52, 560.22, 228.93, 147.33], "category_id": 1, "id": 0}, {"bbox": [0.0, 134.85, 382.1, 184.8], "category_id": 1, "id": 1}, {"bbox": [863.27, 103.22, 487.82, 204.77], "category_id": 1, "id": 4}, {"bbox": [459.52, 206.44, 215.61, 71.59], "category_id": 1, "id": 5}, {"bbox": [459.52, 0.0, 213.11, 52.44], "category_id": 1, "id": 6}, {"bbox": [0.0, 472.81, 392.92, 185.63], "category_id": 1, "id": 7}], "caption": "Scheme 3. Species involved in the reaction between sulfonyl aniline 1 with cyanamide ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 392, 73], "ImageBB": [58, 79, 396, 495]}, "diagram_type": "tree"}, {"id": 1673, "width": 900, "height": 1660, "file_name": "op800136f-Scheme-c11.png", "license": 0, "bboxes": [{"bbox": [0.0, 460.88, 553.67, 278.19], "category_id": 1, "id": 0}, {"bbox": [10.79, 0.0, 558.65, 215.91], "category_id": 1, "id": 1}, {"bbox": [10.79, 1376.83, 889.21, 220.06], "category_id": 1, "id": 2}, {"bbox": [10.79, 969.92, 640.83, 262.42], "category_id": 1, "id": 5}], "caption": "Scheme 11", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 126, 60], "ImageBB": [186, 65, 411, 480]}, "diagram_type": "tree"}, {"id": 1674, "width": 1352, "height": 1164, "file_name": "op800136f-Scheme-c6.png", "license": 0, "bboxes": [{"bbox": [708.8, 700.47, 507.26, 448.27], "category_id": 1, "id": 0}, {"bbox": [663.49, 214.33, 512.66, 243.41], "category_id": 1, "id": 1}, {"bbox": [0.0, 537.52, 371.99, 164.98], "category_id": 1, "id": 2}], "caption": "Scheme 6", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 486, 119, 500], "ImageBB": [58, 505, 396, 796]}, "diagram_type": "tree"}, {"id": 1675, "width": 1180, "height": 1360, "file_name": "op9000687-Scheme-c3.png", "license": 0, "bboxes": [{"bbox": [787.54, 759.94, 373.37, 306.15], "category_id": 1, "id": 0}, {"bbox": [31.28, 1142.29, 189.75, 157.84], "category_id": 1, "id": 3}, {"bbox": [306.72, 1150.46, 259.79, 121.78], "category_id": 1, "id": 5}, {"bbox": [35.36, 0.0, 246.2, 233.36], "category_id": 1, "id": 8}, {"bbox": [0.0, 425.21, 395.81, 219.75], "category_id": 1, "id": 10}, {"bbox": [35.36, 751.1, 397.86, 217.02], "category_id": 1, "id": 11}, {"bbox": [760.34, 349.01, 367.93, 270.1], "category_id": 1, "id": 13}], "caption": "Scheme 3. Some strategies for the synthesis of carbonate 12", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 254, 392, 268], "ImageBB": [79, 273, 374, 613]}, "diagram_type": "tree"}, {"id": 1676, "width": 1308, "height": 1044, "file_name": "op900188v-Scheme-c7.png", "license": 0, "bboxes": [{"bbox": [957.93, 0.0, 350.07, 358.56], "category_id": 1, "id": 0}, {"bbox": [453.45, 620.93, 350.72, 364.44], "category_id": 1, "id": 5}, {"bbox": [313.42, 0.0, 348.76, 358.56], "category_id": 1, "id": 6}, {"bbox": [0.0, 623.55, 346.14, 362.48], "category_id": 1, "id": 7}, {"bbox": [955.32, 626.82, 348.75, 358.55], "category_id": 1, "id": 9}], "caption": "Scheme 7. Synthesis of the bromobenzopyran intermediate 25a ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 274, 753, 301], "ImageBB": [430, 311, 757, 572]}, "diagram_type": "tree"}, {"id": 1677, "width": 1356, "height": 780, "file_name": "op900265h-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [963.92, 2.71, 388.01, 289.57], "category_id": 1, "id": 1}, {"bbox": [0.0, 2.71, 482.3, 291.6], "category_id": 1, "id": 2}, {"bbox": [548.1, 368.91, 771.27, 388.57], "category_id": 1, "id": 3}, {"bbox": [490.44, 2.71, 454.49, 291.6], "category_id": 1, "id": 4}], "caption": "Scheme 1. Synthetic route to S-0139 4 from oleanolic acid 1", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 315, 759, 329], "ImageBB": [424, 334, 763, 529]}, "diagram_type": "multiple"}, {"id": 1678, "width": 1284, "height": 1172, "file_name": "op990044w-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [88.3, 73.21, 116.1, 190.72], "category_id": 1, "id": 0}, {"bbox": [235.09, 483.56, 330.15, 120.73], "category_id": 1, "id": 1}, {"bbox": [806.76, 0.0, 328.86, 211.92], "category_id": 1, "id": 4}, {"bbox": [283.26, 58.44, 328.87, 224.76], "category_id": 1, "id": 6}, {"bbox": [806.76, 399.43, 332.72, 209.35], "category_id": 1, "id": 8}, {"bbox": [848.51, 744.92, 435.49, 309.53], "category_id": 1, "id": 9}, {"bbox": [276.2, 828.41, 333.36, 238.25], "category_id": 1, "id": 13}], "caption": "Scheme 1. Original route to FK453 (1)", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 580, 663, 594], "ImageBB": [448, 603, 769, 896]}, "diagram_type": "multiple"}, {"id": 1679, "width": 1128, "height": 1016, "file_name": "op990067a-Scheme-c5.png", "license": 0, "bboxes": [{"bbox": [352.68, 5.08, 468.35, 397.7], "category_id": 1, "id": 1}, {"bbox": [76.74, 584.42, 473.44, 406.17], "category_id": 1, "id": 2}], "caption": "Scheme 5", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 501, 67], "ImageBB": [467, 73, 749, 327]}, "diagram_type": "multiple"}, {"id": 1680, "width": 2812, "height": 1296, "file_name": "ja0516864-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [870.56, 837.03, 536.99, 338.47], "category_id": 1, "id": 0}, {"bbox": [29.39, 846.0, 543.72, 338.47], "category_id": 1, "id": 1}, {"bbox": [924.49, 350.6, 492.21, 318.03], "category_id": 1, "id": 2}, {"bbox": [186.47, 197.97, 339.59, 418.59], "category_id": 1, "id": 3}], "caption": "Figure 4. (a) The syn/anti isomerization of vinyl cation 1d via its twist boat conformer and by rotation around the C-Cipso bond. (b) Energy profile for both competing isomerization pathways as computed at B3LYP/6-311G(2d,p)//B3LYP/6-31G(d) + \u2206ZPVE. ", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 362, 774, 388], "ImageBB": [74, 35, 776, 359]}}, {"id": 1681, "width": 1276, "height": 492, "file_name": "op020049k-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 0.0, 758.0, 400.0], "category_id": 1, "id": 0}, {"bbox": [902.0, 164.1, 367.7, 236.9], "category_id": 1, "id": 3}], "caption": "Figure 1. Structures of nelfinavir mesylate 1 and its key intermediate 2. ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 346, 775, 374], "ImageBB": [449, 218, 768, 341]}}, {"id": 1682, "width": 1344, "height": 1140, "file_name": "ol201915j-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [18.1, 177.0, 585.4, 563.4], "category_id": 1, "id": 0}, {"bbox": [345.0, 657.0, 671.0, 477.0], "category_id": 1, "id": 1}, {"bbox": [634.0, 201.0, 693.0, 556.0], "category_id": 1, "id": 2}], "caption": "Figure 2. ORTEP plot (50% probability level) of the solid-state structure of the pseudorotaxane shown at the bottom. Left: Top view; right: side view. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 750, 405, 791], "ImageBB": [71, 452, 407, 737]}}, {"id": 1683, "width": 1348, "height": 480, "file_name": "ol1014703-Figure-c5.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [341.0, 119.0, 668.0, 273.0], "category_id": 1, "id": 1}], "caption": "Figure 5. Structure and selected HMBC correlations of compound 3. Bold: bonds were confirmed by 1H-1H COSY correlations. ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 873, 760, 901], "ImageBB": [425, 746, 762, 866]}}, {"id": 1684, "width": 1352, "height": 480, "file_name": "op400242j-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [288.0, 38.0, 775.0, 402.0], "category_id": 1, "id": 1}], "caption": "Figure 1. Structure of brivanib alaninate (1).", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 668, 301, 682], "ImageBB": [82, 538, 420, 658]}}, {"id": 1685, "width": 1352, "height": 324, "file_name": "op400215h-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [469.5, 37.2, 350.4, 268.8], "category_id": 1, "id": 0}, {"bbox": [34.5, 47.6, 359.5, 270.4], "category_id": 1, "id": 1}, {"bbox": [954.0, 37.2, 366.0, 284.8], "category_id": 1, "id": 2}], "caption": "Figure 2. Byproducts of cyclobutanation.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 695, 282, 709], "ImageBB": [82, 605, 420, 686]}}, {"id": 1686, "width": 1352, "height": 472, "file_name": "ol0521782-Figure-c2.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [332.0, 192.0, 682.0, 274.0], "category_id": 1, "id": 0}], "caption": "Figure 2. Anion-hydrogen bonding results in partial charge transfer from electron-rich pyrrole to electron-poor indanylidene. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 182, 775, 209], "ImageBB": [439, 52, 777, 170]}}, {"id": 1687, "width": 1352, "height": 724, "file_name": "ol052113z-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [0.0, 504.0, 378.7, 174.0], "category_id": 1, "id": 0}, {"bbox": [946.2, 239.2, 381.8, 179.7], "category_id": 1, "id": 1}, {"bbox": [539.4, 143.0, 282.3, 250.7], "category_id": 1, "id": 2}, {"bbox": [95.4, 247.1, 280.6, 143.4], "category_id": 1, "id": 3}, {"bbox": [444.3, 481.2, 391.2, 197.8], "category_id": 1, "id": 4}, {"bbox": [940.0, 479.0, 410.0, 200.0], "category_id": 1, "id": 8}], "caption": "Figure 1. Aminoarenethiolate-Copper(I) Complexes.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 409, 721, 422], "ImageBB": [439, 216, 777, 397]}}, {"id": 1688, "width": 1592, "height": 1604, "file_name": "jo016363e-Figure-c4.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [871.0, 2.0, 494.9, 258.4], "category_id": 1, "id": 0}], "caption": "Figure 4. Energy (kcal mol-1) surface computed14 as a function of the torsion angles of the tert-butyl and phenyl groups in 1. The full line represents the pathway for the phenyl rotation process (the dihedral angle being C2-C1-Cq-O) and the dotted line that for the tert-butyl rotation process (the dihedral angle being Me-Cq-Cq-O). ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 477, 775, 519], "ImageBB": [227, 65, 625, 466]}}, {"id": 1689, "width": 2824, "height": 1040, "file_name": "ol501514b-Figure-c1.png", "license": 0, "flickr_url": "", "coco_url": "", "date_captured": 0, "bboxes": [{"bbox": [452.6, 45.6, 796.4, 410.0], "category_id": 1, "id": 0}, {"bbox": [772.4, 600.6, 460.8, 393.0], "category_id": 1, "id": 1}, {"bbox": [126.0, 646.0, 597.8, 269.0], "category_id": 1, "id": 2}, {"bbox": [125.0, 189.6, 371.0, 246.4], "category_id": 1, "id": 3}], "caption": "Figure 1. Natural compounds with 3-pyrrolin-2-one skeletons.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 749, 380, 763], "ImageBB": [82, 490, 788, 750]}}, {"id": 1690, "width": 2820, "height": 984, "file_name": "acs.oprd.6b00128-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1486.88, 8.47, 307.54, 362.65], "category_id": 1, "id": 1}, {"bbox": [1936.9, 0.0, 390.76, 361.24], "category_id": 1, "id": 2}, {"bbox": [1872.01, 378.18, 565.69, 492.47], "category_id": 1, "id": 3}, {"bbox": [816.8, 22.58, 462.71, 197.55], "category_id": 1, "id": 4}, {"bbox": [723.69, 366.89, 995.96, 510.82], "category_id": 1, "id": 6}, {"bbox": [380.89, 67.73, 279.32, 141.11], "category_id": 1, "id": 9}], "caption": "Scheme 1. General Scheme for Synthesis of Glutamine Conjugates", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 457, 110], "ImageBB": [82, 116, 787, 362]}, "diagram_type": "tree"}, {"id": 1691, "width": 1276, "height": 928, "file_name": "jo991071n-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [981.1, 227.99, 294.9, 208.83], "category_id": 1, "id": 0}, {"bbox": [0.0, 261.2, 290.44, 141.77], "category_id": 1, "id": 1}, {"bbox": [604.49, 0.0, 287.24, 141.77], "category_id": 1, "id": 2}, {"bbox": [461.5, 714.61, 281.5, 209.47], "category_id": 1, "id": 3}, {"bbox": [135.96, 0.0, 275.12, 115.59], "category_id": 1, "id": 4}, {"bbox": [481.29, 253.53, 297.46, 127.09], "category_id": 1, "id": 9}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 64, 636, 78], "ImageBB": [449, 84, 768, 316]}, "diagram_type": "tree"}, {"id": 1692, "width": 1352, "height": 940, "file_name": "ol006192k-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [1018.57, 0.0, 325.31, 331.33], "category_id": 1, "id": 1}, {"bbox": [522.81, 533.51, 305.03, 333.36], "category_id": 1, "id": 3}, {"bbox": [522.13, 0.0, 303.0, 332.68], "category_id": 1, "id": 4}, {"bbox": [8.12, 529.45, 354.4, 337.42], "category_id": 1, "id": 6}, {"bbox": [8.79, 0.0, 346.96, 327.95], "category_id": 1, "id": 8}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 136, 265, 149], "ImageBB": [73, 156, 411, 391]}, "diagram_type": "graph"}, {"id": 1693, "width": 1356, "height": 712, "file_name": "ol500248h-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [458.9, 270.63, 129.9, 114.62], "category_id": 1, "id": 1}, {"bbox": [681.05, 450.9, 259.13, 207.7], "category_id": 1, "id": 2}, {"bbox": [951.71, 236.71, 259.13, 193.31], "category_id": 1, "id": 4}, {"bbox": [143.13, 284.87, 207.57, 119.38], "category_id": 1, "id": 8}, {"bbox": [667.49, 19.67, 212.32, 196.7], "category_id": 1, "id": 9}], "caption": "Scheme 1. Possible Pathways for Pd-Catalyzed Double Arylations of 2-Arylbenzimidazoles and 1,2-Dihaloarenes ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 545, 768, 575], "ImageBB": [448, 582, 787, 760]}, "diagram_type": "graph"}, {"id": 1694, "width": 1752, "height": 1076, "file_name": "ol501424f-Scheme-c2.png", "license": 0, "bboxes": [{"bbox": [184.93, 75.34, 261.18, 129.66], "category_id": 1, "id": 0}, {"bbox": [1018.42, 5.26, 317.27, 209.38], "category_id": 1, "id": 1}, {"bbox": [942.17, 459.94, 392.65, 207.64], "category_id": 1, "id": 5}, {"bbox": [184.93, 467.83, 302.37, 183.98], "category_id": 1, "id": 7}, {"bbox": [486.42, 49.94, 268.19, 131.41], "category_id": 1, "id": 9}], "caption": "Scheme 2. Transformation of (S)-1,3,4-Oxadiazin-6-ones into (S)-\u03b1-Amino Acid Ester ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 811, 784, 841], "ImageBB": [421, 858, 859, 1127]}, "diagram_type": "tree"}, {"id": 1695, "width": 1704, "height": 1740, "file_name": "op300162d-Scheme-c1.png", "license": 0, "bboxes": [{"bbox": [62.69, 0.0, 508.5, 518.78], "category_id": 1, "id": 1}, {"bbox": [727.05, 637.16, 440.58, 525.74], "category_id": 1, "id": 2}, {"bbox": [626.04, 20.89, 461.48, 517.91], "category_id": 1, "id": 3}, {"bbox": [70.53, 631.94, 443.19, 518.78], "category_id": 1, "id": 7}], "caption": "Scheme 1. Schematic Conversion of HBIW to HNIW", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 671, 751, 686], "ImageBB": [433, 692, 859, 1127]}, "diagram_type": "multiple"}], "annotations": [{"id": 0, "image_id": 1356, "category_id": 1, "segmentation": [], "area": 18231.3664, "bbox": [864.78, 7.22, 157.82, 115.52], "iscrowd": 0, "attributes": {"occluded": false, "rotation": 0.0}}, {"id": 1, "image_id": 1356, "category_id": 1, "segmentation": [], "area": 31385.488200000003, "bbox": [312.23, 23.26, 382.47, 82.06], "iscrowd": 0, "attributes": {"occluded": false, "rotation": 0.0}}, {"id": 2, "image_id": 1357, "category_id": 1, "segmentation": [], "area": 184416.0, "bbox": [1010.0, 2211.0, 339.0, 544.0], "iscrowd": 0, "attributes": {"occluded": false, "rotation": 0.0}}, {"id": 3, "image_id": 1357, "category_id": 1, "segmentation": [], "area": 99066.0, "bbox": [378.0, 1000.0, 418.0, 237.0], "iscrowd": 0, "attributes": {"occluded": false, "rotation": 0.0}}, {"id": 4, 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