{ "electrochemistry_R2_pos_000442": { "query": "Find cyclic voltammetry experiments targeting DCF in phosphoric acid electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "phosphoric acid" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "DCF" } ], "explore_field": null }, "electrochemistry_R1_pos_000499": { "query": "Find electrochemical experiments targeting 2,4-DNP in 100 mM phosphate buffer.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R1", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "phosphate buffer" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "target_species", "op": "=", "value": "2,4-DNP" } ], "explore_field": null }, "electrochemistry_R1_pos_000182": { "query": "Find electrochemical experiments targeting O2 in 30 wt% NaOH electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R1", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "NaOH" }, { "field": "electrolytes.concentration", "op": "=", "value": "30 wt%", "parsed": { "kind": "point", "number": 30.0, "unit": "wt%", "raw": "30 wt%" } }, { "field": "target_species", "op": "=", "value": "O2" } ], "explore_field": null }, "electrochemistry_R2_pos_000344": { "query": "Find cyclic voltammetry experiments targeting K3[Fe(CN)6] in KNO3 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KNO3" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" } ], "explore_field": null }, "electrochemistry_R1_pos_000301": { "query": "Find electrochemical experiments targeting Ca2+ in 100 mM CaCl2 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R1", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "CaCl2" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "target_species", "op": "=", "value": "Ca2+" } ], "explore_field": null }, "electrochemistry_R2_pos_000109": { "query": "Find electrochemical experiments targeting CO2 with a gas diffusion electrode (GDE) in KOH electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KOH" }, { "field": "target_species", "op": "=", "value": "CO2" }, { "field": "working_electrode", "op": "=", "value": "GDE" } ], "explore_field": null }, "electrochemistry_R1_pos_000391": { "query": "Find electrochemical experiments targeting O2 in 50 mM Na2SO4 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R1", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "Na2SO4" }, { "field": "electrolytes.concentration", "op": "=", "value": "50 mM", "parsed": { "kind": "point", "number": 50.0, "unit": "mm", "raw": "50 mM" } }, { "field": "target_species", "op": "=", "value": "O2" } ], "explore_field": null }, "electrochemistry_R1_pos_000422": { "query": "Find electrochemical experiments targeting PD-L1 in 10 mM PBS.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R1", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "PBS" }, { "field": "electrolytes.concentration", "op": "=", "value": "10 mM", "parsed": { "kind": "point", "number": 10.0, "unit": "mm", "raw": "10 mM" } }, { "field": "target_species", "op": "=", "value": "PD-L1" } ], "explore_field": null }, "electrochemistry_R1_pos_000448": { "query": "Find electrochemical experiments targeting [Fe(CN)6]3-/4- in 100 mM K3[Fe(CN)6] electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R1", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "K3[Fe(CN)6]" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" } ], "explore_field": null }, "electrochemistry_R1_pos_000148": { "query": "Find electrochemical experiments targeting N2 in 0.5 m H2SO4 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R1", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "H2SO4" }, { "field": "electrolytes.concentration", "op": "=", "value": "0.5 m", "parsed": { "kind": "point", "number": 0.5, "unit": "m", "raw": "0.5 m" } }, { "field": "target_species", "op": "=", "value": "N2" } ], "explore_field": null }, "electrochemistry_R2_pos_000408": { "query": "Find cyclic voltammetry experiments targeting CO2 in K2SO4 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "K2SO4" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "CO2" } ], "explore_field": null }, "electrochemistry_R1_pos_000425": { "query": "Find electrochemical experiments targeting the K3[Fe(CN)6]/K4[Fe(CN)6] redox couple in electrolyte containing 2 mM K4[Fe(CN)6].", "domain": "electrochemistry", "type": "reproduction", "type_id": "R1", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "K4[Fe(CN)6]" }, { "field": "electrolytes.concentration", "op": "=", "value": "2 mM", "parsed": { "kind": "point", "number": 2.0, "unit": "mm", "raw": "2 mM" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]/K4[Fe(CN)6]" } ], "explore_field": null }, "electrochemistry_R1_pos_000404": { "query": "Find electrochemical experiments targeting Hg2+ in 100 mM NaCl electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R1", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "NaCl" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "target_species", "op": "=", "value": "Hg2+" } ], "explore_field": null }, "electrochemistry_R1_pos_000375": { "query": "Find electrochemical experiments targeting V(IV) in 100 mM VOSO4 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R1", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "VOSO4" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "target_species", "op": "=", "value": "V(IV)" } ], "explore_field": null }, "electrochemistry_R2_pos_000095": { "query": "Find electrochemical experiments targeting CO2 in KCl electrolyte with an F-CuNS working electrode.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "target_species", "op": "=", "value": "CO2" }, { "field": "working_electrode", "op": "=", "value": "F-CuNS" } ], "explore_field": null }, "electrochemistry_R2_pos_000415": { "query": "Find cyclic voltammetry experiments targeting Li+ in PC electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "PC" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "Li+" } ], "explore_field": null }, "electrochemistry_R2_pos_000277": { "query": "Find electrochemical experiments using LSV to target O2 in NaOH electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "NaOH" }, { "field": "measurement_method", "op": "=", "value": "LSV" }, { "field": "target_species", "op": "=", "value": "O2" } ], "explore_field": null }, "electrochemistry_R5_pos_000305": { "query": "Find cyclic voltammetry experiments targeting K3[Fe(CN)6]/K4[Fe(CN)6] in 5 mM KCl electrolyte at scan rates of 100-1000 mV/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": true, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "electrolytes.concentration", "op": "=", "value": "5 mM", "parsed": { "kind": "point", "number": 5.0, "unit": "mm", "raw": "5 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "between", "range": { "lower": 100.0, "upper": 1000.0, "unit": "mv/s" }, "surface": "100-1000 mV/s" }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]/K4[Fe(CN)6]" } ], "explore_field": null }, "electrochemistry_R5_pos_000023": { "query": "Find electrochemical impedance spectroscopy experiments targeting [Fe(CN)6]3-/4- in 100 mM KCl at room temperature.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "measurement_method", "op": "=", "value": "EIS" }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": null }, "electrochemistry_R5_pos_000128": { "query": "Find electrochemical experiments targeting O2 by linear sweep voltammetry at 5 mV/s in 0.5 M H2SO4 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "H2SO4" }, { "field": "electrolytes.concentration", "op": "=", "value": "0.5 M", "parsed": { "kind": "point", "number": 0.5, "unit": "m", "raw": "0.5 M" } }, { "field": "measurement_method", "op": "=", "value": "LSV" }, { "field": "scan_rate", "op": "=", "value": "5 mV/s", "parsed": { "kind": "point", "number": 5.0, "unit": "mv/s", "raw": "5 mV/s" } }, { "field": "target_species", "op": "=", "value": "O2" } ], "explore_field": null }, "electrochemistry_R5_pos_000089": { "query": "Find cyclic voltammetry experiments targeting [Fe(CN)6]3-/4- in 100 mM KCl at a scan rate of 0.05 V/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "0.05 V/s", "parsed": { "kind": "point", "number": 0.05, "unit": "v/s", "raw": "0.05 V/s" } }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" } ], "explore_field": null }, "electrochemistry_R5_pos_000109": { "query": "Find cyclic voltammetry experiments targeting V(IV) in 2 M H2SO4 at a scan rate of 2 mV/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "H2SO4" }, { "field": "electrolytes.concentration", "op": "=", "value": "2 M", "parsed": { "kind": "point", "number": 2.0, "unit": "m", "raw": "2 M" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "2 mV/s", "parsed": { "kind": "point", "number": 2.0, "unit": "mv/s", "raw": "2 mV/s" } }, { "field": "target_species", "op": "=", "value": "V(IV)" } ], "explore_field": null }, "electrochemistry_R5_pos_000005": { "query": "Find cyclic voltammetry experiments on K3[Fe(CN)6] in K3[Fe(CN)6] electrolyte at room temperature with scan rates of 10-100 mV/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": true, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "K3[Fe(CN)6]" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "between", "range": { "lower": 10.0, "upper": 100.0, "unit": "mv/s" }, "surface": "10-100 mV/s" }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": null }, "electrochemistry_R5_pos_000179": { "query": "Find cyclic voltammetry experiments targeting K3[Fe(CN)6] in 5 mM K3[Fe(CN)6] electrolyte at a scan rate of 10 mV/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "K3[Fe(CN)6]" }, { "field": "electrolytes.concentration", "op": "=", "value": "5 mM", "parsed": { "kind": "point", "number": 5.0, "unit": "mm", "raw": "5 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "10 mV/s", "parsed": { "kind": "point", "number": 10.0, "unit": "mv/s", "raw": "10 mV/s" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" } ], "explore_field": null }, "electrochemistry_R5_pos_000265": { "query": "Find cyclic voltammetry experiments targeting K3[Fe(CN)6] in 100 mM KCl electrolyte at a scan rate of 0.05 V/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "0.05 V/s", "parsed": { "kind": "point", "number": 0.05, "unit": "v/s", "raw": "0.05 V/s" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" } ], "explore_field": null }, "electrochemistry_R5_pos_000040": { "query": "Find cyclic voltammetry experiments targeting the [Fe(CN)6]3-/[Fe(CN)6]4- redox couple in 5 mM Fe(CN)6^4- electrolyte at a scan rate of 50 mV/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "Fe(CN)6^4-" }, { "field": "electrolytes.concentration", "op": "=", "value": "5 mM", "parsed": { "kind": "point", "number": 5.0, "unit": "mm", "raw": "5 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "50 mV/s", "parsed": { "kind": "point", "number": 50.0, "unit": "mv/s", "raw": "50 mV/s" } }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/[Fe(CN)6]4-" } ], "explore_field": null }, "electrochemistry_R5_pos_000090": { "query": "Find cyclic voltammetry experiments targeting [Fe(CN)6]3-/4- in 5 mM KCl electrolyte at a scan rate of 0.05 V/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "electrolytes.concentration", "op": "=", "value": "5 mM", "parsed": { "kind": "point", "number": 5.0, "unit": "mm", "raw": "5 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "0.05 V/s", "parsed": { "kind": "point", "number": 0.05, "unit": "v/s", "raw": "0.05 V/s" } }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" } ], "explore_field": null }, "electrochemistry_R5_pos_000284": { "query": "Find cyclic voltammetry experiments targeting the [Ru(NH3)6]2+/[Ru(NH3)6]3+ redox couple in 1 mM [Ru(NH3)6]3+ electrolyte at scan rates of 100-1000 mV/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": true, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "[Ru(NH3)6]3+" }, { "field": "electrolytes.concentration", "op": "=", "value": "1 mM", "parsed": { "kind": "point", "number": 1.0, "unit": "mm", "raw": "1 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "between", "range": { "lower": 100.0, "upper": 1000.0, "unit": "mv/s" }, "surface": "100-1000 mV/s" }, { "field": "target_species", "op": "=", "value": "[Ru(NH3)6]2+/[Ru(NH3)6]3+" } ], "explore_field": null }, "electrochemistry_R5_pos_000206": { "query": "Find cyclic voltammetry experiments targeting the K3[Fe(CN)6]/K4[Fe(CN)6] redox couple in 5 mM K3[Fe(CN)6] electrolyte at a scan rate of 50 mV/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "K3[Fe(CN)6]" }, { "field": "electrolytes.concentration", "op": "=", "value": "5 mM", "parsed": { "kind": "point", "number": 5.0, "unit": "mm", "raw": "5 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "50 mV/s", "parsed": { "kind": "point", "number": 50.0, "unit": "mv/s", "raw": "50 mV/s" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]/K4[Fe(CN)6]" } ], "explore_field": null }, "electrochemistry_R5_pos_000283": { "query": "Find cyclic voltammetry experiments targeting the [Ru(NH3)6]2+/[Ru(NH3)6]3+ redox couple in 1 mM [Ru(NH3)6]2+ at scan rates of 100-1000 mV/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": true, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "[Ru(NH3)6]2+" }, { "field": "electrolytes.concentration", "op": "=", "value": "1 mM", "parsed": { "kind": "point", "number": 1.0, "unit": "mm", "raw": "1 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "between", "range": { "lower": 100.0, "upper": 1000.0, "unit": "mv/s" }, "surface": "100-1000 mV/s" }, { "field": "target_species", "op": "=", "value": "[Ru(NH3)6]2+/[Ru(NH3)6]3+" } ], "explore_field": null }, "electrochemistry_R5_pos_000147": { "query": "Find cyclic voltammetry experiments targeting the [Fe(CN)6]3-/[Fe(CN)6]4- redox couple in 1 mM [Fe(CN)6]3- with scan rates of 10-250 mV/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": true, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "[Fe(CN)6]3-" }, { "field": "electrolytes.concentration", "op": "=", "value": "1 mM", "parsed": { "kind": "point", "number": 1.0, "unit": "mm", "raw": "1 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "between", "range": { "lower": 10.0, "upper": 250.0, "unit": "mv/s" }, "surface": "10-250 mV/s" }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/[Fe(CN)6]4-" } ], "explore_field": null }, "electrochemistry_R4_pos_000181": { "query": "Find cyclic voltammetry experiments targeting [Fe(CN)6]3-/4- in K4[Fe(CN)6] electrolyte at a scan rate of 200 mV/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "K4[Fe(CN)6]" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "200 mV/s", "parsed": { "kind": "point", "number": 200.0, "unit": "mv/s", "raw": "200 mV/s" } }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" } ], "explore_field": null }, "electrochemistry_R4_pos_000323": { "query": "Find electrochemical experiments targeting NO3- in 100 mM KOH using an Hg/HgO reference electrode.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KOH" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "reference_electrode", "op": "=", "value": "Hg/HgO" }, { "field": "target_species", "op": "=", "value": "NO3-" } ], "explore_field": null }, "electrochemistry_R4_pos_000661": { "query": "Find chronoamperometry experiments targeting H2O2 in 100 mM PBS electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "PBS" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "measurement_method", "op": "=", "value": "CA" }, { "field": "target_species", "op": "=", "value": "H2O2" } ], "explore_field": null }, "electrochemistry_R4_pos_000262": { "query": "Find cyclic voltammetry experiments targeting K3[Fe(CN)6] in KCl electrolyte at a scan rate of 120 mV/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "120 mV/s", "parsed": { "kind": "point", "number": 120.0, "unit": "mv/s", "raw": "120 mV/s" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" } ], "explore_field": null }, "electrochemistry_R4_pos_000719": { "query": "Find cyclic voltammetry experiments targeting aniline in 1 M H2SO4 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "H2SO4" }, { "field": "electrolytes.concentration", "op": "=", "value": "1 M", "parsed": { "kind": "point", "number": 1.0, "unit": "m", "raw": "1 M" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "aniline" } ], "explore_field": null }, "electrochemistry_R4_pos_000677": { "query": "Find electrochemical impedance spectroscopy experiments targeting the K3[Fe(CN)6]/K4[Fe(CN)6] redox couple in an electrolyte containing 2 mM K4[Fe(CN)6].", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "K4[Fe(CN)6]" }, { "field": "electrolytes.concentration", "op": "=", "value": "2 mM", "parsed": { "kind": "point", "number": 2.0, "unit": "mm", "raw": "2 mM" } }, { "field": "measurement_method", "op": "=", "value": "EIS" }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]/K4[Fe(CN)6]" } ], "explore_field": null }, "electrochemistry_R4_pos_000410": { "query": "Find electrochemical experiments using electrolysis to target CO2 in 0.5 M KCl electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "electrolytes.concentration", "op": "=", "value": "0.5 M", "parsed": { "kind": "point", "number": 0.5, "unit": "m", "raw": "0.5 M" } }, { "field": "measurement_method", "op": "=", "value": "electrolysis" }, { "field": "target_species", "op": "=", "value": "CO2" } ], "explore_field": null }, "electrochemistry_R4_pos_000785": { "query": "Find electrochemical experiments targeting [Fe(CN)6]3-/4- at an SPCE in 1 mM [Fe(CN)6]3- electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "[Fe(CN)6]3-" }, { "field": "electrolytes.concentration", "op": "=", "value": "1 mM", "parsed": { "kind": "point", "number": 1.0, "unit": "mm", "raw": "1 mM" } }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" }, { "field": "working_electrode", "op": "=", "value": "SPCE" } ], "explore_field": null }, "electrochemistry_R4_pos_000038": { "query": "Find cyclic voltammetry experiments targeting ferricyanide/ferrocyanide ([Fe(CN)6]3-/4-) in PBS at scan rates of 10-300 mV/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": true, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "PBS" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "between", "range": { "lower": 10.0, "upper": 300.0, "unit": "mv/s" }, "surface": "10-300 mV/s" }, { "field": "target_species", "op": "=", "value": "ferricyanide/ferrocyanide ([Fe(CN)6]3-/4-)" } ], "explore_field": null }, "electrochemistry_R4_pos_000109": { "query": "Find cyclic voltammetry experiments at a scan rate of 50 mV/s for Fe(CN)6^3-/Fe(CN)6^4- in KCl electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "50 mV/s", "parsed": { "kind": "point", "number": 50.0, "unit": "mv/s", "raw": "50 mV/s" } }, { "field": "target_species", "op": "=", "value": "Fe(CN)6^3-/Fe(CN)6^4-" } ], "explore_field": null }, "electrochemistry_R4_pos_000722": { "query": "Find electrochemical experiments targeting CO2 with a Cu working electrode in 1 M KOH electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KOH" }, { "field": "electrolytes.concentration", "op": "=", "value": "1 M", "parsed": { "kind": "point", "number": 1.0, "unit": "m", "raw": "1 M" } }, { "field": "target_species", "op": "=", "value": "CO2" }, { "field": "working_electrode", "op": "=", "value": "Cu" } ], "explore_field": null }, "electrochemistry_R4_pos_000363": { "query": "Find electrochemical experiments targeting H2O2 in 50 mM phosphate buffer using an Ag pseudo-reference electrode.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "phosphate buffer" }, { "field": "electrolytes.concentration", "op": "=", "value": "50 mM", "parsed": { "kind": "point", "number": 50.0, "unit": "mm", "raw": "50 mM" } }, { "field": "reference_electrode", "op": "=", "value": "Ag (pseudo-reference)" }, { "field": "target_species", "op": "=", "value": "H2O2" } ], "explore_field": null }, "electrochemistry_R4_pos_000628": { "query": "Find cyclic voltammetry experiments targeting VO2+ in 100 mM H2SO4 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "H2SO4" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "VO2+" } ], "explore_field": null }, "electrochemistry_R4_pos_000126": { "query": "Find cyclic voltammetry experiments targeting ethanol in KOH electrolyte at a scan rate of 50 mV/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KOH" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "50 mV/s", "parsed": { "kind": "point", "number": 50.0, "unit": "mv/s", "raw": "50 mV/s" } }, { "field": "target_species", "op": "=", "value": "ethanol" } ], "explore_field": null }, "electrochemistry_R4_pos_000417": { "query": "Find cyclic voltammetry experiments targeting the [Fe(CN)6]3-/[Fe(CN)6]4- redox couple in 5 mM [Fe(CN)6]4- electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "[Fe(CN)6]4-" }, { "field": "electrolytes.concentration", "op": "=", "value": "5 mM", "parsed": { "kind": "point", "number": 5.0, "unit": "mm", "raw": "5 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/[Fe(CN)6]4-" } ], "explore_field": null }, "electrochemistry_R4_pos_000345": { "query": "Find electrochemical experiments targeting the [Fe(CN)6]3-/4- redox couple in 1 mM [Fe(CN)6]4- with an Ag/AgCl reference electrode.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "[Fe(CN)6]4-" }, { "field": "electrolytes.concentration", "op": "=", "value": "1 mM", "parsed": { "kind": "point", "number": 1.0, "unit": "mm", "raw": "1 mM" } }, { "field": "reference_electrode", "op": "=", "value": "Ag/AgCl" }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" } ], "explore_field": null }, "electrochemistry_EC4_pos_000046": { "query": "What scan rate is used for cyclic voltammetry of the [Fe(CN)6]3-/4- redox couple in an electrolyte containing K4[Fe(CN)6]?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC4", "constraint_count": 4, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "K4[Fe(CN)6]" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" } ], "explore_field": "scan_rate" }, "electrochemistry_EC4_pos_000391": { "query": "What HCl concentration is used as the electrolyte for electrochemical measurement of DCF at an AGCE working electrode?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC4", "constraint_count": 4, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "HCl" }, { "field": "target_species", "op": "=", "value": "DCF" }, { "field": "working_electrode", "op": "=", "value": "AGCE" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC4_pos_000035": { "query": "What scan rate is used for CV of H2 in KOH electrolyte?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC4", "constraint_count": 4, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KOH" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "H2" } ], "explore_field": "scan_rate" }, "electrochemistry_EC4_pos_000384": { "query": "What concentration of fructose is used in the electrolyte for electrochemical glucose measurements with a Cu sheet working electrode?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC4", "constraint_count": 4, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "fructose" }, { "field": "target_species", "op": "=", "value": "glucose" }, { "field": "working_electrode", "op": "=", "value": "Cu sheet" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC3_pos_000051": { "query": "What temperature is used for electrochemical experiments targeting CO2 in 0.5 M KCl?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC3", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "electrolytes.concentration", "op": "=", "value": "0.5 M", "parsed": { "kind": "point", "number": 0.5, "unit": "m", "raw": "0.5 M" } }, { "field": "target_species", "op": "=", "value": "CO2" } ], "explore_field": "temperature" }, "electrochemistry_EC4_pos_000264": { "query": "What KOH concentration is used for chronoamperometry of urea?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC4", "constraint_count": 4, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KOH" }, { "field": "measurement_method", "op": "=", "value": "CA" }, { "field": "target_species", "op": "=", "value": "urea" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC3_pos_000016": { "query": "What PBS concentration is used for electrochemical experiments targeting O2 at room temperature?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC3", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "PBS" }, { "field": "target_species", "op": "=", "value": "O2" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC4_pos_000225": { "query": "What electrolyte concentration is used for EIS with Na2SO4 as the electrolyte and K3[Fe(CN)6] as the target species?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC4", "constraint_count": 4, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "Na2SO4" }, { "field": "measurement_method", "op": "=", "value": "EIS" }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC4_pos_000248": { "query": "What electrolyte concentration is used for CV of NO3- in KOH?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC4", "constraint_count": 4, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KOH" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "NO3-" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC4_pos_000180": { "query": "What electrolyte concentration is used for EIS in PBS with ferricyanide/ferrocyanide ([Fe(CN)6]3-/4-)?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC4", "constraint_count": 4, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "PBS" }, { "field": "measurement_method", "op": "=", "value": "EIS" }, { "field": "target_species", "op": "=", "value": "ferricyanide/ferrocyanide ([Fe(CN)6]3-/4-)" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC4_pos_000164": { "query": "What electrolyte concentration is used for NO3- electrochemistry in KNO3 with an RHE reference electrode?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC4", "constraint_count": 4, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KNO3" }, { "field": "reference_electrode", "op": "=", "value": "RHE" }, { "field": "target_species", "op": "=", "value": "NO3-" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC4_pos_000115": { "query": "What electrolyte concentration is used for electrochemical detection or oxidation of urea in a urea-containing electrolyte with an Ag/AgCl reference electrode?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC4", "constraint_count": 4, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "urea" }, { "field": "reference_electrode", "op": "=", "value": "Ag/AgCl" }, { "field": "target_species", "op": "=", "value": "urea" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC4_pos_000310": { "query": "What electrolyte concentration is used for KCl in cyclic voltammetry of FcMeOH?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC4", "constraint_count": 4, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "FcMeOH" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC4_pos_000374": { "query": "What electrolyte concentration is used for KCl with [Fe(CN)6]3-/4- at an SPE working electrode?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC4", "constraint_count": 4, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" }, { "field": "working_electrode", "op": "=", "value": "SPE" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC4_pos_000315": { "query": "What PBS concentration is used for cyclic voltammetry of UA?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC4", "constraint_count": 4, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "PBS" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "UA" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC4_pos_000177": { "query": "What electrolyte concentration is used for EIS with potassium ferricyanide and ferricyanide/ferrocyanide ([Fe(CN)6]3-/4-) as the target redox species?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC4", "constraint_count": 4, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "potassium ferricyanide" }, { "field": "measurement_method", "op": "=", "value": "EIS" }, { "field": "target_species", "op": "=", "value": "ferricyanide/ferrocyanide ([Fe(CN)6]3-/4-)" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC5_pos_000197": { "query": "What electrolyte concentration is used for CV at 200 mV/s with K3[Fe(CN)6] as the electrolyte and [Fe(CN)6]3-/4- as the target species?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "K3[Fe(CN)6]" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "200 mV/s", "parsed": { "kind": "point", "number": 200.0, "unit": "mv/s", "raw": "200 mV/s" } }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC5_pos_000324": { "query": "What scan rate is used for cyclic voltammetry of 1 mM [Ru(NH3)6]2+ targeting the [Ru(NH3)6]2+/[Ru(NH3)6]3+ redox couple?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "[Ru(NH3)6]2+" }, { "field": "electrolytes.concentration", "op": "=", "value": "1 mM", "parsed": { "kind": "point", "number": 1.0, "unit": "mm", "raw": "1 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "[Ru(NH3)6]2+/[Ru(NH3)6]3+" } ], "explore_field": "scan_rate" }, "electrochemistry_EC5_pos_000116": { "query": "What KCl concentration is used for cyclic voltammetry at 200 mV/s with the [Ru(NH3)6]2+/[Ru(NH3)6]3+ redox couple?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "200 mV/s", "parsed": { "kind": "point", "number": 200.0, "unit": "mv/s", "raw": "200 mV/s" } }, { "field": "target_species", "op": "=", "value": "[Ru(NH3)6]2+/[Ru(NH3)6]3+" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC5_pos_000275": { "query": "What scan rate is used for cyclic voltammetry of dopamine in 100 mM PBS?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "PBS" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "dopamine" } ], "explore_field": "scan_rate" }, "electrochemistry_EC5_pos_000217": { "query": "What electrolyte concentration is used for cyclic voltammetry of K3[Fe(CN)6] in KCl at a scan rate of 0.05 V/s?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "0.05 V/s", "parsed": { "kind": "point", "number": 0.05, "unit": "v/s", "raw": "0.05 V/s" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC5_pos_000110": { "query": "What electrolyte concentration is used for cyclic voltammetry at 300 mV/s with [Ru(NH3)6]2+ as the electrolyte and the [Ru(NH3)6]2+/[Ru(NH3)6]3+ redox couple as the target species?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "[Ru(NH3)6]2+" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "300 mV/s", "parsed": { "kind": "point", "number": 300.0, "unit": "mv/s", "raw": "300 mV/s" } }, { "field": "target_species", "op": "=", "value": "[Ru(NH3)6]2+/[Ru(NH3)6]3+" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC5_pos_000002": { "query": "What KCl electrolyte concentration is used with an Ag/AgCl reference electrode for [Fe(CN)6]3-/4- measurements at room temperature?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "reference_electrode", "op": "=", "value": "Ag/AgCl" }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC5_pos_000011": { "query": "What scan rate is used for LSV of O2 in KOH at room temperature?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KOH" }, { "field": "measurement_method", "op": "=", "value": "LSV" }, { "field": "target_species", "op": "=", "value": "O2" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": "scan_rate" }, "electrochemistry_EC5_pos_000211": { "query": "What electrolyte concentration is used for cyclic voltammetry of dopamine in PBS at a scan rate of 50 mV/s?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "PBS" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "50 mV/s", "parsed": { "kind": "point", "number": 50.0, "unit": "mv/s", "raw": "50 mV/s" } }, { "field": "target_species", "op": "=", "value": "dopamine" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC2_pos_000040": { "query": "What temperature is used for galvanostatic cycling with Li as the target species?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "measurement_method", "op": "=", "value": "galvanostatic cycling" }, { "field": "target_species", "op": "=", "value": "Li" } ], "explore_field": "temperature" }, "electrochemistry_EC1_pos_000238": { "query": "What concentration of LiI is used in an electrochemical setup targeting I3-?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC1", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "LiI" }, { "field": "target_species", "op": "=", "value": "I3-" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC1_pos_000171": { "query": "What electrolyte concentration is used in PBS for electrochemical measurements targeting [Fe(CN)6]4-?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC1", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "PBS" }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]4-" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC1_pos_000108": { "query": "What acetate buffer concentration is used for electrochemical detection of H2O2?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC1", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "acetate buffer" }, { "field": "target_species", "op": "=", "value": "H2O2" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC1_pos_000004": { "query": "What temperature is used for electrochemical glucose detection in PBS?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC1", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "PBS" }, { "field": "target_species", "op": "=", "value": "glucose" } ], "explore_field": "temperature" }, "electrochemistry_EC1_pos_000129": { "query": "What Na2SO4 electrolyte concentration is used for electrochemical experiments targeting benzaldehyde?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC1", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "Na2SO4" }, { "field": "target_species", "op": "=", "value": "benzaldehyde" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC1_pos_000027": { "query": "What temperature is used for electrochemical experiments targeting O2 in an HF electrolyte?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC1", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "HF" }, { "field": "target_species", "op": "=", "value": "O2" } ], "explore_field": "temperature" }, "electrochemistry_EC1_pos_000152": { "query": "What PBS concentration is used for electrochemical detection of methylone?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC1", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "PBS" }, { "field": "target_species", "op": "=", "value": "methylone" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC2_pos_000012": { "query": "What temperature is used for electrochemical measurements of O2 at a glassy carbon rotating disk electrode (RDE)?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "target_species", "op": "=", "value": "O2" }, { "field": "working_electrode", "op": "=", "value": "glassy carbon (RDE)" } ], "explore_field": "temperature" }, "electrochemistry_EC2_pos_000010": { "query": "What temperature is used for electrochemical CO2 experiments with an Ag working electrode?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "target_species", "op": "=", "value": "CO2" }, { "field": "working_electrode", "op": "=", "value": "Ag" } ], "explore_field": "temperature" }, "electrochemistry_EC1_pos_000160": { "query": "What electrolyte concentration is used for [Fe(CN)6]3-/4- in phosphate buffer?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC1", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "phosphate buffer" }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EC1_pos_000191": { "query": "What electrolyte concentration is used with [Fe(CN)6]3- for electrochemical detection of carcinoembryonic antigen (CEA)?", "domain": "electrochemistry", "type": "condition_exploration", "type_id": "EC1", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "[Fe(CN)6]3-" }, { "field": "target_species", "op": "=", "value": "carcinoembryonic antigen (CEA)" } ], "explore_field": "electrolytes.concentration" }, "electrochemistry_EM2_pos_000021": { "query": "What electrochemical measurement method is used for O2 at 298 K?", "domain": "electrochemistry", "type": "method_exploration", "type_id": "EM2", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "target_species", "op": "=", "value": "O2" }, { "field": "temperature", "op": "=", "value": "298 K", "parsed": { "kind": "point", "number": 298.0, "unit": "k", "raw": "298 K" } } ], "explore_field": "measurement_method" }, "electrochemistry_EM2_pos_000039": { "query": "What electrochemical measurement method is used for CO at 600-750 °C?", "domain": "electrochemistry", "type": "method_exploration", "type_id": "EM2", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": true, "constraints": [ { "field": "target_species", "op": "=", "value": "CO" }, { "field": "temperature", "op": "between", "range": { "lower": 600.0, "upper": 750.0, "unit": "c" }, "surface": "600-750 °C" } ], "explore_field": "measurement_method" }, "electrochemistry_EM2_pos_000040": { "query": "What electrochemical measurement method is used for CO2 at 600-750 °C?", "domain": "electrochemistry", "type": "method_exploration", "type_id": "EM2", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": true, "constraints": [ { "field": "target_species", "op": "=", "value": "CO2" }, { "field": "temperature", "op": "between", "range": { "lower": 600.0, "upper": 750.0, "unit": "c" }, "surface": "600-750 °C" } ], "explore_field": "measurement_method" }, "electrochemistry_EM1_pos_000055": { "query": "What reference electrode is used for electrochemical detection of dopamine in water?", "domain": "electrochemistry", "type": "method_exploration", "type_id": "EM1", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "water" }, { "field": "target_species", "op": "=", "value": "dopamine" } ], "explore_field": "reference_electrode" }, "electrochemistry_EM1_pos_000154": { "query": "What electrochemical measurement method is used to detect NGAL in PBS?", "domain": "electrochemistry", "type": "method_exploration", "type_id": "EM1", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "PBS" }, { "field": "target_species", "op": "=", "value": "NGAL" } ], "explore_field": "measurement_method" }, "electrochemistry_EM1_pos_000031": { "query": "What reference electrode is used for electrochemical measurements of H2 in HClO4 electrolyte?", "domain": "electrochemistry", "type": "method_exploration", "type_id": "EM1", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "HClO4" }, { "field": "target_species", "op": "=", "value": "H2" } ], "explore_field": "reference_electrode" }, "electrochemistry_EM1_pos_000182": { "query": "What electrochemical measurement method is used for detecting cTnI with [Fe(CN)6]3- as the electrolyte component?", "domain": "electrochemistry", "type": "method_exploration", "type_id": "EM1", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "[Fe(CN)6]3-" }, { "field": "target_species", "op": "=", "value": "cTnI" } ], "explore_field": "measurement_method" }, "electrochemistry_EM1_pos_000203": { "query": "What electrochemical measurement method is used for favipiravir in a CTAB-containing electrolyte?", "domain": "electrochemistry", "type": "method_exploration", "type_id": "EM1", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "CTAB" }, { "field": "target_species", "op": "=", "value": "favipiravir" } ], "explore_field": "measurement_method" }, "electrochemistry_EM3_pos_000144": { "query": "What electrochemical measurement method is used for Zn in 2 M ZnSO4 electrolyte?", "domain": "electrochemistry", "type": "method_exploration", "type_id": "EM3", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "ZnSO4" }, { "field": "electrolytes.concentration", "op": "=", "value": "2 M", "parsed": { "kind": "point", "number": 2.0, "unit": "m", "raw": "2 M" } }, { "field": "target_species", "op": "=", "value": "Zn" } ], "explore_field": "measurement_method" }, "electrochemistry_EM3_pos_000098": { "query": "What reference electrode is used for electrochemical measurements of 1 mM ferrocenemethanol when ferrocenemethanol is the target species?", "domain": "electrochemistry", "type": "method_exploration", "type_id": "EM3", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "ferrocenemethanol" }, { "field": "electrolytes.concentration", "op": "=", "value": "1 mM", "parsed": { "kind": "point", "number": 1.0, "unit": "mm", "raw": "1 mM" } }, { "field": "target_species", "op": "=", "value": "ferrocenemethanol" } ], "explore_field": "reference_electrode" }, "electrochemistry_EI_NEG_neg_002735": { "query": "What electrolyte other than PBS is used for CV of K4[Fe(CN)6] at a scan rate of 10-70 mV/s?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": true, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "PBS" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "between", "range": { "lower": 10.0, "upper": 70.0, "unit": "mv/s" }, "surface": "10-70 mV/s" }, { "field": "target_species", "op": "=", "value": "K4[Fe(CN)6]" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_002001": { "query": "What electrolyte other than NaOH is used for CV at 10 mV/s with K3[Fe(CN)6]/K4[Fe(CN)6]?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "NaOH" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "10 mV/s", "parsed": { "kind": "point", "number": 10.0, "unit": "mv/s", "raw": "10 mV/s" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]/K4[Fe(CN)6]" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001070": { "query": "What electrolyte other than Na2SO4 is used with an Ag/AgCl reference electrode for [Fe(CN)6]3-/4- measurements at room temperature?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "Na2SO4" }, { "field": "reference_electrode", "op": "=", "value": "Ag/AgCl" }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_002282": { "query": "What electrolyte other than KOH is used for CV at 0.05 V/s with K4[Fe(CN)6] as the target species?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "KOH" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "0.05 V/s", "parsed": { "kind": "point", "number": 0.05, "unit": "v/s", "raw": "0.05 V/s" } }, { "field": "target_species", "op": "=", "value": "K4[Fe(CN)6]" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_002383": { "query": "What electrolyte other than KCl is used for cyclic voltammetry of ferricyanide ([Fe(CN)6]3-) at a scan rate of 150 mV/s?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "KCl" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "150 mV/s", "parsed": { "kind": "point", "number": 150.0, "unit": "mv/s", "raw": "150 mV/s" } }, { "field": "target_species", "op": "=", "value": "ferricyanide ([Fe(CN)6]3-)" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_002633": { "query": "What electrolyte other than PBS is used for cyclic voltammetry of K3[Fe(CN)6] at a scan rate of 0.02 V/s?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "PBS" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "0.02 V/s", "parsed": { "kind": "point", "number": 0.02, "unit": "v/s", "raw": "0.02 V/s" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_002636": { "query": "What electrolyte other than NaCl is used for cyclic voltammetry of K3[Fe(CN)6] at 0.02 V/s?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "NaCl" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "0.02 V/s", "parsed": { "kind": "point", "number": 0.02, "unit": "v/s", "raw": "0.02 V/s" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_002662": { "query": "What electrolyte other than KOH is used for CV at 0.08 V/s with K3[Fe(CN)6] as the target species?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "KOH" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "0.08 V/s", "parsed": { "kind": "point", "number": 0.08, "unit": "v/s", "raw": "0.08 V/s" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_002271": { "query": "What electrolyte other than phosphate buffer is used for cyclic voltammetry of VO2+ at a scan rate of 5 mV/s?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "phosphate buffer" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "5 mV/s", "parsed": { "kind": "point", "number": 5.0, "unit": "mv/s", "raw": "5 mV/s" } }, { "field": "target_species", "op": "=", "value": "VO2+" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI4_pos_000120": { "query": "What electrolyte chemical is used for cyclic voltammetry of H2O2 at a scan rate of 150 mV/s?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "150 mV/s", "parsed": { "kind": "point", "number": 150.0, "unit": "mv/s", "raw": "150 mV/s" } }, { "field": "target_species", "op": "=", "value": "H2O2" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI4_pos_000012": { "query": "What electrolyte chemical composition is used for EIS measurements targeting O2 at 387-594 °C?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": true, "constraints": [ { "field": "measurement_method", "op": "=", "value": "EIS" }, { "field": "target_species", "op": "=", "value": "O2" }, { "field": "temperature", "op": "between", "range": { "lower": 387.0, "upper": 594.0, "unit": "c" }, "surface": "387-594 °C" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_002411": { "query": "What electrolyte other than KCl is used for CV at 25 mV/s with ferricyanide ([Fe(CN)6]3-)?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "KCl" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "25 mV/s", "parsed": { "kind": "point", "number": 25.0, "unit": "mv/s", "raw": "25 mV/s" } }, { "field": "target_species", "op": "=", "value": "ferricyanide ([Fe(CN)6]3-)" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_002047": { "query": "What electrolyte other than Na2SO4 is used for cyclic voltammetry of K4[Fe(CN)6] at 10 mV/s?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "Na2SO4" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "10 mV/s", "parsed": { "kind": "point", "number": 10.0, "unit": "mv/s", "raw": "10 mV/s" } }, { "field": "target_species", "op": "=", "value": "K4[Fe(CN)6]" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI4_pos_000001": { "query": "What electrolyte chemical is used for CO2 electrochemistry at room temperature with an Ag/AgCl (sat. KCl) reference electrode?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "reference_electrode", "op": "=", "value": "Ag/AgCl (sat. KCl)" }, { "field": "target_species", "op": "=", "value": "CO2" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI4_pos_000021": { "query": "What electrolyte chemical composition is used for LSV of N2 at room temperature?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "measurement_method", "op": "=", "value": "LSV" }, { "field": "target_species", "op": "=", "value": "N2" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001996": { "query": "What electrolyte other than H2SO4 is used for CV at 10 mV/s with K3[Fe(CN)6]/K4[Fe(CN)6]?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "H2SO4" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "10 mV/s", "parsed": { "kind": "point", "number": 10.0, "unit": "mv/s", "raw": "10 mV/s" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]/K4[Fe(CN)6]" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_002290": { "query": "What electrolyte other than Na2SO4 is used for cyclic voltammetry of K4[Fe(CN)6] at a scan rate of 0.05 V/s?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "Na2SO4" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "0.05 V/s", "parsed": { "kind": "point", "number": 0.05, "unit": "v/s", "raw": "0.05 V/s" } }, { "field": "target_species", "op": "=", "value": "K4[Fe(CN)6]" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001934": { "query": "What electrolyte other than [Fe(CN)6]3- is used for cyclic voltammetry of CH3OH at 24 °C?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "[Fe(CN)6]3-" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "CH3OH" }, { "field": "temperature", "op": "=", "value": "24 °C", "parsed": { "kind": "point", "number": 24.0, "unit": "c", "raw": "24 °C" } } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_000882": { "query": "What electrolyte component other than [Fe(CN)6]4- is used for glucose measurements with a Cu(II)/GO/SPCE working electrode?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "[Fe(CN)6]4-" }, { "field": "target_species", "op": "=", "value": "glucose" }, { "field": "working_electrode", "op": "=", "value": "Cu(II)/GO/SPCE" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001028": { "query": "What electrolyte other than [Fe(CN)6]3- is used for electrochemical detection of O2•- at a Pt working electrode?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "[Fe(CN)6]3-" }, { "field": "target_species", "op": "=", "value": "O2•-" }, { "field": "working_electrode", "op": "=", "value": "Pt" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_000236": { "query": "What electrolyte other than KOH is used for H2O2 electrochemistry with an Ag pseudo-reference electrode?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "KOH" }, { "field": "reference_electrode", "op": "=", "value": "Ag (pseudo-reference)" }, { "field": "target_species", "op": "=", "value": "H2O2" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_000508": { "query": "What electrolyte other than Na2SO4 is used for DPV measurement of IgG?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "Na2SO4" }, { "field": "measurement_method", "op": "=", "value": "DPV" }, { "field": "target_species", "op": "=", "value": "IgG" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_000518": { "query": "What electrolyte other than phosphate buffer is used for DPV detection of IgM?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "phosphate buffer" }, { "field": "measurement_method", "op": "=", "value": "DPV" }, { "field": "target_species", "op": "=", "value": "IgM" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_000965": { "query": "What electrolyte other than KCl is used for electrochemical experiments targeting aniline at a CFC working electrode?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "KCl" }, { "field": "target_species", "op": "=", "value": "aniline" }, { "field": "working_electrode", "op": "=", "value": "CFC" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_000791": { "query": "What electrolyte other than H2SO4 is used for [Fe(CN)6]3-/4- electrochemistry at an SPE working electrode?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "H2SO4" }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" }, { "field": "working_electrode", "op": "=", "value": "SPE" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_000936": { "query": "What electrolyte other than H2SO4 is used for CH3OH on a Pt-rGO/PAC-1:2 working electrode?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "H2SO4" }, { "field": "target_species", "op": "=", "value": "CH3OH" }, { "field": "working_electrode", "op": "=", "value": "Pt-rGO/PAC-1:2" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_000170": { "query": "What electrolyte other than [Fe(CN)6]3− is used for electrochemical measurements of urea with an Hg/HgO reference electrode?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "[Fe(CN)6]3-" }, { "field": "reference_electrode", "op": "=", "value": "Hg/HgO" }, { "field": "target_species", "op": "=", "value": "urea" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_000503": { "query": "What electrolyte other than KCl is used for DPV detection of IgG?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "KCl" }, { "field": "measurement_method", "op": "=", "value": "DPV" }, { "field": "target_species", "op": "=", "value": "IgG" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001297": { "query": "What electrolyte other than water is used for CV of DA?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "water" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "DA" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_000347": { "query": "What electrolyte other than [Fe(CN)6]3- is used for CO2 electrochemistry at an F-CuNS working electrode?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "[Fe(CN)6]3-" }, { "field": "target_species", "op": "=", "value": "CO2" }, { "field": "working_electrode", "op": "=", "value": "F-CuNS" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001539": { "query": "What electrolyte other than phosphate buffer is used for SWV detection of cyclobenzaprine?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "phosphate buffer" }, { "field": "measurement_method", "op": "=", "value": "SWV" }, { "field": "target_species", "op": "=", "value": "cyclobenzaprine" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_000101": { "query": "What electrolyte other than PBS is used for electrochemical measurements of V(III) with an SCE reference electrode?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "PBS" }, { "field": "reference_electrode", "op": "=", "value": "SCE" }, { "field": "target_species", "op": "=", "value": "V(III)" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_000875": { "query": "What electrolyte other than KOH is used for glucose detection with a Cu(II)/GO/SPCE working electrode?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "KOH" }, { "field": "target_species", "op": "=", "value": "glucose" }, { "field": "working_electrode", "op": "=", "value": "Cu(II)/GO/SPCE" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_000107": { "query": "What electrolyte other than NaOH is used for electrochemical experiments targeting V(III) with an SCE reference electrode?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "NaOH" }, { "field": "reference_electrode", "op": "=", "value": "SCE" }, { "field": "target_species", "op": "=", "value": "V(III)" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001988": { "query": "What electrolyte chemical other than NaCl is used for cyclic voltammetry of CH3OH at 100 mV/s and 24 °C?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 5, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "NaCl" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "100 mV/s", "parsed": { "kind": "point", "number": 100.0, "unit": "mv/s", "raw": "100 mV/s" } }, { "field": "target_species", "op": "=", "value": "CH3OH" }, { "field": "temperature", "op": "=", "value": "24 °C", "parsed": { "kind": "point", "number": 24.0, "unit": "c", "raw": "24 °C" } } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001973": { "query": "What electrolyte other than NaOH is used for cyclic voltammetry of CH3OH at 50 mV/s and 25 °C?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 5, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "NaOH" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "50 mV/s", "parsed": { "kind": "point", "number": 50.0, "unit": "mv/s", "raw": "50 mV/s" } }, { "field": "target_species", "op": "=", "value": "CH3OH" }, { "field": "temperature", "op": "=", "value": "25 °C", "parsed": { "kind": "point", "number": 25.0, "unit": "c", "raw": "25 °C" } } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001956": { "query": "What electrolyte other than Na2SO4 is used for cyclic voltammetry of K3[Fe(CN)6] at 100 mV/s and room temperature?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 5, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "Na2SO4" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "100 mV/s", "parsed": { "kind": "point", "number": 100.0, "unit": "mv/s", "raw": "100 mV/s" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001949": { "query": "What electrolyte other than PBS is used for cyclic voltammetry of K3[Fe(CN)6] at 100 mV/s and room temperature?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 5, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "PBS" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "100 mV/s", "parsed": { "kind": "point", "number": 100.0, "unit": "mv/s", "raw": "100 mV/s" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001971": { "query": "What electrolyte other than [Fe(CN)6]3- is used for CV at 50 mV/s to study CH3OH at 25 °C?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 5, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "[Fe(CN)6]3-" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "50 mV/s", "parsed": { "kind": "point", "number": 50.0, "unit": "mv/s", "raw": "50 mV/s" } }, { "field": "target_species", "op": "=", "value": "CH3OH" }, { "field": "temperature", "op": "=", "value": "25 °C", "parsed": { "kind": "point", "number": 25.0, "unit": "c", "raw": "25 °C" } } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001990": { "query": "What electrolyte other than [Fe(CN)6]4- is used for cyclic voltammetry of CH3OH at 100 mV/s and 24 °C?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 5, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "[Fe(CN)6]4-" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "100 mV/s", "parsed": { "kind": "point", "number": 100.0, "unit": "mv/s", "raw": "100 mV/s" } }, { "field": "target_species", "op": "=", "value": "CH3OH" }, { "field": "temperature", "op": "=", "value": "24 °C", "parsed": { "kind": "point", "number": 24.0, "unit": "c", "raw": "24 °C" } } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001985": { "query": "What electrolyte other than KCl is used for cyclic voltammetry of CH3OH at 100 mV/s and 24 °C?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 5, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "KCl" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "100 mV/s", "parsed": { "kind": "point", "number": 100.0, "unit": "mv/s", "raw": "100 mV/s" } }, { "field": "target_species", "op": "=", "value": "CH3OH" }, { "field": "temperature", "op": "=", "value": "24 °C", "parsed": { "kind": "point", "number": 24.0, "unit": "c", "raw": "24 °C" } } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001977": { "query": "What electrolyte other than H2SO4 is used for cyclic voltammetry of K3[Fe(CN)6] at room temperature with a scan rate of 10-100 mV/s?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 5, "has_numeric": true, "has_negation": true, "has_range": true, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "H2SO4" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "between", "range": { "lower": 10.0, "upper": 100.0, "unit": "mv/s" }, "surface": "10-100 mV/s" }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001986": { "query": "What electrolyte other than H2SO4 is used for cyclic voltammetry of CH3OH at 100 mV/s and 24 °C?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 5, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "H2SO4" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "100 mV/s", "parsed": { "kind": "point", "number": 100.0, "unit": "mv/s", "raw": "100 mV/s" } }, { "field": "target_species", "op": "=", "value": "CH3OH" }, { "field": "temperature", "op": "=", "value": "24 °C", "parsed": { "kind": "point", "number": 24.0, "unit": "c", "raw": "24 °C" } } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001950": { "query": "What electrolyte other than H2SO4 is used for cyclic voltammetry of K3[Fe(CN)6] at 100 mV/s and room temperature?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 5, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "H2SO4" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "100 mV/s", "parsed": { "kind": "point", "number": 100.0, "unit": "mv/s", "raw": "100 mV/s" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001948": { "query": "What electrolyte other than KOH is used for CV at 100 mV/s with K3[Fe(CN)6] at room temperature?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 5, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "KOH" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "100 mV/s", "parsed": { "kind": "point", "number": 100.0, "unit": "mv/s", "raw": "100 mV/s" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001978": { "query": "What electrolyte other than water is used for cyclic voltammetry of K3[Fe(CN)6] at room temperature with a scan rate of 10-100 mV/s?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 5, "has_numeric": true, "has_negation": true, "has_range": true, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "water" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "between", "range": { "lower": 10.0, "upper": 100.0, "unit": "mv/s" }, "surface": "10-100 mV/s" }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001814": { "query": "What electrolyte other than KOH is used for electrochemical H2 experiments at 650 °C?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "KOH" }, { "field": "target_species", "op": "=", "value": "H2" }, { "field": "temperature", "op": "=", "value": "650 °C", "parsed": { "kind": "point", "number": 650.0, "unit": "c", "raw": "650 °C" } } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_000507": { "query": "What electrolyte other than NaOH is used for DPV detection of IgG?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "NaOH" }, { "field": "measurement_method", "op": "=", "value": "DPV" }, { "field": "target_species", "op": "=", "value": "IgG" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_002660": { "query": "What electrolyte other than Na2SO4 is used for cyclic voltammetry of K3[Fe(CN)6] at 0.06 V/s?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "Na2SO4" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "0.06 V/s", "parsed": { "kind": "point", "number": 0.06, "unit": "v/s", "raw": "0.06 V/s" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001930": { "query": "What electrolyte other than KCl is used for cyclic voltammetry of CH3OH at 24 °C?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "KCl" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "CH3OH" }, { "field": "temperature", "op": "=", "value": "24 °C", "parsed": { "kind": "point", "number": 24.0, "unit": "c", "raw": "24 °C" } } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_000794": { "query": "What electrolyte other than NaOH is used for electrochemistry of [Fe(CN)6]3-/4- at an SPE working electrode?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "NaOH" }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" }, { "field": "working_electrode", "op": "=", "value": "SPE" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_R2_pos_000385": { "query": "Find cyclic voltammetry experiments targeting ferricyanide/ferrocyanide ([Fe(CN)6]3-/[Fe(CN)6]4-) in PBS electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "PBS" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "ferricyanide/ferrocyanide ([Fe(CN)6]3-/[Fe(CN)6]4-)" } ], "explore_field": null }, "electrochemistry_R2_pos_000328": { "query": "Find cyclic voltammetry experiments targeting lysozyme in PBS electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "PBS" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "lysozyme" } ], "explore_field": null }, "electrochemistry_R4_pos_000457": { "query": "Find electrolysis experiments targeting CO2 in 1 m KOH electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KOH" }, { "field": "electrolytes.concentration", "op": "=", "value": "1 m", "parsed": { "kind": "point", "number": 1.0, "unit": "m", "raw": "1 m" } }, { "field": "measurement_method", "op": "=", "value": "electrolysis" }, { "field": "target_species", "op": "=", "value": "CO2" } ], "explore_field": null }, "electrochemistry_R4_pos_000650": { "query": "Find electrochemical impedance spectroscopy experiments targeting Fe(CN)6^3- in 100 mM KCl electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "measurement_method", "op": "=", "value": "EIS" }, { "field": "target_species", "op": "=", "value": "Fe(CN)6^3-" } ], "explore_field": null }, "electrochemistry_R4_pos_000474": { "query": "Find electrochemical experiments using LSV to target NO3- in 100 mM KOH electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KOH" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "measurement_method", "op": "=", "value": "LSV" }, { "field": "target_species", "op": "=", "value": "NO3-" } ], "explore_field": null }, "electrochemistry_R2_pos_000160": { "query": "Find electrochemical experiments targeting glucose in NaOH electrolyte using an MWCNT-CuBTC working electrode.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "NaOH" }, { "field": "target_species", "op": "=", "value": "glucose" }, { "field": "working_electrode", "op": "=", "value": "MWCNT-CuBTC" } ], "explore_field": null }, "electrochemistry_R4_pos_000500": { "query": "Find electrochemical experiments targeting CO2 using EIS in 1 M KHCO3 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KHCO3" }, { "field": "electrolytes.concentration", "op": "=", "value": "1 M", "parsed": { "kind": "point", "number": 1.0, "unit": "m", "raw": "1 M" } }, { "field": "measurement_method", "op": "=", "value": "EIS" }, { "field": "target_species", "op": "=", "value": "CO2" } ], "explore_field": null }, "electrochemistry_R4_pos_000683": { "query": "Find cyclic voltammetry experiments targeting Cu(II) in 100 mM H2SO4 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "H2SO4" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "Cu(II)" } ], "explore_field": null }, "electrochemistry_R4_pos_000142": { "query": "Find cyclic voltammetry experiments targeting K3[Fe(CN)6] in KCl electrolyte at a scan rate of 0.1 V/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "0.1 V/s", "parsed": { "kind": "point", "number": 0.1, "unit": "v/s", "raw": "0.1 V/s" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" } ], "explore_field": null }, "electrochemistry_R5_pos_000015": { "query": "Find electrochemical experiments using LSV to target O2 in 100 mM KOH at room temperature.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KOH" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "measurement_method", "op": "=", "value": "LSV" }, { "field": "target_species", "op": "=", "value": "O2" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": null }, "electrochemistry_R5_pos_000025": { "query": "Find cyclic voltammetry experiments targeting CH3OH in 1 M KOH electrolyte at 24 °C.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KOH" }, { "field": "electrolytes.concentration", "op": "=", "value": "1 M", "parsed": { "kind": "point", "number": 1.0, "unit": "m", "raw": "1 M" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "CH3OH" }, { "field": "temperature", "op": "=", "value": "24 °C", "parsed": { "kind": "point", "number": 24.0, "unit": "c", "raw": "24 °C" } } ], "explore_field": null }, "electrochemistry_R4_pos_000139": { "query": "Find cyclic voltammetry experiments targeting K3[Fe(CN)6] in KCl electrolyte at a scan rate of 0.04 V/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "0.04 V/s", "parsed": { "kind": "point", "number": 0.04, "unit": "v/s", "raw": "0.04 V/s" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" } ], "explore_field": null }, "electrochemistry_R4_pos_000731": { "query": "Find electrochemical experiments targeting CO2 with an F-CuNS working electrode in 3 M KCl electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "electrolytes.concentration", "op": "=", "value": "3 M", "parsed": { "kind": "point", "number": 3.0, "unit": "m", "raw": "3 M" } }, { "field": "target_species", "op": "=", "value": "CO2" }, { "field": "working_electrode", "op": "=", "value": "F-CuNS" } ], "explore_field": null }, "electrochemistry_EI_NEG_neg_000878": { "query": "What electrolyte other than H2SO4 is used for electrochemical glucose detection with a Cu(II)/GO/SPCE working electrode?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "H2SO4" }, { "field": "target_species", "op": "=", "value": "glucose" }, { "field": "working_electrode", "op": "=", "value": "Cu(II)/GO/SPCE" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_R4_pos_000519": { "query": "Find cyclic voltammetry experiments targeting K4[Fe(CN)6] in 5 mM KCl electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "electrolytes.concentration", "op": "=", "value": "5 mM", "parsed": { "kind": "point", "number": 5.0, "unit": "mm", "raw": "5 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "K4[Fe(CN)6]" } ], "explore_field": null }, "electrochemistry_R5_pos_000002": { "query": "Find cyclic voltammetry experiments targeting CH3OH in KOH electrolyte at scan rates of 20-100 mV/s and temperatures of 5-84 °C.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": true, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KOH" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "between", "range": { "lower": 20.0, "upper": 100.0, "unit": "mv/s" }, "surface": "20-100 mV/s" }, { "field": "target_species", "op": "=", "value": "CH3OH" }, { "field": "temperature", "op": "between", "range": { "lower": 5.0, "upper": 84.0, "unit": "c" }, "surface": "5-84 °C" } ], "explore_field": null }, "electrochemistry_R1_pos_000193": { "query": "Find electrochemical experiments targeting CO2 in 0.5 M K2HPO4 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R1", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "K2HPO4" }, { "field": "electrolytes.concentration", "op": "=", "value": "0.5 M", "parsed": { "kind": "point", "number": 0.5, "unit": "m", "raw": "0.5 M" } }, { "field": "target_species", "op": "=", "value": "CO2" } ], "explore_field": null }, "electrochemistry_R1_pos_000068": { "query": "Find electrochemical experiments targeting CO2 in 50 mM K2CO3 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R1", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "K2CO3" }, { "field": "electrolytes.concentration", "op": "=", "value": "50 mM", "parsed": { "kind": "point", "number": 50.0, "unit": "mm", "raw": "50 mM" } }, { "field": "target_species", "op": "=", "value": "CO2" } ], "explore_field": null }, "electrochemistry_R1_pos_000412": { "query": "Find electrochemical experiments targeting the K3[Fe(CN)6]/K4[Fe(CN)6] redox couple in 2.5 mM K3[Fe(CN)6] electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R1", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "K3[Fe(CN)6]" }, { "field": "electrolytes.concentration", "op": "=", "value": "2.5 mM", "parsed": { "kind": "point", "number": 2.5, "unit": "mm", "raw": "2.5 mM" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]/K4[Fe(CN)6]" } ], "explore_field": null }, "electrochemistry_R4_pos_000288": { "query": "Find electrochemical experiments targeting CO2 in 0.5 M KHCO3 electrolyte using an Ag/AgCl (KCl-sat.) reference electrode.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KHCO3" }, { "field": "electrolytes.concentration", "op": "=", "value": "0.5 M", "parsed": { "kind": "point", "number": 0.5, "unit": "m", "raw": "0.5 M" } }, { "field": "reference_electrode", "op": "=", "value": "Ag/AgCl (KCl-sat.)" }, { "field": "target_species", "op": "=", "value": "CO2" } ], "explore_field": null }, "electrochemistry_R2_pos_000086": { "query": "Find electrochemical experiments targeting NO2- in KCl electrolyte with an Ag/AgCl reference electrode.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "reference_electrode", "op": "=", "value": "Ag/AgCl" }, { "field": "target_species", "op": "=", "value": "NO2-" } ], "explore_field": null }, "electrochemistry_EI_NEG_neg_002265": { "query": "What electrolyte other than water is used for CV at 5 mV/s with VO2+ as the target species?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "water" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "5 mV/s", "parsed": { "kind": "point", "number": 5.0, "unit": "mv/s", "raw": "5 mV/s" } }, { "field": "target_species", "op": "=", "value": "VO2+" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_R4_pos_000805": { "query": "Find electrochemical experiments targeting DCF at an AGCE working electrode in 25 mM phosphate buffer.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "phosphate buffer" }, { "field": "electrolytes.concentration", "op": "=", "value": "25 mM", "parsed": { "kind": "point", "number": 25.0, "unit": "mm", "raw": "25 mM" } }, { "field": "target_species", "op": "=", "value": "DCF" }, { "field": "working_electrode", "op": "=", "value": "AGCE" } ], "explore_field": null }, "electrochemistry_EI_NEG_neg_000237": { "query": "What electrolyte other than PBS is used for H2O2 electrochemistry with an Ag pseudo-reference electrode?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "PBS" }, { "field": "reference_electrode", "op": "=", "value": "Ag (pseudo-reference)" }, { "field": "target_species", "op": "=", "value": "H2O2" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_R4_pos_000605": { "query": "Find cyclic voltammetry experiments targeting Fe(CN)6^3-/Fe(CN)6^4- in 10 mM KCl electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "electrolytes.concentration", "op": "=", "value": "10 mM", "parsed": { "kind": "point", "number": 10.0, "unit": "mm", "raw": "10 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "Fe(CN)6^3-/Fe(CN)6^4-" } ], "explore_field": null }, "electrochemistry_R2_pos_000175": { "query": "Find electrochemical experiments targeting aniline in H2SO4 electrolyte using a CFC working electrode.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "H2SO4" }, { "field": "target_species", "op": "=", "value": "aniline" }, { "field": "working_electrode", "op": "=", "value": "CFC" } ], "explore_field": null }, "electrochemistry_R2_pos_000238": { "query": "Find electrochemical impedance spectroscopy experiments targeting the [Fe(CN)6]3-/4- redox couple in K4[Fe(CN)6] electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "K4[Fe(CN)6]" }, { "field": "measurement_method", "op": "=", "value": "EIS" }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" } ], "explore_field": null }, "electrochemistry_EI_NEG_neg_002096": { "query": "What electrolyte other than Na2SO4 is used for CV at 300 mV/s with [Ru(NH3)6]2+/[Ru(NH3)6]3+?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "Na2SO4" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "300 mV/s", "parsed": { "kind": "point", "number": 300.0, "unit": "mv/s", "raw": "300 mV/s" } }, { "field": "target_species", "op": "=", "value": "[Ru(NH3)6]2+/[Ru(NH3)6]3+" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_EI_NEG_neg_001064": { "query": "What electrolyte other than KOH is used with an Ag/AgCl reference electrode for electrochemical measurements of [Fe(CN)6]3-/4- at room temperature?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 4, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "KOH" }, { "field": "reference_electrode", "op": "=", "value": "Ag/AgCl" }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_R4_pos_000624": { "query": "Find cyclic voltammetry experiments targeting FcMeOH in 100 mM KCl electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "FcMeOH" } ], "explore_field": null }, "electrochemistry_R4_pos_000706": { "query": "Find cyclic voltammetry experiments targeting NO2- in 100 mM KCl electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "NO2-" } ], "explore_field": null }, "electrochemistry_R4_pos_000211": { "query": "Find cyclic voltammetry experiments targeting [Fe(CN)6]3-/[Fe(CN)6]4- in PBS at a scan rate of 100 mV/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "PBS" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "=", "value": "100 mV/s", "parsed": { "kind": "point", "number": 100.0, "unit": "mv/s", "raw": "100 mV/s" } }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/[Fe(CN)6]4-" } ], "explore_field": null }, "electrochemistry_R4_pos_000062": { "query": "Find cyclic voltammetry experiments targeting the [Fe(CN)6]3-/4- redox couple in K4[Fe(CN)6] electrolyte at scan rates of 20-250 mV/s.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": true, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "K4[Fe(CN)6]" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "scan_rate", "op": "between", "range": { "lower": 20.0, "upper": 250.0, "unit": "mv/s" }, "surface": "20-250 mV/s" }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]3-/4-" } ], "explore_field": null }, "electrochemistry_R4_pos_000001": { "query": "Find electrochemical experiments targeting CO2 in KHCO3 electrolyte at room temperature using an Ag/AgCl (sat. KCl) reference electrode.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KHCO3" }, { "field": "reference_electrode", "op": "=", "value": "Ag/AgCl (sat. KCl)" }, { "field": "target_species", "op": "=", "value": "CO2" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": null }, "electrochemistry_R4_pos_000792": { "query": "Find electrochemical experiments targeting Cd2+ in 100 mM acetate buffer using an IONP-COOH/APTES-ITO working electrode.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "acetate buffer" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "target_species", "op": "=", "value": "Cd2+" }, { "field": "working_electrode", "op": "=", "value": "IONP-COOH/APTES-ITO" } ], "explore_field": null }, "electrochemistry_R2_pos_000097": { "query": "Find electrochemical experiments targeting CO2 with an ER-CuNS working electrode in KCl electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KCl" }, { "field": "target_species", "op": "=", "value": "CO2" }, { "field": "working_electrode", "op": "=", "value": "ER-CuNS" } ], "explore_field": null }, "electrochemistry_EI_NEG_neg_001628": { "query": "What electrolyte other than KOH is used for electrochemical H2 experiments at 600 °C?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": true, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "KOH" }, { "field": "target_species", "op": "=", "value": "H2" }, { "field": "temperature", "op": "=", "value": "600 °C", "parsed": { "kind": "point", "number": 600.0, "unit": "c", "raw": "600 °C" } } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_R1_pos_000355": { "query": "Find electrochemical experiments targeting D-xylose in 0.5 M NaOH electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R1", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "NaOH" }, { "field": "electrolytes.concentration", "op": "=", "value": "0.5 M", "parsed": { "kind": "point", "number": 0.5, "unit": "m", "raw": "0.5 M" } }, { "field": "target_species", "op": "=", "value": "D-xylose" } ], "explore_field": null }, "electrochemistry_R2_pos_000250": { "query": "Find cyclic voltammetry experiments targeting CO2 in H2SO4 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "H2SO4" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "CO2" } ], "explore_field": null }, "electrochemistry_R1_pos_000474": { "query": "Find electrochemical experiments targeting ferrocene (Fc) in 100 mM NaCl electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R1", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "NaCl" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "target_species", "op": "=", "value": "ferrocene (Fc)" } ], "explore_field": null }, "electrochemistry_R2_pos_000035": { "query": "Find electrochemical experiments targeting V(IV) in H2SO4 electrolyte using an SCE reference electrode.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "H2SO4" }, { "field": "reference_electrode", "op": "=", "value": "SCE" }, { "field": "target_species", "op": "=", "value": "V(IV)" } ], "explore_field": null }, "electrochemistry_R4_pos_000800": { "query": "Find electrochemical experiments targeting K3[Fe(CN)6] in 5 mM K3[Fe(CN)6] electrolyte using a GCE working electrode.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "K3[Fe(CN)6]" }, { "field": "electrolytes.concentration", "op": "=", "value": "5 mM", "parsed": { "kind": "point", "number": 5.0, "unit": "mm", "raw": "5 mM" } }, { "field": "target_species", "op": "=", "value": "K3[Fe(CN)6]" }, { "field": "working_electrode", "op": "=", "value": "GCE" } ], "explore_field": null }, "electrochemistry_R4_pos_000806": { "query": "Find electrochemical experiments targeting CH3OH with a Pt-rGO/PAC-1:1 working electrode in 1 M HClO4 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "HClO4" }, { "field": "electrolytes.concentration", "op": "=", "value": "1 M", "parsed": { "kind": "point", "number": 1.0, "unit": "m", "raw": "1 M" } }, { "field": "target_species", "op": "=", "value": "CH3OH" }, { "field": "working_electrode", "op": "=", "value": "Pt-rGO/PAC-1:1" } ], "explore_field": null }, "electrochemistry_R1_pos_000028": { "query": "Find electrochemical experiments targeting CH3OH in KOH electrolyte at 5-84 °C.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R1", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": true, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KOH" }, { "field": "target_species", "op": "=", "value": "CH3OH" }, { "field": "temperature", "op": "between", "range": { "lower": 5.0, "upper": 84.0, "unit": "c" }, "surface": "5-84 °C" } ], "explore_field": null }, "electrochemistry_R2_pos_000361": { "query": "Find differential pulse voltammetry experiments targeting AA in PBS electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "PBS" }, { "field": "measurement_method", "op": "=", "value": "DPV" }, { "field": "target_species", "op": "=", "value": "AA" } ], "explore_field": null }, "electrochemistry_R1_pos_000500": { "query": "Find electrochemical experiments targeting NO3- in 0.4 M KNO3 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R1", "constraint_count": 3, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KNO3" }, { "field": "electrolytes.concentration", "op": "=", "value": "0.4 M", "parsed": { "kind": "point", "number": 0.4, "unit": "m", "raw": "0.4 M" } }, { "field": "target_species", "op": "=", "value": "NO3-" } ], "explore_field": null }, "electrochemistry_R4_pos_000014": { "query": "Find cyclic voltammetry experiments targeting O2 in KOH electrolyte at room temperature.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KOH" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "O2" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": null }, "electrochemistry_EI_NEG_neg_000535": { "query": "What electrolyte other than [Fe(CN)6]4- is used for LSV measurements targeting urea?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "[Fe(CN)6]4-" }, { "field": "measurement_method", "op": "=", "value": "LSV" }, { "field": "target_species", "op": "=", "value": "urea" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_R4_pos_000711": { "query": "Find cyclic voltammetry experiments targeting [Fe(CN)6]^3-/[Fe(CN)6]^4- in 100 mM LiClO4 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "LiClO4" }, { "field": "electrolytes.concentration", "op": "=", "value": "100 mM", "parsed": { "kind": "point", "number": 100.0, "unit": "mm", "raw": "100 mM" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "[Fe(CN)6]^3-/[Fe(CN)6]^4-" } ], "explore_field": null }, "electrochemistry_R4_pos_000804": { "query": "Find electrochemical experiments targeting DCF with an AGCE working electrode in 25 mM acetate buffer.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "acetate buffer" }, { "field": "electrolytes.concentration", "op": "=", "value": "25 mM", "parsed": { "kind": "point", "number": 25.0, "unit": "mm", "raw": "25 mM" } }, { "field": "target_species", "op": "=", "value": "DCF" }, { "field": "working_electrode", "op": "=", "value": "AGCE" } ], "explore_field": null }, "electrochemistry_R4_pos_000451": { "query": "Find electrochemical experiments targeting CO2 by potentiostatic electrolysis in 0.5 M KHCO3 electrolyte.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KHCO3" }, { "field": "electrolytes.concentration", "op": "=", "value": "0.5 M", "parsed": { "kind": "point", "number": 0.5, "unit": "m", "raw": "0.5 M" } }, { "field": "measurement_method", "op": "=", "value": "potentiostatic electrolysis" }, { "field": "target_species", "op": "=", "value": "CO2" } ], "explore_field": null }, "electrochemistry_R2_pos_000253": { "query": "Find electrochemical experiments targeting CO2 in KHCO3 electrolyte using chronopotentiometry.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R2", "constraint_count": 3, "has_numeric": false, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KHCO3" }, { "field": "measurement_method", "op": "=", "value": "chronopotentiometry" }, { "field": "target_species", "op": "=", "value": "CO2" } ], "explore_field": null }, "electrochemistry_EI_NEG_neg_000509": { "query": "What electrolyte other than phosphate buffer is used for DPV detection of IgG?", "domain": "electrochemistry", "type": "input_exploration", "type_id": "EI_NEG", "constraint_count": 3, "has_numeric": false, "has_negation": true, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "!=", "value": "phosphate buffer" }, { "field": "measurement_method", "op": "=", "value": "DPV" }, { "field": "target_species", "op": "=", "value": "IgG" } ], "explore_field": "electrolytes.chemical" }, "electrochemistry_R5_pos_000014": { "query": "Find cyclic voltammetry experiments targeting O2 in 0.5 M H2SO4 at 25 °C.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R5", "constraint_count": 5, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "H2SO4" }, { "field": "electrolytes.concentration", "op": "=", "value": "0.5 M", "parsed": { "kind": "point", "number": 0.5, "unit": "m", "raw": "0.5 M" } }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "O2" }, { "field": "temperature", "op": "=", "value": "25 °C", "parsed": { "kind": "point", "number": 25.0, "unit": "c", "raw": "25 °C" } } ], "explore_field": null }, "electrochemistry_R4_pos_000008": { "query": "Find electrochemical experiments targeting CO2 using potentiostatic electrolysis in KHCO3 electrolyte at room temperature.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": false, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KHCO3" }, { "field": "measurement_method", "op": "=", "value": "potentiostatic electrolysis" }, { "field": "target_species", "op": "=", "value": "CO2" }, { "field": "temperature", "op": "=", "value": "room temperature" } ], "explore_field": null }, "electrochemistry_R4_pos_000703": { "query": "Find cyclic voltammetry experiments targeting urea in KOH electrolyte at 1.0-3.0 M.", "domain": "electrochemistry", "type": "reproduction", "type_id": "R4", "constraint_count": 4, "has_numeric": true, "has_negation": false, "has_range": true, "constraints": [ { "field": "electrolytes.chemical", "op": "=", "value": "KOH" }, { "field": "electrolytes.concentration", "op": "between", "range": { "lower": 1.0, "upper": 3.0, "unit": "m" }, "surface": "1.0-3.0 M" }, { "field": "measurement_method", "op": "=", "value": "CV" }, { "field": "target_species", "op": "=", "value": "urea" } ], "explore_field": null } }