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materials-science
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electronic-skin
self-healing-polymers
mechanochemistry
neuromorphic-materials
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"purpose": "mathematical and dimensional consistency only; no experimental data",
"layer_sum_um": 1600,
"taxel_count": 256,
"last_center_mm": 17.5,
"active_field_limits_mm": [
2,
18
],
"HS_NH2_mmol": 4.8,
"HS_NCO_mmol": 3.36,
"HS_CHO_mmol": 1.44,
"HS_group_balance_difference_mmol": 0.0,
"HS_active_feed_g": 12.5185752,
"MCI_reagent_g_at_exact_90percent_assay": 0.48971999999999993,
"TFB_reagent_g_at_exact_98percent_assay": 0.07941551020408164,
"HS_formal_imine_water_g": 0.025941600000000002,
"ionic_liquid_weight_fraction": 0.3,
"ionic_diffusion_tau_s_at_D1e-11": {
"5": 0.2533029591058444,
"15": 2.2797266319525997,
"50": 25.330295910584443
},
"Dlat_max_m2_s_for_10um_blur_25s": 2.0000000000000004e-12,
"Dlat_max_m2_s_for_10um_blur_24h": 5.787037037037038e-16,
"healing_archive_selectivity_ratio_min": 15.275531847822252,
"kH_min_for_80percent_in_24h_s-1": 1.862775361613542e-05,
"kM_max_for_90percent_in_24h_s-1": 1.2194504127063226e-06,
"kM_max_for_90percent_24h_s-1": 1.2194504127063226e-06,
"archive_decay_time_days_for_90percent_24h": 9.491221581029906,
"RM_codewords": 256,
"RM_pairwise_comparisons": 32640,
"RM_dmin": 64,
"RM_max_correctable_arbitrary_errors": 31,
"witness_fraction_excluding_anchors": 0.00017006802721088434,
"hypothetical_ligament_stress_gain_per_load_fraction": 981.7477042468104,
"hypothetical_ligament_stress_MPa_at_200kPa_1percent_axial_loadshare": 1.9634954084936203,
"nominal_cavity_loads_mN": {
"20": 3.926990816987242,
"80": 15.707963267948967,
"200": 39.26990816987241
},
"tile_envelope_volume_cm3": 0.64,
"tile_mass_g_if_all_density1p1": 0.7040000000000001,
"nominal_200kPa_load_N_tile": 80.0,
"nominal_200kPa_load_N_active": 51.2,
"thermal_diffusion_s_at_alpha1e-7": {
"0.5mm": 2.5,
"1.6mm": 25.6
},
"all_checks_passed": true,
"force_recruitment": {
"initial": {
"g_N_m": 25,
"Ks_N_m": 20.0,
"Ktotal_N_m": 100.0,
"phi": 0.2,
"overall_indentation_um": 39.26990816987242,
"receptor_force_mN": 0.7853981633974484,
"receptor_extension_um": 7.853981633974484,
"pressure_for_1mN_kPa": 25.464790894703256
},
"written": {
"g_N_m": 200,
"Ks_N_m": 66.66666666666667,
"Ktotal_N_m": 146.66666666666669,
"phi": 0.45454545454545453,
"overall_indentation_um": 26.77493738854937,
"receptor_force_mN": 1.7849958259032916,
"receptor_extension_um": 17.849958259032917,
"pressure_for_1mN_kPa": 11.204507993669433
},
"local_gain_ratio": 2.2727272727272725,
"relative_total_stiffness_increase": 0.4666666666666668,
"phi_ceiling": 0.5555555555555556,
"gain_ceiling": 2.7777777777777777,
"minimum_1mN_threshold_kPa": 9.167324722093172,
"counterexample_bypass400_N_m": {
"g_N_m": 200,
"Ks_N_m": 66.66666666666667,
"Ktotal_N_m": 466.6666666666667,
"phi": 0.14285714285714285,
"overall_indentation_um": 8.414980322115516,
"receptor_force_mN": 0.5609986881410346,
"receptor_extension_um": 5.609986881410346,
"pressure_for_1mN_kPa": 35.65070725258457
},
"counterexample_capture_yield_0p04": {
"g_N_m": 22.4,
"Ks_N_m": 18.30065359477124,
"Ktotal_N_m": 98.30065359477123,
"phi": 0.18617021276595744,
"overall_indentation_um": 39.94877626323458,
"receptor_force_mN": 0.7310887159284759,
"receptor_extension_um": 7.310887159284758,
"pressure_for_1mN_kPa": 27.35646107545264
}
},
"nonlinear_implicit_derivative_check": {
"dimensionless_test_equilibria": 100,
"max_abs_error": 1.1429002189089488e-10,
"scope": "independent equilibrium-root finite difference against analytic derivative; not an experimental constitutive model"
},
"illustrative_kinetics": {
"kw_law": "0.03*exp(4*delta_g/delta_g_initial) s^-1",
"kc_normalized": 5,
"theta": 1,
"integration": "RK4 dt=0.01s; 60s, no fitted data",
"inventory_reference": "interface-eligible N_I; reduced model assumes no inaccessible bulk activation (L_B=0)",
"min_g_N_m": 24.911275808276574,
"last_record": [
60.0,
0.9987329853901284,
0.991923965756561,
198.51860381106252,
0.45392957497135905,
146.5012502660331
],
"warning": "initial softening is present; finite capacity does not guarantee fracture protection",
"configuration": "reference-free control only; final referenced module is verified below"
},
"receiver_protected_feed_g": 1.7361616,
"formal_receiver_deacetylation_mass_loss_g": 0.0210185,
"upper_bound_accessible_writer_inventory": {
"assumed_density_kg_m3": 1000,
"assumed_writer_repeat_fraction": 0.005,
"assumed_accessible_depth_nm": 5,
"cD_mol_m3": 29.368575624082233,
"gamma_mol_m2": 1.4684287812041118e-07,
"sites_per_1000_um2": 88430848.16446404,
"fraction_of_uniform_5um_film_one_face": 0.001,
"scope": "uniform bulk CONTROL; not the final gate-coat design or measured active-link density"
},
"final_referenced_module": {
"initial": {
"KA_N_m": 20.0,
"KR_N_m": 20.0,
"Ktotal_N_m": 120.0,
"delta_um": 32.72492347489368,
"FA_mN": 0.6544984694978735,
"FR_mN": 0.6544984694978735,
"Q": 1.0,
"xg_um": 26.17993877991494,
"xi_um": 6.544984694978735,
"P_for_active_1mN_kPa": 30.557749073643908
},
"written": {
"KA_N_m": 66.66666666666667,
"KR_N_m": 20.0,
"Ktotal_N_m": 166.66666666666669,
"delta_um": 23.561944901923443,
"FA_mN": 1.5707963267948961,
"FR_mN": 0.47123889803846886,
"Q": 3.3333333333333335,
"xg_um": 7.85398163397448,
"xi_um": 15.70796326794896,
"P_for_active_1mN_kPa": 12.73239544735163
},
"actual_FA_gain": 2.3999999999999995,
"reference_ratio_gain": 3.3333333333333335,
"host_bypass_invariance_max_abs_error": 8.881784197001252e-16,
"tested_Kb_N_m": [
0,
10,
80,
200,
1000
],
"g_programmed_from_Q_N_m": {
"1": 25.0,
"2": 66.66666666666667,
"3": 150.0
},
"Q_architectural_ceiling": 5,
"cannot_infer": "absolute pressure without total-force/bypass calibration"
},
"nonlinear_reference_reconstruction": {
"model_equilibria": 72,
"max_absolute_extension_error": 2.220446049250313e-16,
"scope": "dimensionless monotone nonlinear constitutive models; no measured material properties"
},
"antipodal_geometry": {
"footprints_inside_radius250um": true,
"matched_affine_tilt_ratio": 1.0,
"scope": "linear matched positive-contact model; no plate-bending validation"
},
"conditional_loaded_travel_limit": {
"required_measured_delta_max_um": 50,
"FA_max_mN": 3.3333333333333335,
"FR_max_mN": 1.0,
"each_active_post_force_cap_mN": 1.6666666666666667,
"active_sensor_extension_um": 33.333333333333336,
"generic_g_infinite_FA_bound_mN": 5.0,
"ideal_stop_onset_kPa_initial": 30.557749073643908,
"ideal_stop_onset_kPa_written": 42.441318157838765,
"ideal_stop_force_at200kPa_mN_initial": 33.269908169872416,
"ideal_stop_force_at200kPa_mN_written": 30.93657483653908,
"scope": "conditional idealized upper-travel contract; finite stop compliance, impact and survival require tests"
},
"example_force_error_budget": {
"assumed_each_force_error_uN": 5,
"extension_error_bound_um": 0.30000000000000004,
"written_xg_um_at20kPa": 7.85398163397448,
"scope": "assumed readout error; calibration and mismatch errors excluded"
},
"surface_writer_geometry_budget": {
"WG_nominal_thickness_nm": 100,
"WG_thickness_tolerance_nm": 20,
"W0_support_um": 4.9,
"assumed_accessible_depth_nm": 5,
"accessible_fraction": 0.05,
"geometric_utilization_ratio_vs5um_control": 50,
"gamma_upper_mol_m2": 7.342143906020559e-07,
"areal_inventory_ratio_vs_control": 5.0,
"total_writer_per_area_ratio_vs_control": 0.09999999999999999,
"scope": "approximate HMA-repeat inventory geometry; not sensitivity, activation or yield"
}
} |