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Credits adapted from the Loose liner notes .
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= = Charts = =
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= = Certifications = =
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= = Release history = =
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= 2013 – 14 York City F.C. season =
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The 2013 – 14 season was the 92nd season of competitive association football and 77th season in the Football League played by York City Football Club , a professional football club based in York , North Yorkshire , England . Their 17th @-@ place finish in 2012 – 13 meant it was their second consecutive season in Leagu...
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Nigel Worthington , starting his first full season as York manager , made eight permanent summer signings . By the turn of the year York were only above the relegation zone on goal difference , before a 17 @-@ match unbeaten run saw the team finish in seventh @-@ place in the 24 @-@ team 2013 – 14 Football League Two ...
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35 players made at least one appearance in nationally organised first @-@ team competition , and there were 12 different goalscorers . Defender Ben Davies missed only five of the fifty @-@ two competitive matches played over the season . Wes Fletcher finished as leading scorer with 13 goals , of which 10 came in leagu...
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= = Background and pre @-@ season = =
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The 2012 – 13 season was York City 's first season back in the Football League , having won the Conference Premier play @-@ offs in 2011 – 12 after eights years in the Football Conference . Manager Gary Mills was sacked in March 2013 following an 11 @-@ match run without a victory , and was replaced by former Northern...
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Following the previous season 's conclusion Lee Bullock , Jon Challinor , Chris Doig , Ben Everson , Scott Kerr , David McDaid , Patrick McLaughlin , Michael Potts , Jamie Reed and Jason Walker were released by York , while Matty Blair departed for Fleetwood Town . David McGurk , Lanre Oyebanjo , Danny Parslow , Tom P...
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York retained the previous season 's home and away kits . The home kit comprised red shirts with white sleeves , light blue shorts and white socks . The away kit included light blue shirts with white sleeves , white shorts and light blue socks . Benenden Health continued as shirt sponsors for the second successive sea...
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= = Review = =
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= = = August = = =
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York began the season with a 1 – 0 home win over the previous season 's play @-@ off finalists , Northampton Town , with debutant Jarvis scoring the winning goal in the 90th @-@ minute . However , defeat came in York 's match against Championship side Burnley in the first round of the League Cup , going down 4 – 0 at ...
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= = = September = = =
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York suffered their first home league defeat of the season after AFC Wimbledon won 2 – 0 , with Michael Smith scoring in each half . Former Ipswich Town midfielder Josh Carson , who had a spell on loan with York the previous season , signed a contract until the end of 2013 – 14 and Sheffield United midfielder Elliott ...
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= = = October = = =
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Defender Luke O 'Neill was signed from Burnley on a 28 @-@ day emergency loan . He made his debut in York 's 3 – 0 win away at Torquay , which was the team 's first successive win of the season . York were knocked out of the Football League Trophy in the second round after being beaten 3 – 0 at home by League One team...
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= = = November = = =
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Bowman scored his first goals for York away to Cheltenham Town , as York twice fought back from behind to draw 2 – 2 . York drew 3 – 3 away to Bristol Rovers to earn a first round replay in the FA Cup , taking the lead through Jarvis before Eliot Richards equalised for the home team . Carson scored a 30 yard volley to...
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Defender Keith Lowe , of Cheltenham , and goalkeeper Nick Pope , of Charlton Athletic , were signed on loan until January 2014 . They both played in York 's first league defeat in four weeks , 2 – 1 away , to Southend United . Kevan Hurst gave Southend the lead early into the match and Bowman equalised for York with a...
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= = = December = = =
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Cresswell retired from playing as a result of an eye complaint and a knee injury . York drew 1 – 1 away to Burton Albion , with an own goal scored by Shane Cansdell @-@ Sherriff giving York the lead in the 64th @-@ minute before the home team equalised eight minutes later through Billy Kee . Atkinson was released afte...
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= = = January = = =
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Jarvis scored the only goal in York 's first win since October 2013 , a 1 – 0 home victory over Morecambe on New Year 's Day . McCarey was recalled by Wolverhampton Wanderers due to an injury to one of their goalkeepers , while O 'Neill was recalled by Burnley to take part in their FA Cup match . York achieved back @-...
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York achieved three successive wins for the first time in 2013 – 14 after beating Northampton 2 – 0 away , with Bowman and Fletcher scoring in three @-@ second half minutes . Defender John McCombe was signed on a two @-@ and @-@ a @-@ half @-@ year contract following his release from Mansfield , before Clay and Jamal ...
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= = = February = = =
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Fletcher scored a 90th @-@ minute winner for York away to Fleetwood in a 2 – 1 win , a result that ended Fleetwood 's five @-@ match unbeaten run . York then drew 0 – 0 at home to fellow mid @-@ table team Cheltenham , before beating Plymouth 4 – 0 away with goals from Fletcher , McCombe ( 2 ) and Carson as the team a...
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= = = March = = =
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York achieved their first home win in five matches after beating Exeter 2 – 1 , with first half goals scored by McCombe and Coulson . Hayhurst 's loan was extended to the end of the season , having impressed in his six appearances for the club . Coulson scored again with the only goal , a 41st @-@ minute header , in Y...
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Striker Calvin Andrew , who had been released by Mansfield in January 2014 , was signed on a contract for the remainder of the season . He made his debut as a substitute in York 's 1 – 0 home win over bottom of the table Torquay , in which Hayhurst scored the only goal in the 11th @-@ minute with an 18 yard shot that ...
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= = = April = = =
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Pope made a number of saves as York held league leaders Rochdale to a 0 – 0 away draw , with a point being enough to lift the team back into seventh @-@ place . York were prevented from equalling a club record of eight consecutive clean sheets when Accrington scored a stoppage time equaliser in a 1 – 1 home draw , in ...
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= = = May = = =
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The league season concluded with an away match against divisional runners @-@ up Scunthorpe ; having gone two goals down York fought back to draw 2 – 2 with goals scored by Brobbel and Andrew . This result meant York finished the season in seventh @-@ place in League Two , and would thus play fourth @-@ placed Fleetwo...
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= = Summary and aftermath = =
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York mostly occupied the bottom half of the table before the turn of the year , and dropped as low as 23rd in September 2013 . During February 2014 the team broke into the top half of the table and with one match left were in sixth @-@ place . York 's defensive record was the third best in League Two with 41 goals con...
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After the season ended York released Tom Allan , Andrew , Dickinson , McDonald , Puri and Reed , while McGurk retired from professional football . Bowman and Oyebanjo left to sign for Torquay and Crawley Town respectively while Coulson signed a new contract with the club . York 's summer signings included goalkeeper J...
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= = Match details = =
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League positions are sourced by Statto , while the remaining information is referenced individually .
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= = = Football League Two = = =
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= = = League table ( part ) = = =
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= = = FA Cup = = =
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= = = League Cup = = =
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= = = Football League Trophy = = =
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= = = Football League Two play @-@ offs = = =
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= = Transfers = =
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= = = In = = =
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Brackets around club names denote the player 's contract with that club had expired before he joined York .
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= = = Out = = =
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Brackets around club names denote the player joined that club after his York contract expired .
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= = = Loan in = = =
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= = = Loan out = = =
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= = Appearances and goals = =
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Source :
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Numbers in parentheses denote appearances as substitute .
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Players with names struck through and marked left the club during the playing season .
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Players with names in italics and marked * were on loan from another club for the whole of their season with York .
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Players listed with no appearances have been in the matchday squad but only as unused substitutes .
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Key to positions : GK – Goalkeeper ; DF – Defender ; MF – Midfielder ; FW – Forward
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= Antimony =
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Antimony is a chemical element with symbol Sb ( from Latin : stibium ) and atomic number 51 . A lustrous gray metalloid , it is found in nature mainly as the sulfide mineral stibnite ( Sb2S3 ) . Antimony compounds have been known since ancient times and were used for cosmetics ; metallic antimony was also known , but ...
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For some time , China has been the largest producer of antimony and its compounds , with most production coming from the Xikuangshan Mine in Hunan . The industrial methods to produce antimony are roasting and reduction using carbon or direct reduction of stibnite with iron .
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The largest applications for metallic antimony are as alloying material for lead and tin and for lead antimony plates in lead – acid batteries . Alloying lead and tin with antimony improves the properties of the alloys which are used in solders , bullets and plain bearings . Antimony compounds are prominent additives ...
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= = Characteristics = =
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= = = Properties = = =
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Antimony is in the nitrogen group ( group 15 ) and has an electronegativity of 2 @.@ 05 . As expected from periodic trends , it is more electronegative than tin or bismuth , and less electronegative than tellurium or arsenic . Antimony is stable in air at room temperature , but reacts with oxygen if heated , to form a...
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Antimony is a silvery , lustrous gray metalloid that has a Mohs scale hardness of 3 . Thus pure antimony is too soft to make hard objects ; coins made of antimony were issued in China 's Guizhou province in 1931 , but because of their rapid wear , their minting was discontinued . Antimony is resistant to attack by aci...
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Four allotropes of antimony are known : a stable metallic form and three metastable forms ( explosive , black and yellow ) . Elemental antimony is a brittle , silver @-@ white shiny metalloid . When slowly cooled , molten antimony crystallizes in a trigonal cell , isomorphic with the gray allotrope of arsenic . A rare...
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Elemental antimony adopts a layered structure ( space group R3m No. 166 ) in which layers consist of fused ruffled six @-@ membered rings . The nearest and next @-@ nearest neighbors form an irregular octahedral complex , with the three atoms in the same double layer being slightly closer than the three atoms in the n...
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= = = Isotopes = = =
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Antimony has two stable isotopes : 121Sb with a natural abundance of 57 @.@ 36 % and 123Sb with a natural abundance of 42 @.@ 64 % . It also has 35 radioisotopes , of which the longest @-@ lived is 125Sb with a half @-@ life of 2 @.@ 75 years . In addition , 29 metastable states have been characterized . The most stab...
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= = = Occurrence = = =
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The abundance of antimony in the Earth 's crust is estimated at 0 @.@ 2 to 0 @.@ 5 parts per million , comparable to thallium at 0 @.@ 5 parts per million and silver at 0 @.@ 07 ppm . Even though this element is not abundant , it is found in over 100 mineral species . Antimony is sometimes found natively ( e.g. on Ant...
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= = Compounds = =
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Antimony compounds are often classified according to their oxidation state : Sb ( III ) and Sb ( V ) . The + 5 oxidation state is more stable .
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= = = Oxides and hydroxides = = =
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Antimony trioxide ( Sb
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4O
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6 ) is formed when antimony is burnt in air . In the gas phase , this compound exists as Sb
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4O
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6 , but it polymerizes upon condensing . Antimony pentoxide ( Sb
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4O
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10 ) can only be formed by oxidation by concentrated nitric acid . Antimony also forms a mixed @-@ valence oxide , antimony tetroxide ( Sb
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2O
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4 ) , which features both Sb ( III ) and Sb ( V ) . Unlike oxides of phosphorus and arsenic , these various oxides are amphoteric , do not form well @-@ defined oxoacids and react with acids to form antimony salts .
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Antimonous acid Sb ( OH )
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3 is unknown , but the conjugate base sodium antimonite ( [ Na
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3SbO
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3 ]
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4 ) forms upon fusing sodium oxide and Sb
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4O
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6 . Transition metal antimonites are also known . Antimonic acid exists only as the hydrate HSb ( OH )
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6 , forming salts containing the antimonate anion Sb ( OH ) βˆ’
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6 . Dehydrating metal salts containing this anion yields mixed oxides .
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Many antimony ores are sulfides , including stibnite ( Sb
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2S
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3 ) , pyrargyrite ( Ag
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3SbS
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