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Oct 16

Development of different methods and their efficiencies for the estimation of diffusion coefficients following the diffusion couple technique

The interdiffusion coefficients are estimated either following the Wagner's method expressed with respect to the composition (mol or atomic fraction) normalized variable after considering the molar volume variation or the den Broeder's method expressed with respect to the concentration (composition divided by the molar volume) normalized variable. On the other hand, the relations for estimation of the intrinsic diffusion coefficients of components as established by van Loo and integrated diffusion coefficients in a phase with narrow homogeneity range as established by Wagner are currently available with respect to the composition normalized variable only. In this study, we have first derived the relation proposed by den Broeder following the line of treatment proposed by Wagner. Further, the relations for estimation of the intrinsic diffusion coefficients of the components and integrated interdiffusion coefficient are established with respect to the concentration normalized variable, which were not available earlier. The veracity of these methods is examined based on the estimation of data in Ni-Pd, Ni-Al and Cu-Sn systems. Our analysis indicates that both the approaches are logically correct and there is small difference in the estimated data in these systems although a higher difference could be found in other systems. The integrated interdiffusion coefficients with respect to the concentration (or concentration normalized variable) can only be estimated considering the ideal molar volume variation. This might be drawback in certain practical systems.

  • 2 authors
·
Jul 23, 2018

Learning Where to Split: Dynamic Band Splitting for Audio Source Separation

Audio source separation models must preserve fine spectral structure while keeping the cost of the separator tractable. Band-split architectures reduce this cost by manually partitioning the spectrum into predefined frequency bands and encoding each band as a token, but the same boundaries are used for every mixture. Because informative spectral structure varies with source content, fixed boundaries can merge discriminative components or spend tokens where little resolution is needed. We introduce Dynamic Band Splitting (DBS), an end-to-end framework that adapts boundary locations and band widths to each mixture under a fixed band-token budget. DBS predicts content-conditioned boundary scores within frequency blocks, selects a prescribed number of boundaries using hard Top-K, and applies content-dependent pooling to obtain compact band tokens. After separation, it smooths and expands these tokens to the original STFT grid, refines them along frequency, and decodes complex masks with a frequency-shared head. DBS improved separation over the corresponding static models on DnR v2, MUSDB18-HQ, and EchoSet, with DBS-BSRNN achieving relative gain of 29.0% in average SI-SDR on DnR v2. These results and boundary analyses on DnR v2 show that content-adaptive frequency partitioning benefits multiple separator backbones under a fixed band-token budget. Code and audio demos are available at https://cslikai.cn/Dynamic-Band-Splitting

Where Does the Audio Jailbreak Live? A Controlled Frequency-Depth Audit of AdvWave-P on Qwen2-Audio

We audit frequency and decoder-depth claims for AdvWave-P, an additive audio jailbreak, on Qwen2-Audio. The protocol masks frequency components of the perturbation in the short-time Fourier transform (STFT) domain and measures attack success and audio-span representations. On 520 AdvBench prompts, the primary judge labels 76.7% of adversarial inputs as jailbreaks. A condition-blind, single-annotator validation yields a Rogan-Gladen sensitivity estimate of 0.87 for this condition (about 0.83-0.95 with validation-rate uncertainty); this correction is not applied to masked conditions. The apparent frequency ranking depends on the partition: energy share alone predicts the standard eight-band ranking (Spearman's rho = 0.95), and equal-Hz and equal-energy partitions show that masking any tested band can sharply reduce attack success. At a finer 16-band equal-energy resolution, however, masking the narrow 7520-7960 Hz band leaves ASR at 0.10, which remains unresolved without a matched control. Matched-energy scattered-removal tests show that contiguous removal is more damaging in lower bands, while both forms approach the floor in upper bands. Global rescaling leaves ASR near baseline but tests amplitude sensitivity rather than frequency location. In a re-optimization pilot (n = 20), tested single- and two-band supports reach ASRs of 0.00, 0.25, and 0.40, while random supports covering about half the STFT bins reach a mean of 0.86. In a prompt- and energy-adjusted model, audio-span divergence is associated with band necessity, with the coefficient rising from +0.63 at the projector output to +0.93 at layer 30 (contrast +0.293, 95% CI [0.11, 0.51]). This association is not a causal localization, and single-layer patching does not establish a causal layer. The results support partition-aware auditing of frequency claims, leaving the fine-resolution top-band result and broader generality open.

  • 7 authors
·
Oct 3