Daily Papers

In this paper, both the pointwise space-time structures of the solution for a three-dimensional model describing gas dynamics in thermal non-equilibrium and the corresponding background stabilities within the L^p framework are investigated under the small initial perturbation assumption and the irrotationality condition. Our main tools are the modified Green's function according to the irrotationality condition, a priori energy method and a refined decay estimates of products composed of the entropy function and high-order derivatives.

The principle of detailed balance states that in equilibrium each elementary process is equilibrated by its reverse process. For many real physico-chemical complex systems (e.g. homogeneous combustion, heterogeneous catalytic oxidation, most enzyme reactions etc), detailed mechanisms include both reversible and irreversible reactions. In this case, the principle of detailed balance cannot be applied directly. We represent irreversible reactions as limits of reversible steps and obtain the principle of detailed balance for complex mechanisms with some irreversible elementary processes. We proved two consequences of the detailed balance for these mechanisms: the structural condition and the algebraic condition that form together the extended form of detailed balance. The algebraic condition is the principle of detailed balance for the reversible part. The structural condition is: the convex hull of the stoichiometric vectors of the irreversible reactions has empty intersection with the linear span of the stoichiometric vectors of the reversible reaction. Physically, this means that the irreversible reactions cannot be included in oriented pathways. The systems with the extended form of detailed balance are also the limits of the reversible systems with detailed balance when some of the equilibrium concentrations (or activities) tend to zero. Surprisingly, the structure of the limit reaction mechanism crucially depends on the relative speeds of this tendency to zero.

Zonal flows in planetary atmospheres are ubiquitous, and nearly all the planets in the Solar System have flows that are zonally rather than meridionally aligned. Jets, which are essentially concentrated streams of fluid that are distinct from a more quiescent background, are less common but can also be found in both deep and shallow atmospheres. Superrotation, which in most circumstances simply means prograde motion (relative to the planetary rotation) at the equator, is less common but can be found in both deep and shallow planetary atmospheres, and in both quickly and slowly-rotating atmospheres: Jupiter, Saturn, Venus and Titan all have superrotating atmospheres. Jets, especially superrotating jets, imply some form of `antidiffusion' of momentum, meaning that momentum (or angular momentum) must be transported upgradient. This article discusses some of the mechanisms that give rise to jets and superrotation in both deep and shallow planetary atmospheres, on both slow and fast rotators, contrasting and comparing the processes involved. Topics discussed include the roles of convection in deep atmospheres, geometric and topographic β-effects, potential-vorticity homogenization, wave--mean-flow interaction and tidal locking in exoplanets.